Color Tuning in Garnet Oxides: The Role of Tetrahedral Coordination Geometry for 3 d Metal Ions and Ligand-Metal Charge Transfer (Band-Gap Manipulation)

Ligand-to-metal charge transfer, orbital-mixing, chelatoaromatic effect and topological constraints control the binding of lanthanide and actinide ions to hydroxypyridinone-based decorporation agents.

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Picosecond to Nanosecond Manipulation of Excited-State Lifetimes in Complexes with an FeII to TiIV Metal-to-Metal Charge Transfer: The Role of Ferrocene Centered Excited States

Inorganic Chemistry ◽

10.1021/acs.inorgchem.9b02316 ◽

2019 ◽

Vol 58 (22) ◽

pp. 15320-15329 ◽

Cited By ~ 1

Author(s):

Maksim Y. Livshits ◽

Michael D. Turlington ◽

Carl O. Trindle ◽

Lei Wang ◽

Zikri Altun ◽

...

Keyword(s):

Excited State ◽

Charge Transfer ◽

Excited States ◽

Metal Charge ◽

Excited State Lifetimes ◽

Metal Charge Transfer

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Metal-to-metal charge transfer band position control and luminescence quenching by cationic substitution in NaNbO3:Pr3+

10.1117/12.2253177 ◽

2017 ◽

Cited By ~ 2

Author(s):

V. Castaing ◽

L. Li ◽

D. Rytz ◽

Y. Katayama ◽

A. D. Sontakke ◽

...

Keyword(s):

Charge Transfer ◽

Position Control ◽

Charge Transfer Band ◽

Luminescence Quenching ◽

Metal Charge ◽

Band Position ◽

Cationic Substitution ◽

Metal Charge Transfer

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Role of Ligand-to-Metal Charge Transfer in O3-Type NaFeO2–NaNiO2Solid Solution for Enhanced Electrochemical Properties

The Journal of Physical Chemistry C ◽

10.1021/jp411382r ◽

2014 ◽

Vol 118 (6) ◽

pp. 2970-2976 ◽

Cited By ~ 91

Author(s):

Xianfen Wang ◽

Guandong Liu ◽

Tatsumi Iwao ◽

Masashi Okubo ◽

Atsuo Yamada

Keyword(s):

Charge Transfer ◽

Electrochemical Properties ◽

Metal Charge ◽

Metal Charge Transfer

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The role of ligand to metal charge-transfer states on the luminescence of Europium complexes with 18-membered macrocyclic ligands

Dalton Transactions ◽

10.1039/c8dt05005h ◽

2019 ◽

Vol 48 (12) ◽

pp. 4035-4045 ◽

Cited By ~ 9

Author(s):

Aline Nonat ◽

David Esteban-Gómez ◽

Laura Valencia ◽

Paulo Pérez-Lourido ◽

José Luis Barriada ◽

...

Keyword(s):

Charge Transfer ◽

Macrocyclic Ligands ◽

Macrocyclic Complexes ◽

Europium Complexes ◽

Metal Charge ◽

Divalent Europium ◽

Metal Charge Transfer

The stabilization of a divalent Europium provides an efficient pathway for the quenching of the luminescence in ten-coordinate macrocyclic complexes.

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Complexes of the Early Transition Metals with o-Mercaptophenol and 1,2-Dihydroxybenzene

Canadian Journal of Chemistry ◽

10.1139/v75-079 ◽

1975 ◽

Vol 53 (4) ◽

pp. 572-577 ◽

Cited By ~ 11

Author(s):

Joel L. Martin ◽

Josef Takats

Keyword(s):

Charge Transfer ◽

Transition Metals ◽

Synthetic Approach ◽

Coordination Geometry ◽

Metal Charge ◽

Visible Spectra ◽

Derivatives Of ◽

Metal Charge Transfer ◽

Early Transition

A novel synthetic approach, based on the reactivity of amido derivatives of the transition metals, M(NR2)x, towards protic reagents, for the synthesis of complexes of Ti, Zr, Hf, Nb, and Ta with o-mercaptophenol and 1,2-dihydroxybenzene is reported. The complexes, isolated as their tetraalkylammonium and tetraphenylarsonium salts, are moderately air stable, well behaved 2:1 (Ti, Zr, Hf) and 1:1 (Nb, Ta) electrolytes. The u. v.–visible spectra of the complexes, which are somewhat reminiscent of the corresponding benzene-1,2-dithiolates, are dominated by ligand-to-metal charge transfer bands. The band positions change in the expected manner, hypsochromic shifts in the order C6H4S22− < C6H4SO2− < C6H4O22− for a given metal and Ti < Zr ∼ Hf, Nb < Ta, Nb < Zr for a given ligand. lt is argued that these spectral resemblances could be a possible indication of variations in coordination geometry of the reported complexes similar to the ones found in compounds of benzene-1,2-dithiol.

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