scholarly journals Adsorption of acrolein, propanal, and allyl alcohol on Pd(111): a combined infrared reflection–absorption spectroscopy and temperature programmed desorption study

2016 ◽  
Vol 18 (20) ◽  
pp. 13960-13973 ◽  
Author(s):  
Karl-Heinz Dostert ◽  
Casey P. O'Brien ◽  
Francesca Mirabella ◽  
Francisco Ivars-Barceló ◽  
Swetlana Schauermann

We present a mechanistic study on adsorption of acrolein and its partial hydrogenation products propanal and allyl alcohol over Pd(111) to understand the factors governing the selectivity in acrolein hydrogenation.

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