Block co-polyMOFs: assembly of polymer–polyMOF hybrids via iterative exponential growth and “click” chemistry

Photoanodes comprising a transparent glass substrate coated with a thin conductive film of fluorine-doped tin oxide (FTO) and a thin layer of a photoactive phase have been fabricated and tested with regard to the photo-electro-oxidation of water into molecular oxygen. The photoactive layer was made of a mat of TiO2 nanorods (TDNRs) of micrometric thickness. Individual nanorods were successfully photosensitized with nanoparticles of a metal–organic framework (MOF) of nickel and 1,2-benzene dicarboxylic acid (BDCA). Detailed microstructural information was obtained from SEM and TEM analysis. The chemical composition of the active layer was determined by XRD, XPS and FTIR analysis. Optical properties were determined by UV–Vis spectroscopy. The water photooxidation activity was evaluated by linear sweep voltammetry and the robustness was assessed by chrono-amperometry. The OER (oxygen evolution reaction) photo-activity of these photoelectrodes was found to be directly related to the amount of MOF deposited on the TiO2 nanorods, and was therefore maximized by adjusting the MOF content. The microscopic reaction mechanism which controls the photoactivity of these photoelectrodes was analyzed by photo-electrochemical impedance spectroscopy. Microscopic rate parameters are reported. These results contribute to the development and characterization of MOF-sensitized OER photoanodes.

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Apoptosis Activity of 1,2,-Benzene Dicarboxylic Acid Isolated from Andrographis paniculata on KB, SiHa and IMR Cancer Cell Line

Drug Development for Cancer and Diabetes ◽

10.1201/9780429330490-11 ◽

2020 ◽

pp. 129-139

Author(s):

P. Krishnamoorthy ◽

D. Kalaiselvan

Keyword(s):

Dicarboxylic Acid ◽

Cell Line ◽

Cancer Cell ◽

Cancer Cell Line ◽

Andrographis Paniculata ◽

Benzene Dicarboxylic Acid

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Stacked nano rods of cobalt and nickel based metal organic frame work of 2–amino benzene dicarboxylic acid for photocatalytic hydrogen generation

International Journal of Hydrogen Energy ◽

10.1016/j.ijhydene.2020.06.135 ◽

2020 ◽

Vol 45 (46) ◽

pp. 24582-24594 ◽

Cited By ~ 1

Author(s):

P.C. Meenu ◽

M. Ameen Sha ◽

Rani Pavithran ◽

V.S. Dilimon ◽

S.M.A. Shibli

Keyword(s):

Dicarboxylic Acid ◽

Hydrogen Generation ◽

Photocatalytic Hydrogen Generation ◽

Metal Organic ◽

Frame Work ◽

Nano Rods ◽

Benzene Dicarboxylic Acid ◽

Cobalt And Nickel

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Characterization and fractionation of PS-b-PMMA diblock copolymer synthesized via click chemistry

Polymer ◽

10.1016/j.polymer.2015.10.032 ◽

2015 ◽

Vol 80 ◽

pp. 46-51 ◽

Cited By ~ 4

Author(s):

Junyoung Lee ◽

Kyuseong Lee ◽

Jinhwi Park ◽

Jin Kon Kim ◽

Taihyun Chang

Keyword(s):

Click Chemistry ◽

Diblock Copolymer

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Zur Genese Der Amidisch An Den Chromophor Von Pyoverdinen Gebundenen Dicarbonsäuren [1]

Zeitschrift für Naturforschung C ◽

10.1515/znc-1991-5-611 ◽

1991 ◽

Vol 46 (5-6) ◽

pp. 398-406 ◽

Cited By ~ 20

Author(s):

H. Schäfer ◽

K. Taraz ◽

H. Budzikiewicz

Keyword(s):

Glutamic Acid ◽

Dicarboxylic Acid ◽

Succinic Acid ◽

Pseudomonas Fluorescens ◽

Exponential Growth ◽

Culture Medium ◽

Culture Time ◽

Hydrolysis Of

Pseudomonas strains of the so-called fluorescent group usually produce several pyoverdins which differ only in the nature of a dicarboxylic acid bound amidically to the chromophor. For the pyoverdins isolated from the culture medium of Pseudomonas fluorescens 12 it is shown that succinic acid is an artefact formed by hydrolysis of succinic amide, and that a-ketoglutaric acid is transformed enzymatically to glutamic acid. This process is reversed after the phase of exponential growth of the bacteria. The ratio C4- vs. C5 -acids changes with the culture time and with increasing Fe3+ content of the medium in favor of the latter

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Metal–organic frameworks constructed from crown ether-based 1,4-benzenedicarboxylic acid derivatives

Dalton Transactions ◽

10.1039/c5dt04316f ◽

2016 ◽

Vol 45 (7) ◽

pp. 3063-3069 ◽

Cited By ~ 12

Author(s):

Teng-Hao Chen ◽

Andreas Schneemann ◽

Roland A. Fischer ◽

Seth M. Cohen

Keyword(s):

Crown Ether ◽

Dicarboxylic Acid ◽

Metal Organic Framework ◽

Metal Organic Frameworks ◽

Thiacrown Ether ◽

Benzenedicarboxylic Acid ◽

Metal Organic ◽

Benzene Dicarboxylic Acid ◽

Organic Framework

A series of crown ether- and thiacrown ether-derivatized benzene dicarboxylic acid (H2bdc) ligands has been synthesized and incorporated into the prototypical isoreticular metal–organic framework (IRMOF) and UiO-66 materials.

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