scholarly journals In situ electrochemical electron paramagnetic resonance spectroscopy as a tool to probe electrical double layer capacitance

2018 ◽  
Vol 54 (31) ◽  
pp. 3827-3830 ◽  
Author(s):  
Bin Wang ◽  
Alistair J. Fielding ◽  
Robert A. W. Dryfe

In situ electrochemical electron paramagnetic resonance (EPR) spectroscopy is presented as a means to distinguish between purely capacitive and pseudo-capacitive processes in supercapacitors.

FEBS Letters ◽  
1991 ◽  
Vol 281 (1-2) ◽  
pp. 130-132 ◽  
Author(s):  
Ikuko Ueno ◽  
Satoshi Fujii ◽  
Hiroaki Ohya-Nishiguchi ◽  
Tetsutaro Iizuka ◽  
Shiro Kanegasaki

2016 ◽  
Vol 7 (12) ◽  
pp. 6952-6960 ◽  
Author(s):  
Sabine Richert ◽  
Jonathan Cremers ◽  
Harry L. Anderson ◽  
Christiane R. Timmel

Electron paramagnetic resonance spectroscopy reveals the molecular geometry and metal–ligand interactions in template-bound ten-membered bis-copper porphyrin nanorings.


2017 ◽  
Vol 19 (40) ◽  
pp. 27173-27177 ◽  
Author(s):  
Luca Bolzonello ◽  
Marco Albertini ◽  
Elisabetta Collini ◽  
Marilena Di Valentin

In this work, the electronic structure of the triplet state of self-assembled J-aggregates of tetrakis(4-sulfonatophenyl)porphyrin (TPPS) has been characterized by means of time-resolved electron paramagnetic resonance spectroscopy.


2015 ◽  
Vol 8 (4) ◽  
pp. 1358-1367 ◽  
Author(s):  
Johannes Wandt ◽  
Cyril Marino ◽  
Hubert A. Gasteiger ◽  
Peter Jakes ◽  
Rüdiger-A. Eichel ◽  
...  

Time-resolved formation of micro-structured mossy/dendritic lithium is investigated during battery cycling byoperandoEPR spectroscopy, using a novel electrochemical cell design.


2020 ◽  
Vol 6 (22) ◽  
pp. eaaz8244
Author(s):  
Fei Kong ◽  
Pengju Zhao ◽  
Pei Yu ◽  
Zhuoyang Qin ◽  
Zhehua Huang ◽  
...  

Electron paramagnetic resonance (EPR) spectroscopy is among the most important analytical tools in physics, chemistry, and biology. The emergence of nitrogen-vacancy (NV) centers in diamond, serving as an atomic-sized magnetometer, has promoted this technique to single-spin level, even under ambient conditions. Despite the enormous progress in spatial resolution, the current megahertz spectral resolution is still insufficient to resolve key heterogeneous molecular information. A major challenge is the short coherence times of the sample electron spins. Here, we address this challenge by using a magnetic noise–insensitive transition between states of different symmetry. We demonstrate a 27-fold narrower spectrum of single substitutional nitrogen (P1) centers in diamond with a linewidth of several kilohertz, and then some weak couplings can be resolved. Those results show both spatial and spectral advances of NV center–based EPR and provide a route toward analytical (EPR) spectroscopy at the single-molecule level.


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