Water mediated proton conductance in a hydrogen-bonded Ni(ii)-bipyridine-glycoluril chloride self-assembled framework

CrystEngComm ◽  
2018 ◽  
Vol 20 (8) ◽  
pp. 1094-1100 ◽  
Author(s):  
Sakharam B. Tayade ◽  
Satish S. Bhat ◽  
Rajith Illathvalappil ◽  
Vishal M. Dhavale ◽  
Vitthal A. Kawade ◽  
...  
Keyword(s):  
Proton Conductance ◽  
Proton Conducting ◽  
Porous Framework ◽  
Self Assembled ◽  
Hydrogen Bonded

Proton conducting properties have been investigated in a new Ni(ii)-based hydrogen-bonded porous framework synthesized using bipyridine-glycoluril (BPG) tecton.

Selectivity of guest–host interactions in self-assembled hydrogen-bonded nanostructures observed by NMR

2007 ◽  
Vol 9 (32) ◽  
pp. 4545 ◽  
Author(s):  
Gunther Brunklaus ◽  
Achim Koch ◽  
Daniel Sebastiani ◽  
Hans Wolfgang Spiess
Keyword(s):  
Host Interactions ◽  
Self Assembled ◽  
Hydrogen Bonded

Proton-Conducting Hydrogen-Bonded Organic Frameworks

2021 ◽  
pp. 4431-4453
Author(s):  
Shyam Chand Pal ◽  
Debolina Mukherjee ◽  
Rupam Sahoo ◽  
Supriya Mondal ◽  
Madhab C. Das
Keyword(s):  
Proton Conducting ◽  
Hydrogen Bonded

scholarly journals Synthesis and design of laboratory device from proton conducting block copolymer membrane

BIBECHANA ◽  
2012 ◽  
Vol 9 ◽  
pp. 50-58
Author(s):  
Shankar P Khatiwada ◽  
Amar P Yadav ◽  
Werner Lebek ◽  
Jean Marc Saiter ◽  
Rameshwar Adhikari
Keyword(s):  
Electron Microscopy ◽  
Atomic Force Microscopy ◽  
Fourier Transform ◽  
Block Copolymer ◽  
Triblock Copolymer ◽  
Proton Conductance ◽  
Proton Conducting ◽  
Force Microscopy ◽  
Atomic Force ◽  
Laboratory Device

The butadiene units of polystyrene-block-polybutadiene-block-polystyrene (SBS) triblock copolymer were subjected to epoxidation and subsequent sulphonation in order to prepare proton conducting ionomer membrane. The products were characterized by different techniques such as atomic force microscopy, Fourier transform infrared (FTIR) spectroscopy and electron microscopy. A simple laboratory device was developed to carry out the tests on proton conductance ability of the prepared ionomer membrane. The experiments demonstrated that the prepared membrane excellently performed as proton conducting membrane. DOI: http://dx.doi.org/10.3126/bibechana.v9i0.7174 BIBECHANA 9 (2013) 50-58

Synthesis and Crystal Structure of [(CH2)6N4CH3]2[CoCl4]

2002 ◽  
Vol 55 (9) ◽  
pp. 561 ◽  
Author(s):  
W. Li ◽  
S.-L. Zheng ◽  
C.-R. Zhu ◽  
Y.-X. Tong ◽  
X.-M. Chen
Keyword(s):  
Crystal Structure ◽  
Nitrogen Atom ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Chlorine Atoms ◽  
Synthesis And Crystal Structure ◽  
Methylene Groups ◽  
Self Assembled ◽  
Hydrogen Bonded

The interesting three-dimensional hydrogen-bonded self-assembled network of [(CH2)6N4CH3]+ cations and [CoCl4]2– anions has been prepared and structurally characterized. In the title complex, the quaternization of one hexamethylenetetramine nitrogen atom has been trapped, and further stabilized by the large [CoCl4]2– anions, featuring C–H���Cl hydrogen bonds (3.497–3.709 �) between the methylene groups of [(CH2)6N4CH3]+ cations and the chlorine atoms of the [CoCl4]2– anions.

Strategies for Crystal Engineering of Polar Solids

1993 ◽  
Vol 328 ◽  
Author(s):  
Mike Zaworotko ◽  
S. Subramanian ◽  
L. R. Macgillivray
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Crystal Engineering ◽  
Organic Cation ◽  
Polar Materials ◽  
Structural Analogues ◽  
Cubane Cluster ◽  
Self Assembled ◽  
Hydrogen Bonded

ABSTRACTCrystal engineering has been invoked to design structural analogues of two prototypal SHG active solids, p-nitroaniline (pNA) and potassium dihydrogenphosphate (KDP). pNA exists as linear polar strands because of head-to-tail hydrogen bonding between adjacent molecules whereas KDP is a self-assembled hydrogen bonded diamondoid network that becomes polar when the hydrogen bonds align. We detail preparation and crystallographic characterization of two classes of multicomponent solid, organic cation hydrogen sulfates and cocrystals of the cubane cluster [M (CO)3(μ3-OH)]4, which structurally mimic pNA and KDP, respectively. Several of the Multi-component solids are polar and they represent a generic approach to designing new polar materials since one component can be changed without altering the basic architecture within the crystal.

Synthesis and proton-conducting performance of crystalline hydrogen-bonded organic networks

2020 ◽  
Vol 290 ◽  
pp. 121550
Author(s):  
Mei-Jie Wei ◽  
Bo Li ◽  
Heng-Ye Li ◽  
Lin Zhang ◽  
Yu-Ting Luo ◽  
...  
Keyword(s):  
Proton Conducting ◽  
Organic Networks ◽  
Hydrogen Bonded

Proton Conducting Self-Assembled Metal–Organic Framework/Polyelectrolyte Hollow Hybrid Nanostructures

2016 ◽  
Vol 8 (35) ◽  
pp. 23015-23021 ◽  
Author(s):  
Unal Sen ◽  
Mustafa Erkartal ◽  
Chung-Wei Kung ◽  
Vijay Ramani ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Hybrid Nanostructures ◽  
Proton Conducting ◽  
Metal Organic ◽  
Self Assembled ◽  
Organic Framework

Self-Assembled Nanoparticles Formed via Complementary Nucleobase Pair Interactions between Drugs and Nanocarriers for Highly Efficient Tumor-Selective Chemotherapy

2021 ◽  
Author(s):  
Fasih Bintang Ilhami ◽  
Ai Chung ◽  
Yihalem Abebe Alemayehu ◽  
Ai-Wei Lee ◽  
Jemkun Chen ◽  
...  
Keyword(s):  
Drug Carrier ◽  
Highly Efficient ◽  
Construction Of Self ◽  
Self Assembled ◽  
Selective Chemotherapy ◽  
Carrier Systems ◽  
Drug Carrier Systems ◽  
Tumor Selective ◽  
Pair Interactions ◽  
Hydrogen Bonded

We report a significant breakthrough in the development of complementary hydrogen-bonded drug-carrier systems, namely the construction of self-assembled nanoparticles with desirable functionalities conferred by the presence of stable complementary uracil–adenine...

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