Atomic level changes during capacity fade in highly oriented thin films of cathode material LiCoPO4

High-quality thin films of cathode material LiCoPO4 are analyzed using a combination of STEM-EELS, XRD, and atomistic simulations. Capacity fade during cycling is accompanied by formation of large numbers of cation exchange defects, especially at surfaces, blocking the preferred Li-ion migration pathways.

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Ab initio calculations on Li-ion migration in Li2FeSiO4 cathode material with a P21 symmetry structure

Applied Physics Letters ◽

10.1063/1.3645617 ◽

2011 ◽

Vol 99 (14) ◽

pp. 141909 ◽

Cited By ~ 27

Author(s):

Dawei Su ◽

Hyojun Ahn ◽

Guoxiu Wang

Keyword(s):

Cathode Material ◽

Ab Initio Calculations ◽

Ab Initio ◽

Ion Migration ◽

Li Ion ◽

Symmetry Structure

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Effect of ultrasonic irradiation on structure and electrochemical properties of LiMn2O4 thin films cathode material for Li-ion micro-batteries

Solid State Ionics ◽

10.1016/j.ssi.2010.06.046 ◽

2011 ◽

Vol 192 (1) ◽

pp. 339-342 ◽

Cited By ~ 5

Author(s):

Haixia Liang ◽

Xuan Zhao ◽

Zhiyong Yu ◽

Minghe Cao ◽

Hanxing Liu

Keyword(s):

Thin Films ◽

Cathode Material ◽

Electrochemical Properties ◽

Ultrasonic Irradiation ◽

Limn2o4 Thin Films ◽

Li Ion

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Capacity Fade Study of LiCo0.4Al0.1Mn1.5O4 Cathode Material for Li-Ion Batteries Cycled at Low Discharge Rates

Journal of Advanced Chemical Engineering ◽

10.4172/2090-4568.1000127 ◽

2015 ◽

Vol 5 (3) ◽

Author(s):

Pai KV

Keyword(s):

Cathode Material ◽

Capacity Fade ◽

Li Ion Batteries ◽

Discharge Rates ◽

Li Ion

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Atomic layer deposition of transparent semiconducting oxide CuCrO2 thin films

Journal of Materials Chemistry C ◽

10.1039/c5tc01384d ◽

2015 ◽

Vol 3 (32) ◽

pp. 8364-8371 ◽

Cited By ~ 24

Author(s):

T. S. Tripathi ◽

Janne-Petteri Niemelä ◽

Maarit Karppinen

Keyword(s):

Thin Films ◽

Reaction Mechanism ◽

Atomic Layer Deposition ◽

Gas Phase ◽

Surface Reaction ◽

Atomic Layer ◽

Atomic Level ◽

High Quality ◽

Layer Deposition ◽

Controlled Deposition

Atomic layer deposition (ALD) is a vital gas-phase technique for atomic-level thickness-controlled deposition of high-quality thin films of CuCrO2 on various substrate morphologies owing to its self-limiting gas-surface reaction mechanism.

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Crystal Structure Revision and Identification of Li+-Ion Migration Pathways in the Garnet-like Li5La3M2O12(M = Nb, Ta) Oxides

Chemistry of Materials ◽

10.1021/cm031176d ◽

2004 ◽

Vol 16 (16) ◽

pp. 2998-3006 ◽

Cited By ~ 122

Author(s):

Venkataraman Thangadurai ◽

Stefan Adams ◽

Werner Weppner

Keyword(s):

Crystal Structure ◽

Ion Migration ◽

Structure Revision ◽

Li Ion ◽

Migration Pathways

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Electronic charge density as a fast approach for predicting Li-ion migration pathways in superionic conductors with first-principles level precision

Computational Materials Science ◽

10.1016/j.commatsci.2021.110380 ◽

2021 ◽

Vol 192 ◽

pp. 110380

Author(s):

Yinqiao Liu ◽

Xue Jiang ◽

Jijun Zhao ◽

Ming Hu

Keyword(s):

Charge Density ◽

First Principles ◽

Superionic Conductors ◽

Electronic Charge ◽

Electronic Charge Density ◽

Ion Migration ◽

Fast Approach ◽

Li Ion ◽

Migration Pathways

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Chemo-mechanical degradation in V2O5 thin film cathodes of Li-ion batteries during electrochemical cycling

Journal of Materials Chemistry A ◽

10.1039/c9ta05243g ◽

2019 ◽

Vol 7 (41) ◽

pp. 23922-23930 ◽

Cited By ~ 7

Author(s):

Yuwei Zhang ◽

Yuting Luo ◽

Cole Fincher ◽

Sarbajit Banerjee ◽

Matt Pharr

Keyword(s):

Thin Film ◽

Thin Films ◽

Mechanical Degradation ◽

Capacity Fade ◽

Li Ion Batteries ◽

Root Cause ◽

Electrochemical Cycling ◽

Li Ion

We have devised an approach to fabricate dense textured V2O5 thin films, which allows us to scrutinize the root cause of capacity fade in V2O5 cathodes of Li-ion batteries.

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