Microwave-assisted MgO NP catalyzed one-pot multicomponent synthesis of polysubstituted steroidal pyridines

2018 ◽  
Vol 42 (1) ◽  
pp. 184-197 ◽  
Author(s):  
Anam Ansari ◽  
Abad Ali ◽  
Mohd Asif ◽  
Shamsuzzaman Shamsuzzaman

MgO NPs were proved to be a highly efficient catalyst for mild and clean conversion of steroids to steroidal heterocycles.

Author(s):  
Kahdijah S. Alghamdi ◽  
Nesreen S.I. Ahmed ◽  
D. Bakhotmah ◽  
Mohamed Mokhtar

Chitosan decorated copper nanoparticles catalysts (CSCuNPs) were synthesized via reduction methods utilizing green protocol. The CSCuNPs catalysts were tested for the synthesis of quinoline derivatives utilizing one-pot multicomponent reaction (MCR) under ultrasonic irradiation. The best catalyst (Cu-CS-NPs) that provided good conversion reaction yield and high turnover frequency (TOF) was characterized using FTIR, TGA, XRD, TEM and XPS techniques. Generalization of the scope of the proposed catalytic process was studied using different aldehydes. Excellent products yield and high TOF in even shorter reaction time (~5 min) was attained. Recyclability performance of the catalyst over five times re-use without detectable loss in product yield was recorded. The current method is green process utilizing environmentally benign catalyst and considered to be promising sustainable protocol for the synthesis of fine chemicals.


ChemInform ◽  
2006 ◽  
Vol 37 (48) ◽  
Author(s):  
Biswanath Das ◽  
K. Ravinder Reddy ◽  
R. Ramu ◽  
P. Thirupathi ◽  
B. Ravikanth

2020 ◽  
Vol 7 (1) ◽  
pp. 82-90 ◽  
Author(s):  
Xiao Chen ◽  
Shuhua Han ◽  
Dongdong Yin ◽  
Changhai Liang

For the one-pot reductive amination of benzaldehyde with nitrobenzene, intermetallic Ni2Si/SiCN from the decomposition of a nickel-modified polysilazane precursor exhibited high activity (>99%) and high selectivity (92% to aromatic amine).


2018 ◽  
Vol 32 (4) ◽  
pp. e4235 ◽  
Author(s):  
Seyedeh Fatemeh Hojati ◽  
Amirhassan Amiri ◽  
Nasrin MoeiniEghbali ◽  
Sakineh Mohamadi

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