Sustainable synthesis of alkaline metal oxide-mesoporous carbons via mechanochemical coordination self-assembly

2017 ◽  
Vol 5 (45) ◽  
pp. 23446-23452 ◽  
Author(s):  
Weida Shan ◽  
Pengfei Zhang ◽  
Shize Yang ◽  
Huiyuan Zhu ◽  
Peiwen Wu ◽  
...  

A solvent-free self-assembly strategy for the synthesis of alkaline-metal-doped mesoporous carbons (MCs) is developed through mechanochemical coordination assembly between polyphenols and various metal ions.


2018 ◽  
Vol 54 (16) ◽  
pp. 2044-2047 ◽  
Author(s):  
Fang Cui ◽  
Jiajia Zhang ◽  
Qing Shao ◽  
Linxu Xu ◽  
Xinzi Pan ◽  
...  

Despite numerous reports on noble metal/metal oxide composites, the control of the exposed facet is still a great challenge. Here, the large-scale synthesis of noble metal/metal oxide spheres with controlled facets is enabled by making use of a bottom-up self-assembly strategy.



Author(s):  
Chien-Te Hsieh ◽  
Kuen-Song Lin ◽  
Shih Hung Chan ◽  
Ay Su

An efficient technique to fabricate metal-oxide/carbon composite nanotubes has been developed through a self-assembly processing that includes implantation of acidic groups and interaction between surface oxides and metal ions or hydration molecules. To functionalize carbon nanotubes, gaseous oxidation at 300 °C was firstly employed to build functional oxygen groups including carboxyl, carbonyl and hydroxyl group, on the ends or sidewalls of the nanotubes. It revealed that the oxidized nanotubes express a slight improvement of surface hydrophilicity, which was demonstrated by contact angle measurement. X-ray photoelectron spectroscope investigation indicated that the ratio of attached metal-oxide onto the oxidized nanotubes gradually increases with oxidation level, i.e., surface O/C atomic ratio. This evidence reflected that the surface oxides act as an adsorption center that strongly interacts with metal ions or hydration molecules in aqueous phase. Applying this method, SnO2, RuO2, NiO and PtRu nanoparticles having an average size of 5 nm were assembled on the oxidized carbon nanotubes.



2003 ◽  
Vol 2003 (5) ◽  
pp. 822-829 ◽  
Author(s):  
Rolf W. Saalfrank ◽  
Bernhard Demleitner ◽  
Horst Glaser ◽  
Harald Maid ◽  
Stefan Reihs ◽  
...  


2003 ◽  
Vol 2003 (6) ◽  
pp. 1253-1254
Author(s):  
Rolf W. Saalfrank ◽  
Bernhard Demleitner ◽  
Horst Glaser ◽  
Harald Maid ◽  
Stefan Reihs ◽  
...  


2020 ◽  
Vol 8 (14) ◽  
pp. 6717-6731 ◽  
Author(s):  
Jixing Liu ◽  
Huifang Cheng ◽  
Junbin Tan ◽  
Bing Liu ◽  
Zihao Zhang ◽  
...  

Porous CeWOx catalysts with impressive specific surface areas and deNOx activity were constructed by a rapid and solvent-free strategy.





2016 ◽  
Vol 4 (8) ◽  
pp. 4473-4479 ◽  
Author(s):  
Fan Xu ◽  
Yiqing Chen ◽  
Minghui Tang ◽  
Haiyan Wang ◽  
Jiang Deng ◽  
...  




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