Physicochemical and electrochemical properties of a new series of protic ionic liquids with N-chloroalkyl functionalized cations

RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 55144-55158 ◽  
Author(s):  
B. Gorska ◽  
L. Timperman ◽  
M. Anouti ◽  
J. Pernak ◽  
F. Béguin
Keyword(s):  
Ionic Liquids ◽  
Electrochemical Properties ◽  
Metathesis Reaction ◽  
Protic Ionic Liquids ◽  
Counter Ion

Six new protic ionic liquids (PILs) based on N-chloroalkyl functionalized morpholinium, piperidinium, pyrrolidinium and alkylammonium cations, with bis[(trifluoromethyl)sulfonyl]imide as counter-ion, were synthesized by a metathesis reaction.

Thermal and Electrochemical Properties of Protic Ionic Liquids and their Binary Mixtures with Water

2019 ◽  
Vol 15 ◽  
pp. 498-503
Author(s):  
Md. Shahriar Hasan Saikat ◽  
Md. Mominul Islam ◽  
M. Yousuf A. Mollah ◽  
Md. Abu Bin Hasan Susan ◽  
Muhammed Shah Miran
Keyword(s):  
Ionic Liquids ◽  
Electrochemical Properties ◽  
Binary Mixtures ◽  
Protic Ionic Liquids

Electrochemical properties of protic ionic liquids: correlation between open circuit potential for H2/O2 cells under non-humidified conditions and ΔpKa

RSC Advances ◽  
2013 ◽  
Vol 3 (13) ◽  
pp. 4141 ◽  
Author(s):  
Muhammed Shah Miran ◽  
Tomohiro Yasuda ◽  
Md. Abu Bin Hasan Susan ◽  
Kaoru Dokko ◽  
Masayoshi Watanabe
Keyword(s):  
Ionic Liquids ◽  
Electrochemical Properties ◽  
Open Circuit Potential ◽  
Open Circuit ◽  
Protic Ionic Liquids

(Keynote) Protic Ionic Liquids Based on a Super-Strong Acid: Bulk and Electrochemical Properties

2013 ◽  
Vol 50 (11) ◽  
pp. 285-291 ◽  
Author(s):  
M. S. Miran ◽  
T. Yasuda ◽  
M. A. B. H. Susan ◽  
K. Dokko ◽  
M. Watanabe
Keyword(s):  
Ionic Liquids ◽  
Electrochemical Properties ◽  
Strong Acid ◽  
Protic Ionic Liquids

scholarly journals Hydroxyl Functionalized Pyridinium Ionic Liquids: Experimental and Theoretical Study on Physicochemical and Electrochemical Properties

2019 ◽  
Vol 7 ◽  
Author(s):  
Kallidanthiyil Chellappan Lethesh ◽  
Sigvart Evjen ◽  
Jaganathan Joshua Raj ◽  
Denis C. D. Roux ◽  
Vishwesh Venkatraman ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Electrochemical Properties ◽  
Theoretical Study

DFT Study on the Chemical Absorption Mechanism of CO2 in Diamino Protic Ionic Liquids

2021 ◽  
Vol 125 (5) ◽  
pp. 1416-1428
Author(s):  
Jing Ma ◽  
Yutong Wang ◽  
Xueqing Yang ◽  
Mingxuan Zhu ◽  
Baohe Wang
Keyword(s):  
Ionic Liquids ◽  
Dft Study ◽  
Protic Ionic Liquids ◽  
Absorption Mechanism ◽  
Chemical Absorption

scholarly journals The Synthesis of Poly(Vinyl Alcohol) Grafted with Fluorinated Protic Ionic Liquids Containing Sulfo Functional Groups

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4158
Author(s):  
Patrycja Glińska ◽  
Andrzej Wolan ◽  
Wojciech Kujawski ◽  
Edyta Rynkowska ◽  
Joanna Kujawa
Keyword(s):  
Ionic Liquids ◽  
Vinyl Alcohol ◽  
Proton Exchange ◽  
Polymer Materials ◽  
Polymerization Reaction ◽  
Poly Vinyl Alcohol ◽  
Hydroxyl Groups ◽  
Protic Ionic Liquids ◽  
Synthesis Route ◽  
Sulfo Groups

There has been an ongoing need to develop polymer materials with increased performance as proton exchange membranes (PEMs) for middle- and high-temperature fuel cells. Poly(vinyl alcohol) (PVA) is a highly hydrophilic and chemically stable polymer bearing hydroxyl groups, which can be further altered. Protic ionic liquids (proticILs) have been found to be an effective modifying polymer agent used as a proton carrier providing PEMs’ desirable proton conductivity at high temperatures and under anhydrous conditions. In this study, the novel synthesis route of PVA grafted with fluorinated protic ionic liquids bearing sulfo groups (–SO3H) was elaborated. The polymer functionalization with fluorinated proticILs was achieved by the following approaches: (i) the PVA acylation and subsequent reaction with fluorinated sultones and (ii) free-radical polymerization reaction of vinyl acetate derivatives modified with 1-methylimidazole and sultones. These modifications resulted in the PVA being chemically modified with ionic liquids of protic character. The successfully grafted PVA has been characterized using 1H, 19F, and 13C-NMR and FTIR-ATR. The presented synthesis route is a novel approach to PVA functionalization with imidazole-based fluorinated ionic liquids with sulfo groups.

Development of a robust soft-SAFT model for protic ionic liquids using new high-pressure density data

2021 ◽  
pp. 113036
Author(s):  
Emanuel A. Crespo ◽  
Liliana P. Silva ◽  
Cristina I.P. Correia ◽  
Mónia A.R. Martins ◽  
Ramesh L. Gardas ◽  
...  
Keyword(s):  
High Pressure ◽  
Ionic Liquids ◽  
Protic Ionic Liquids ◽  
Density Data

Insights into the translational and rotational dynamics of cations and anions in protic ionic liquids by means of NMR fast-field-cycling relaxometry

2021 ◽  
Vol 23 (4) ◽  
pp. 2663-2675
Author(s):  
Viviane Overbeck ◽  
Henning Schröder ◽  
Anne-Marie Bonsa ◽  
Klaus Neymeyr ◽  
Ralf Ludwig
Keyword(s):  
Ionic Liquids ◽  
Rotational Dynamics ◽  
Protic Ionic Liquids ◽  
Field Cycling ◽  
Fast Field ◽  
Hydrogen Bonded

NMR Fast-Field-Cycling (FFC) relaxometry provides important information about translational and rotational dynamics of hydrogen bonded protic ionic liquids (PILs). 

scholarly journals Electrochemical properties of positive electrode in lead-acid battery modified by ammonium-based ionic liquids

2017 ◽  
Vol 22 (3) ◽  
pp. 919-930 ◽  
Author(s):  
Agnieszka Gabryelczyk ◽  
Kacper Kopczyński ◽  
Marek Baraniak ◽  
Bartosz Łęgosz ◽  
Filip Walkiewicz ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Electrochemical Properties ◽  
Positive Electrode ◽  
Lead Acid Battery ◽  
Lead Acid
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