Evaluating topologically diverse metal–organic frameworks for cryo-adsorbed hydrogen storage

2016 ◽  
Vol 9 (10) ◽  
pp. 3279-3289 ◽  
Author(s):  
Diego A. Gómez-Gualdrón ◽  
Yamil J. Colón ◽  
Xu Zhang ◽  
Timothy C. Wang ◽  
Yu-Sheng Chen ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Adsorbed Hydrogen ◽  
Molecular Building Blocks ◽  
Metal Organic ◽  
Inorganic And Organic

Metal–organic frameworks (MOFs) are porous materials synthesized by combining inorganic and organic molecular building blocks into crystalline networks of distinct topologies.

scholarly journals Intrinsically porous molecular building blocks for metal organic frameworks tailored by the bridging effect of counter cations

CrystEngComm ◽  
2020 ◽  
Vol 22 (17) ◽  
pp. 2889-2894 ◽  
Author(s):  
Peng Yang ◽  
Buthainah Alshankiti ◽  
Niveen M. Khashab
Keyword(s):  
Porous Materials ◽  
Rational Design ◽  
Molecular Level ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Molecular Building Blocks ◽  
Metal Organic ◽  
Design And Construction

Intrinsically porous molecular building blocks are used for the rational design and construction of molecular-level controlled porous materials.

A Molecular Artisans Guide to Supramolecular Coordination Complexes and Metal Organic Frameworks

2015 ◽  
Vol 03 (01n02) ◽  
pp. 1540004 ◽  
Author(s):  
Xialu Wu ◽  
David J. Young ◽  
T. S. Andy Hor
Keyword(s):  
Chemical Reactivity ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Coordination Complexes ◽  
Large Molecules ◽  
Molecular Building Blocks ◽  
Supramolecular Coordination ◽  
Metal Organic ◽  
Molecular Synthesis ◽  
And Function

As molecular synthesis advances, we are beginning to learn control of not only the chemical reactivity (and function) of molecules, but also of their interactions with other molecules. It is this basic idea that has led to the current explosion of supramolecular science and engineering. Parallel to this development, chemists have been actively pursuing the design of very large molecules using basic molecular building blocks. Herein, we review the general development of supramolecular chemistry and particularly of two new branches: supramolecular coordination complexes (SCCs) and metal organic frameworks (MOFs). These two fields are discussed in detail with typical examples to illustrate what is now possible and what challenges lie ahead for tomorrow's molecular artisans.

3D Metal−Organic Frameworks Based on Elongated Tetracarboxylate Building Blocks for Hydrogen Storage

2008 ◽  
Vol 47 (10) ◽  
pp. 3955-3957 ◽  
Author(s):  
Liqing Ma ◽  
Jeong Yong Lee ◽  
Jing Li ◽  
Wenbin Lin
Keyword(s):  
Hydrogen Storage ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Metal Organic

Reticular Chemistry and Metal-Organic Frameworks for Clean Energy

MRS Bulletin ◽  
2009 ◽  
Vol 34 (9) ◽  
pp. 682-690 ◽  
Author(s):  
Omar M. Yaghi ◽  
Qiaowei Li
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Clean Energy ◽  
Building Blocks ◽  
Zeolitic Imidazolate Frameworks ◽  
Design Concepts ◽  
Surface Areas ◽  
Molecular Building Blocks ◽  
Metal Organic ◽  
Molecular Aspects

AbstractReticular chemistry concerns the linking of molecular building blocks into predetermined structures using strong bonds. We have been working on creating and developing the conceptual and practical basis of this new area of research. As a result, new classes of crystalline porous materials have been designed and synthesized: metal-organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks. Crystals of this type have exceptional surface areas (2,000−6,000 m2/g) and take up voluminous amounts of hydrogen (7.5 wt% at 77 K and 3−4 × 106 Pa), methane (50 wt% at 298 K and 2.5 × 106 Pa), and carbon dioxide (140 wt% at 298 K and 3 × 106 Pa). We have driven the basic science all the way to applications without losing sight of our quest for understanding the underlying molecular aspects of this chemistry. The presentation was focused on the design concepts, synthesis, and structure of these materials, with emphasis on their applications to onboard energy storage.

Remote Stabilization of Copper Paddlewheel Based Molecular Building Blocks in Metal–Organic Frameworks

2015 ◽  
Vol 27 (6) ◽  
pp. 2144-2151 ◽  
Author(s):  
Wen-Yang Gao ◽  
Rong Cai ◽  
Tony Pham ◽  
Katherine A. Forrest ◽  
Adam Hogan ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Molecular Building Blocks ◽  
Metal Organic

scholarly journals Energy-based descriptors to rapidly predict hydrogen storage in metal–organic frameworks

2019 ◽  
Vol 4 (1) ◽  
pp. 162-174 ◽  
Author(s):  
Benjamin J. Bucior ◽  
N. Scott Bobbitt ◽  
Timur Islamoglu ◽  
Subhadip Goswami ◽  
Arun Gopalan ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Regression Model ◽  
Porous Materials ◽  
Hydrogen Adsorption ◽  
Metal Organic Frameworks ◽  
New Energy ◽  
Metal Organic

A new, energy-based descriptor for porous materials is highly predictive for hydrogen adsorption using an interpretable regression model.

Assembly of Metal–Organic Frameworks (MOFs) Based on Indium-Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage

2007 ◽  
Vol 119 (18) ◽  
pp. 3342-3347 ◽  
Author(s):  
Yunling Liu ◽  
Jarrod F. Eubank ◽  
Amy J. Cairns ◽  
Juergen Eckert ◽  
Victor Ch. Kravtsov ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
High Hydrogen ◽  
Metal Organic

scholarly journals Redox Activity as a Powerful Strategy to Tune Magnetic and/or Conducting Properties in Benzoquinone-Based Metal-Organic Frameworks

2021 ◽  
Vol 7 (8) ◽  
pp. 109
Author(s):  
Noemi Monni ◽  
Mariangela Oggianu ◽  
Suchithra Ashoka Sahadevan ◽  
Maria Laura Mercuri
Keyword(s):  
Electrode Materials ◽  
Metal Organic Frameworks ◽  
Future Generation ◽  
Building Blocks ◽  
Redox Activity ◽  
Semiquinone Radical ◽  
Molecular Building Blocks ◽  
Redox Active ◽  
Metal Organic ◽  
Selection Of

Multifunctional molecular materials have attracted material scientists for several years as they are promising materials for the future generation of electronic devices. Careful selection of their molecular building blocks allows for the combination and/or even interplay of different physical properties in the same crystal lattice. Incorporation of redox activity in these networks is one of the most appealing and recent synthetic strategies used to enhance magnetic and/or conducting and/or optical properties. Quinone derivatives are excellent redox-active linkers, widely used for various applications such as electrode materials, flow batteries, pseudo-capacitors, etc. Quinones undergo a reversible two-electron redox reaction to form hydroquinone dianions via intermediate semiquinone radical formation. Moreover, the possibility to functionalize the six-membered ring of the quinone by various substituents/functional groups make them excellent molecular building blocks for the construction of multifunctional tunable metal-organic frameworks (MOFs). An overview of the recent advances on benzoquinone-based MOFs, with a particular focus on key examples where magnetic and/or conducting properties are tuned/switched, even simultaneously, by playing with redox activity, is herein envisioned.

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