Reaction of H + HONO in solid para-hydrogen: infrared spectrum of ˙ONH(OH)

Hydrogenation reactions in the N/O chemical network are important for an understanding of the mechanism of formation of organic molecules in dark interstellar clouds, but many reactions remain unknown.

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INFRARED SPECTRUM OF (Z)-3-IODO-BUT-2-EN-1-YL [ï¿½ CH2CHC(CH3)I] PRODUCED UPON PHOTODISSOCIATION OF (Z)-1,3-DIIODO-BUT-2-ENE [(CH2I) HC=C(CH3)I] IN SOLID PARA-HYDROGEN

Proceedings of the 74th International Symposium on Molecular Spectroscopy ◽

10.15278/isms.2019.td03 ◽

2019 ◽

Author(s):

Yuan-Pern Lee ◽

Karolina Haupa

Keyword(s):

Infrared Spectrum ◽

Para Hydrogen

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State-of-the-Art Thermochemical and Kinetic Computations for Astrochemical Complex Organic Molecules: Formamide Formation in Cold Interstellar Clouds as a Case Study

Journal of Chemical Theory and Computation ◽

10.1021/acs.jctc.6b00379 ◽

2016 ◽

Vol 12 (11) ◽

pp. 5385-5397 ◽

Cited By ~ 32

Author(s):

Fanny Vazart ◽

Danilo Calderini ◽

Cristina Puzzarini ◽

Dimitrios Skouteris ◽

Vincenzo Barone

Keyword(s):

Organic Molecules ◽

State Of The Art ◽

Interstellar Clouds ◽

Complex Organic

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Models of gas-grain chemistry in dense interstellar clouds with complex organic molecules

The Astrophysical Journal Supplement Series ◽

10.1086/191713 ◽

1992 ◽

Vol 82 ◽

pp. 167 ◽

Cited By ~ 526

Author(s):

Tatsuhiko I. Hasegawa ◽

Eric Herbst ◽

Chun M. Leukng

Keyword(s):

Organic Molecules ◽

Interstellar Clouds ◽

Complex Organic

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Mechanochemistry for sustainable, efficient dehydrogenation/hydrogenation

Canadian Journal of Chemistry ◽

10.1139/cjc-2020-0408 ◽

2020 ◽

Author(s):

Blaine G. Fiss ◽

Austin James Richard ◽

Tomislav Friscic ◽

Audrey Moores

Keyword(s):

Ball Milling ◽

Chemical Industry ◽

Organic Molecules ◽

Solvent Free ◽

Chemical Transformations ◽

Triple Bonds ◽

Bulk Chemicals ◽

Challenges And Opportunities ◽

Hydrogenation Reactions ◽

Solution Routes

Hydrogenation reactions are one of the pillars of the chemical industry, with applications from bulk chemicals to pharmaceuticals manufacturing. The ability to selectively add hydrogen across double and/or triple bonds is key in the chemist’s toolbox, and the enabling component in the development of sustainable processes. Traditional solution-based approaches to hydrogenation reactions are tainted by significant consumption of energy and production of solvent waste. This review highlights the development and applications of recently emerged solvent-free approaches to conduct the hydrogenation of organic molecules using mechanochemistry, i.e. chemical transformations induced or sustained by mechanical force. In particular, we will show how mechanochemical techniques such as ball-milling enable catalytic or stoichiometric metal-mediated hydrogenation reactions that are simple, fast, and are conducted under significantly milder conditions compared to traditional solution routes. Importantly, we highlight the current challenges and opportunities in this field, while also identifying exciting cases in which mechanochemical hydrogenation strategies lead to new, unique targets and reactivity.

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THE INFRARED SPECTRUM OF PROTONATED OVALENE IN SOLID PARA-HYDROGEN AND ITS POSSIBLE CONTRIBUTION TO INTERSTELLAR UNIDENTIFIED INFRARED EMISSION

The Astrophysical Journal ◽

10.3847/0004-637x/825/2/96 ◽

2016 ◽

Vol 825 (2) ◽

pp. 96 ◽

Cited By ~ 15

Author(s):

Masashi Tsuge ◽

Mohammed Bahou ◽

Yu-Jong Wu ◽

Louis Allamandola ◽

Yuan-Pern Lee

Keyword(s):

Infrared Spectrum ◽

Infrared Emission ◽

Para Hydrogen

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THE INTERACTION OF FRIEDEL–CRAFTS CATALYSTS WITH ORGANIC MOLECULES: II. BORON TRIFLUORIDE WITH BENZOIC ANHYDRIDE

Canadian Journal of Chemistry ◽

10.1139/v62-071 ◽

1962 ◽

Vol 40 (3) ◽

pp. 445-448 ◽

Cited By ~ 8

Author(s):

Denys Cook

Keyword(s):

Infrared Spectrum ◽

Boron Trifluoride ◽

Organic Molecules ◽

Carbonyl Groups ◽

Benzoic Anhydride

The complex of boron trifluoride with benzoic anhydride has been prepared. One molecule of anhydride coordinates three molecules of boron trifluoride. The infrared spectrum shows that coordination takes place at the carbonyl groups, whose frequency is lowered some 200 cm−1. There is no trace of the benzoylium cation, C6H5O+. Although the spectra are complex, tentative assignments are made.

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Hydrogen abstraction in astrochemistry: formation of ˙CH2CONH2 in the reaction of H atom with acetamide (CH3CONH2) and photolysis of ˙CH2CONH2 to form ketene (CH2CO) in solid para-hydrogen

Physical Chemistry Chemical Physics ◽

10.1039/c9cp06279c ◽

2020 ◽

Vol 22 (11) ◽

pp. 6192-6201 ◽

Cited By ~ 3

Author(s):

Karolina Anna Haupa ◽

Wei-Siong Ong ◽

Yuan-Pern Lee

Keyword(s):

Organic Molecules ◽

Hydrogen Abstraction ◽

Amide Bond ◽

Para Hydrogen ◽

Hydrogen Exposure ◽

Complex Organic

The amide bond of acetamide is unaffected by hydrogen exposure, but the hydrogen abstraction on its methyl site activates this molecule to react with other species to extend its size as a first step to form interstellar complex organic molecules.

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