A strongly greenish-blue-emitting Cu4Cl4 cluster with an efficient spin–orbit coupling (SOC): fast phosphorescence versus thermally activated delayed fluorescence

2016 ◽  
Vol 52 (37) ◽  
pp. 6288-6291 ◽  
Author(s):  
Xu-Lin Chen ◽  
Rongmin Yu ◽  
Xiao-Yuan Wu ◽  
Dong Liang ◽  
Ji-Hui Jia ◽  
...  
Keyword(s):  
Decay Time ◽  
Delayed Fluorescence ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Greenish Blue

A novel greenish-blue-emitting Cu(i) complex with high PLQY of 90% and short decay time of 9.9 μs is reported. The emission at 293 K consists of approximately equivalent fast phosphorescence and TADF.

scholarly journals Correction: A strongly greenish-blue-emitting Cu4Cl4 cluster with an efficient spin–orbit coupling (SOC): fast phosphorescence versus thermally activated delayed fluorescence

2016 ◽  
Vol 52 (49) ◽  
pp. 7738-7738
Author(s):  
Xu-Lin Chen ◽  
Rongmin Yu ◽  
Xiao-Yuan Wu ◽  
Dong Liang ◽  
Ji-Hui Jia ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Greenish Blue

Correction for ‘A strongly greenish-blue-emitting Cu4Cl4 cluster with an efficient spin–orbit coupling (SOC): fast phosphorescence versus thermally activated delayed fluorescence’ by Xu-Lin Chen et al., Chem. Commun., 2016, 52, 6288–6291.

scholarly journals Thermally activated delayed fluorescence processes for Cu(i) complexes in solid-state: a computational study using quantitative prediction

RSC Advances ◽  
2018 ◽  
Vol 8 (50) ◽  
pp. 28421-28432 ◽  
Author(s):  
Lingling Lv ◽  
Kui Liu ◽  
Kun Yuan ◽  
Yuancheng Zhu ◽  
Yongcheng Wang
Keyword(s):  
Solid State ◽  
Rate Constants ◽  
Computational Study ◽  
Delayed Fluorescence ◽  
Orbit Coupling ◽  
Quantitative Prediction ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

Calculated fluorescence (kF), phosphorescence (kP), and ISC rate constants (kvib.ISC/RISC) with the vibronic spin–orbit coupling at 300 K for Cu(dppb)(pz2Bph2).

scholarly journals Thermally activated delayed fluorescence with a narrow emission spectrum and organic room temperature phosphorescence by controlling spin–orbit coupling and phosphorescence lifetime of metal-free organic molecules

2018 ◽  
Vol 6 (20) ◽  
pp. 5434-5443 ◽  
Author(s):  
Piotr Pander ◽  
Agnieszka Swist ◽  
Radoslaw Motyka ◽  
Jadwiga Soloducho ◽  
Fernando B. Dias ◽  
...  
Keyword(s):  
Room Temperature ◽  
Organic Molecules ◽  
Delayed Fluorescence ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Room Temperature Phosphorescence ◽  
Phosphorescence Lifetime ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Narrow Emission

A novel acridone derivative is presented showing TADF and narrow blue electroluminescence.

A unique tetranuclear Ag(i) complex emitting efficient thermally activated delayed fluorescence with a remarkably short decay time

2018 ◽  
Vol 47 (17) ◽  
pp. 5956-5960 ◽  
Author(s):  
Xue-Min Gan ◽  
Rongmin Yu ◽  
Xu-Lin Chen ◽  
MingXue Yang ◽  
Ling Lin ◽  
...  
Keyword(s):  
Decay Time ◽  
Delayed Fluorescence ◽  
Frontier Orbitals ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Highly Efficient ◽  
Metal Orbital

A novel emissive tetranuclear Ag(i) complex with highly efficient thermally activated delayed fluorescence (TADF) was successfully prepared and characterized. The significant participation of a metal orbital in the occupied frontier orbitals leads to dominant MLCT emission.

Reducing lifetime in Cu(i) complexes with thermally activated delayed fluorescence and phosphorescence promoted by chalcogenolate–diimine ligands

2020 ◽  
Vol 8 (41) ◽  
pp. 14595-14604
Author(s):  
Giliandro Farias ◽  
Cristian A. M. Salla ◽  
Renata S. Heying ◽  
Adailton J. Bortoluzzi ◽  
Sergio F. Curcio ◽  
...  
Keyword(s):  
Heavy Atom ◽  
Delayed Fluorescence ◽  
Spin Orbit Coupling ◽  
Matrix Elements ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Diimine Ligands ◽  
Photoluminescence Lifetime ◽  
Atom Effect ◽  
Fluorescence And Phosphorescence

Cu(i) complexes without the expected heavy atom effect to enhance the spin–orbit coupling matrix elements, but with reduced photoluminescence lifetime.

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