(D)n–σ–(A)m type partially conjugated block copolymer and its performance in single-component polymer solar cells

2017 ◽  
Vol 5 (20) ◽  
pp. 9745-9751 ◽  
Author(s):  
Dae Hee Lee ◽  
Ji Hyung Lee ◽  
Hyung Jong Kim ◽  
Suna Choi ◽  
Gi Eun Park ◽  
...  
Keyword(s):  
Solar Cells ◽  
Block Copolymer ◽  
Block Copolymers ◽  
Polymer Solar Cells ◽  
Single Component

We synthesized two types of novel poly(3-alkylthiophene)-free (D)n-b-(A)m conjugated block copolymers: PTQI-block-PNDISs.

Fully conjugated block copolymers for single-component solar cells: synthesis, purification, and characterization

2016 ◽  
Vol 40 (2) ◽  
pp. 1825-1833 ◽  
Author(s):  
Shifan Wang ◽  
Qingqing Yang ◽  
Youtian Tao ◽  
Yan Guo ◽  
Jie Yang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Block Copolymer ◽  
Block Copolymers ◽  
Power Conversion Efficiency ◽  
Active Layer ◽  
Conversion Efficiency ◽  
Polymer Solar Cells ◽  
Power Conversion ◽  
Purification And Characterization ◽  
Preparative Gpc

All-polymer solar cells using the preparative GPC separated block copolymer P3HT-b-PBIT2 as a simple active layer show a power conversion efficiency of 1.0%.

Facile one-pot polymerization of a fully conjugated donor–acceptor block copolymer and its application in efficient single component polymer solar cells

2019 ◽  
Vol 7 (37) ◽  
pp. 21280-21289 ◽  
Author(s):  
Chang Geun Park ◽  
Su Hong Park ◽  
Youngseo Kim ◽  
Thanh Luan Nguyen ◽  
Han Young Woo ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Block Copolymer ◽  
Power Conversion Efficiency ◽  
Polymer Solar Cell ◽  
Polymer Solar Cells ◽  
Power Conversion ◽  
Single Component ◽  
One Pot ◽  
Donor Acceptor

A single component polymer solar cell with a CDABP film annealed at 180 °C showed a maximum power conversion efficiency of 5.28%, which is much higher than that (2.62%) of the device with the as-cast film.

Synthesis of All-Conjugated ABA and AB-type Donor-Acceptor Block Copolymers and Their Application in All-Polymer Solar Cells

2014 ◽  
Vol 1628 ◽  
Author(s):  
Jin Wang ◽  
Tomoya Higashihara
Keyword(s):  
Solar Cells ◽  
Block Copolymer ◽  
Block Copolymers ◽  
Active Component ◽  
Main Chain ◽  
Polymer Solar Cells ◽  
Stille Coupling ◽  
Naphthalene Diimide ◽  
Chain Composition ◽  
Donor Acceptor

ABSTRACTIn this work, we report the synthesis of all-conjugated donor-acceptor block copolymers via a externally initiated Kumada catalyst-transfer polycondensation (KCTP) method. In the first step, electron acceptor blocks, poly(naphthalene diimide)s (PNDIs), were prepared via the Stille coupling polycondensation. Then, P3HT blocks were polymerized by KCTP initiated by Ni(COD)2 activated PNDI complexes. Therefore, a series of ABA (P3HTs were initiated from both ends of PNDI) and AB-type (P3HT was initiated from one end of PNDI) block copolymers were successfully synthesized. Before fabrication of all-polymer solar cells, the morphologies and crystalline behaviors of the block copolymers were extensively investigated as a function of thermal annealing and the main chain composition of PNDI block. As a control, the crystalline behaviors of the physical blends of P3HT and PNDIs were also reported. Finally, all-polymer solar cells were fabricated by using the block copolymers as the single active component or as surfactants. A PCE of 0.11 % with Voc=0.46 V, Jsc=0.50 mA/cm2, and FF=0.46 was recorded by using the donor-acceptor all-conjugated block copolymer as the single active component.

A conjugated donor-acceptor block copolymer enables over 11% efficiency for single-component polymer solar cells

Joule ◽  
2021 ◽  
Author(s):  
Yao Wu ◽  
Jing Guo ◽  
Wei Wang ◽  
Zhihao Chen ◽  
Zeng Chen ◽  
...  
Keyword(s):  
Solar Cells ◽  
Block Copolymer ◽  
Polymer Solar Cells ◽  
Single Component ◽  
Donor Acceptor

Photovoltaic performance enhancement of P3HT/PCBM solar cells driven by incorporation of conjugated liquid crystalline rod-coil block copolymers

2014 ◽  
Vol 2 (19) ◽  
pp. 3835-3845 ◽  
Author(s):  
Kai Yuan ◽  
Lie Chen ◽  
Yiwang Chen
Keyword(s):  
Solar Cells ◽  
Block Copolymer ◽  
Block Copolymers ◽  
Liquid Crystalline ◽  
Performance Enhancement ◽  
Polymer Solar Cells ◽  
Photovoltaic Performance

Liquid crystalline rod-coil block copolymer compatibilizers are applied in polymer solar cells for modifying the interface between P3HT and PCBM.

Narrow‐Bandgap Single‐Component Polymer Solar Cells with Approaching 9% Efficiency

2021 ◽  
pp. 2101295
Author(s):  
Siying Li ◽  
Xin Yuan ◽  
Qilin Zhang ◽  
Bin Li ◽  
Yuxiang Li ◽  
...  
Keyword(s):  
Solar Cells ◽  
Polymer Solar Cells ◽  
Single Component ◽  
Narrow Bandgap

Fullerene attached all-semiconducting diblock copolymers for stable single-component polymer solar cells

2010 ◽  
Vol 46 (36) ◽  
pp. 6723 ◽  
Author(s):  
Shoji Miyanishi ◽  
Yue Zhang ◽  
Keisuke Tajima ◽  
Kazuhito Hashimoto
Keyword(s):  
Solar Cells ◽  
Diblock Copolymers ◽  
Polymer Solar Cells ◽  
Single Component

scholarly journals “Double-Cable” Conjugated Polymers with Linear Backbone toward High Quantum Efficiencies in Single-Component Polymer Solar Cells

2017 ◽  
Vol 139 (51) ◽  
pp. 18647-18656 ◽  
Author(s):  
Guitao Feng ◽  
Junyu Li ◽  
Fallon J. M. Colberts ◽  
Mengmeng Li ◽  
Jianqi Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Conjugated Polymers ◽  
Polymer Solar Cells ◽  
Single Component ◽  
High Quantum
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