Highly chemoselective hydrogenation of nitroarenes catalyzed by 3,6-di(pyridin-2-yl)-1,2,4,5-s-tetrazine capped‑silver nanoparticles in aqueous medium at room temperature

2019 ◽  
Vol 119 ◽  
pp. 62-66 ◽  
Author(s):  
Shounak Ray ◽  
Papu Biswas
2014 ◽  
Vol 4 (6) ◽  
pp. 1813-1819 ◽  
Author(s):  
Saidulu Ganji ◽  
Siva Sankar Enumula ◽  
Ravi Kumar Marella ◽  
Kamaraju Seetha Rama Rao ◽  
David Raju Burri

A RhNPs/SBA-NH2 catalyst with <3 nm sized nanoparticles has been synthesized and used in the chemoselective hydrogenation of nitroarenes at room temperature in aqueous medium with N2H4·H2O with high TOF.


2021 ◽  
Vol 10 (4) ◽  
pp. 2715-2721

A simple and one-pot protocol has been developed to synthesize bioactive 2-amino-4H-chromenes by using silver nanoparticles (AgNp) as a catalyst at room temperature in an aqueous medium. This method provides operational simplicity and an environment-friendly green approach. All the synthesized compounds were evaluated for antifungal activity against Alternaria alternata.


Biomolecules ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 299
Author(s):  
Reetika Singh ◽  
Christophe Hano ◽  
Gopal Nath ◽  
Bechan Sharma

Carissa carandas L. is traditionally used as antibacterial medicine and accumulates many antioxidant phytochemicals. Here, we expand this traditional usage with the green biosynthesis of silver nanoparticles (AgNPs) achieved using a Carissa carandas L. leaf extract as a reducing and capping agent. The green synthesis of AgNPs reaction was carried out using 1mM silver nitrate and leaf extract. The effect of temperature on the synthesis of AgNPs was examined using room temperature (25 °C) and 60 °C. The silver nanoparticles were formed in one hour by stirring at room temperature. In this case, a yellowish brown colour was developed. The successful formation of silver nanoparticles was confirmed by UV–Vis, Fourier transform infrared (FT-IR) and X-ray diffraction (XRD) analysis. The characteristic peaks of the UV-vis spectrum and XRD confirmed the synthesis of AgNPs. The biosynthesised AgNPs showed potential antioxidant activity through DPPH assay. These AgNPs also exhibited potential antibacterial activity against human pathogenic bacteria. The results were compared with the antioxidant and antibacterial activities of the plant extract, and clearly suggest that the green biosynthesized AgNPs can constitute an effective antioxidant and antibacterial agent.


RSC Advances ◽  
2021 ◽  
Vol 11 (24) ◽  
pp. 14624-14631
Author(s):  
Pablo Eduardo Cardoso-Avila ◽  
Rita Patakfalvi ◽  
Carlos Rodríguez-Pedroza ◽  
Xochitl Aparicio-Fernández ◽  
Sofía Loza-Cornejo ◽  
...  

Gold and silver nanoparticles were synthesized at room temperature using an aqueous extract from dried rosehips acting as reducing and capping agents with no other chemicals involved.


2015 ◽  
Vol 17 (3) ◽  
pp. 1867-1876 ◽  
Author(s):  
Shilpi Ghosh ◽  
Shankha S. Acharyya ◽  
Takehiko Sasaki ◽  
Rajaram Bal

Heterogeneous catalysts comprising silver nanoparticles supported on nanostructured tungsten oxide were applied for room temperature oxidative coupling of aniline to azoxybenzene, an important chemical intermediate and a chemical of industrial interest.


2017 ◽  
Vol 6 (5) ◽  
Author(s):  
Zahra Abbasi ◽  
Sholeh Feizi ◽  
Elham Taghipour ◽  
Parinaz Ghadam

AbstractSilver nanoparticles (AgNPs) have widespread applications. Recently, the synthesis of NPs using plant extract has attracted much attention. In this study, with an easy and rapid process at room temperature, AgNPs were produced by the aqueous extract of dried


RSC Advances ◽  
2016 ◽  
Vol 6 (27) ◽  
pp. 22320-22330 ◽  
Author(s):  
Nazia Kausar ◽  
Indranil Roy ◽  
Dipankar Chattopadhyay ◽  
Asish R. Das

Graphene oxide nanosheet catalyzed strategies for construction of 2,3-dihydroquinazolinones and quinazolin-4(3H)-ones starting from anthranilamide and an aldehyde/ketone in aqueous medium at room temperature have been realized.


2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
M. A. El-Sheikh

The water soluble photoinitiator (PI) 4-(trimethyl ammonium methyl) benzophenone chloride is used for the first time in the synthesis of silver nanoparticles (AgNPs). A new green synthesis method involves using PI/UV system, carboxymethyl starch (CMS), silver nitrate, and water. A mechanism of the reduction of silver ions to AgNPs by PI/UV system as well as by the newly born aldehydic groups was proposed. The synthesis process was assessed by UV-vis spectra and TEM of AgNPs colloidal solution. The highest absorbance was obtained using CMS, PI and AgNO3concentrations of 10 g/L, 1 g/L, and 1 g/L, respectively; 40°C; 60 min; pH 7; and a material : liquor ratio 1 : 20. AgNPs so-obtained were stable in aqueous solution over a period of three weeks at room temperature (~25°C) and have round shape morphology. The sizes of synthesized AgNPs were in the range of 1–21 nm and the highest counts % of these particles were for particles of 6–10 and 1–3 nm, respectively.


2018 ◽  
Vol 3 (46) ◽  
pp. 13197-13206 ◽  
Author(s):  
Bipin Shinde ◽  
Santosh B. Kamble ◽  
Dattaprasad M. Pore ◽  
Prasad Gosavi ◽  
Amol Gaikwad ◽  
...  

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