Silver nanoparticles as highly efficient and selective optical probe for sulphide via dendrimer formation in aqueous medium

RSC Advances ◽  
2016 ◽  
Vol 6 (18) ◽  
pp. 14563-14569 ◽  
Author(s):  
Isha Sanskriti ◽  
K. K. Upadhyay

1-[(4-Nitrophenyl)azo]-2-naphthol capped AgNPs were evaluated as a colorimetric sensor for S2− in aqueous medium over pH 4 to 10 with a nanomolar detection limit. The TEM, SEM and AFM images revealed the transition of spherical AgNPs into dendrimers.

Author(s):  
Divya Singhal ◽  
Neha Gupta ◽  
Ashok Kumar Singh

4-(thiazol-2-yldiazenyl)phenol (L1) and 2-((4-hydroxyphenyl) diazenyl)-5-nitrophenol (L2) based on azo phenol were synthesised and used as selective colorimetric sensor for CN- and AcO− ion in DMSO/H2O-HEPES (v/v; 1:1, pH–7.3 ± 0.2) and showed good sensitivity with large red shifts and nanomolar detection limit for CN- and AcO- ion. The stoichiometry of L1 with CN−/AcO− ion was found to be 1:1 and L2 with CN−/AcO− ion was found to be 1:2. Binding constant for L1+ CN−, L1 + AcO−, L2 + CN− and L2 + AcO− were calculated by B-H plot as 1.6 × 103, 8.0 × 102, 8.4 × 103 and 1.7 × 102 respectively. L2 showed high selectivity towards CN− ion with low detection limit of 81 nM and large binding constant. In addition, 1H NMR titration and DFT studies also supported the deprotonation mechanism of receptors in the presence of selective anions.


2019 ◽  
Vol 43 (4) ◽  
pp. 1972-1979 ◽  
Author(s):  
Noor ul Ain ◽  
Zara Aslam ◽  
Muhammad Yousuf ◽  
Waqas Ahmed Waseem ◽  
Samina Bano ◽  
...  

A highly efficient colorimetric sensor for gentamicin is proposed based on methyl gallate conjugated silver nanoparticles.


2014 ◽  
Vol 1040 ◽  
pp. 923-927 ◽  
Author(s):  
Nataliya A. Gavrilenko ◽  
Nadezhda V. Saranchina ◽  
Mikhail A. Gavrilenko

Silver nanoparticles synthesized by a reagent less method involving only thermal treatment have been used in colorimetric assay for the detection of hydrogen peroxide. The silver nanoparticles were directly synthesized in polymethacrylate matrix (PMM) by method based on the reduction of the inorganic precursor AgNO3, which was pre-adsorbed by PMM from solution, through thermal treatment. These silver nanoparticles were characterized using absorption spectroscopy. It was shown that the silver nanoparticles in PMM (Ag – PMM) had ability for reduction of hydrogen peroxide with silver oxidation. As a result, the yellow color of Ag – PMM samples was gradually changed to transparent color depending on the hydrogen peroxide concentrations. Hence, the silver nanoparticles in PMM could be used as colorimetric sensor for hydrogen peroxide in aqueous medium.


2018 ◽  
Vol 5 (2) ◽  
pp. 122-128 ◽  
Author(s):  
Srinivas L. Nakkalwar ◽  
Shivaji B. Patwari ◽  
Mohasim M. Patel ◽  
Vivekanand B. Jadhav

ACS Omega ◽  
2020 ◽  
Vol 5 (31) ◽  
pp. 19896-19904
Author(s):  
Sanay Naha ◽  
Natesan Thirumalaivasan ◽  
Somenath Garai ◽  
Shu-Pao Wu ◽  
Sivan Velmathi

2018 ◽  
Vol 41 (9) ◽  
pp. 1139-1150
Author(s):  
Larissa D. Bortoli ◽  
Soraya M. Palácio ◽  
Eliane Hermes ◽  
Dilcemara C. Zenatti ◽  
Márcia T. Veit ◽  
...  

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