Missing-node directed synthesis of hierarchical pores on a zirconium metal–organic framework with tunable porosity and enhanced surface acidity via a microdroplet flow reaction

2017 ◽  
Vol 5 (42) ◽  
pp. 22372-22379 ◽  
Author(s):  
Ying Wang ◽  
Liangjun Li ◽  
Pengcheng Dai ◽  
Liting Yan ◽  
Lei Cao ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Surface Acidity ◽  
Hierarchical Pores ◽  
Hierarchical Porous ◽  
Metal Organic ◽  
Flow Reaction ◽  
First Time ◽  
Enhanced Surface ◽  
Zirconium Metal ◽  
Organic Framework

A hierarchical porous zirconium metal–organic framework (UiO-66) was prepared continuously through a microdroplet flow reaction strategy for the first time.

A cellulose monolith supported metal/organic framework as a hierarchical porous material for a flow reaction

2020 ◽  
Vol 56 (3) ◽  
pp. 411-414 ◽  
Author(s):  
Zhaohang Yang ◽  
Taka-Aki Asoh ◽  
Hiroshi Uyama
Keyword(s):  
Porous Material ◽  
Metal Organic Framework ◽  
Injection Method ◽  
Hierarchical Porous ◽  
Highly Effective ◽  
Metal Organic ◽  
Flow Reaction ◽  
Organic Framework ◽  
Supported Metal

A novel cellulose monolith supported ZIF-8 metal organic framework as a hierarchical porous material was designed by using a highly effective pump injection method, which is used for a flow-based reaction.

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

A Microporous Zirconium Metal-Organic Framework Based on trans -Aconitic Acid for Selective Carbon Dioxide Adsorption

2019 ◽  
Vol 2019 (22) ◽  
pp. 2674-2679 ◽  
Author(s):  
Sujing Wang ◽  
Mohammad Wahiduzzaman ◽  
Charlotte Martineau-Corcos ◽  
Guillaume Maurin ◽  
Christian Serre
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Framework ◽  
Carbon Dioxide Adsorption ◽  
Aconitic Acid ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

Improving Water-Treatment Performance of Zirconium Metal-Organic Framework Membranes by Postsynthetic Defect Healing

2017 ◽  
Vol 9 (43) ◽  
pp. 37848-37855 ◽  
Author(s):  
Xuerui Wang ◽  
Linzhi Zhai ◽  
Yuxiang Wang ◽  
Ruitong Li ◽  
Xuehong Gu ◽  
...  
Keyword(s):  
Water Treatment ◽  
Metal Organic Framework ◽  
Treatment Performance ◽  
Defect Healing ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

In-situ one-step deposition of highly dispersed palladium nanoparticles into zirconium metal–organic framework for selective hydrogenation of furfural

2021 ◽  
Vol 514 ◽  
pp. 111859
Author(s):  
Samaneh Sohrabi ◽  
Reza Khaleghi Abasabadi ◽  
Abbas Ali Khodadadi ◽  
Yadollah Mortazavi ◽  
Ali Hoseinzadeh
Keyword(s):  
Selective Hydrogenation ◽  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Highly Dispersed ◽  
Metal Organic ◽  
One Step ◽  
Zirconium Metal ◽  
Organic Framework

The cascade catalysis of the porphyrinic zirconium metal-organic framework PCN-224-Cu for CO2 conversion to alcohols

2021 ◽  
Author(s):  
Shi-Chao Qi ◽  
Zhi-Hui Yang ◽  
Rong-Rong Zhu ◽  
Xiao-Jie Lu ◽  
Ding-Ming Xue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Co2 Conversion ◽  
Cascade System ◽  
The Past ◽  
Highly Efficient ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework ◽  
Cascade Catalysis

Reproducing the highly efficient catalytic cascade system to mimic life behaviors in vitro has been intensively investigated over the past few decades. However, except the biocatalysis with enzymes, most chemocatalytic...

Effective Adsorption of Cefradine from Wastewater with a Stable Zirconium Metal–Organic Framework

2018 ◽  
Vol 57 (44) ◽  
pp. 15132-15137 ◽  
Author(s):  
Yingjie Zhao ◽  
Shijie Hou ◽  
Dahuan Liu ◽  
Chongli Zhong
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

scholarly journals Europium ion post-functionalized zirconium metal–organic frameworks as luminescent probes for effectively sensing hydrazine hydrate

RSC Advances ◽  
2018 ◽  
Vol 8 (31) ◽  
pp. 17471-17476 ◽  
Author(s):  
Yunhui Yang ◽  
Xiaofei Liu ◽  
Dan Yan ◽  
Ping Deng ◽  
Zhiyong Guo ◽  
...  
Keyword(s):  
Hydrazine Hydrate ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Europium Ion ◽  
Luminescent Probes ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A luminescent metal–organic framework have been realized for efficiently sensing hydrazine hydrate.

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