scholarly journals Charge-transfer and impulsive electronic-to-vibrational energy conversion in ferricyanide: ultrafast photoelectron and transient infrared studies

2017 ◽  
Vol 19 (26) ◽  
pp. 17052-17062 ◽  
Author(s):  
José Ojeda ◽  
Christopher A. Arrell ◽  
Luca Longetti ◽  
Majed Chergui ◽  
Jan Helbing

The photophysics of ferricyanide in H2O, D2O and ethylene glycol was studied upon excitation of ligand-to-metal charge transfer (LMCT) transitions by combining ultrafast photoelectron spectroscopy (PES) of liquids and transient vibrational spectroscopy.




2021 ◽  
Author(s):  
Qing-Dou Xu ◽  
Chen Zeng ◽  
Shao-Dong Su ◽  
Yu-Ying Yang ◽  
Sheng-Min Hu ◽  
...  

This work shows that the energy of MMCT in cyanidometal-bridged complexes can be tuned systematically by changing the auxiliary ligand of the cyanidometal bridge.





2017 ◽  
Vol 46 (38) ◽  
pp. 12964-12970 ◽  
Author(s):  
Jishi Chen ◽  
Yanze Pan ◽  
Zonghua Wang ◽  
Peng Zhao

A series of tiara like structural Pdn(SR)2n (5 ≤ n ≤ 20) nanoclusters exhibit emission at 620 nm with excitation at around 268 nm. Their emission is due to ligand to metal charge transfer.







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