Self-supported three-dimensional Cu/Cu2O–CuO/rGO nanowire array electrodes for an efficient hydrogen evolution reaction

2018 ◽  
Vol 54 (49) ◽  
pp. 6388-6391 ◽  
Author(s):  
Lin Ye ◽  
Zhenhai Wen

Cu/Cu2O–CuO/rGO nanowire arrays was fabricated as a highly efficient HER catalyst with a small onset potential and low overpotential.

Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 929 ◽  
Author(s):  
Sajjad Hussain ◽  
Kamran Akbar ◽  
Dhanasekaran Vikraman ◽  
Rana Afzal ◽  
Wooseok Song ◽  
...  

To find an effective alternative to scarce, high-cost noble platinum (Pt) electrocatalyst for hydrogen evolution reaction (HER), researchers are pursuing inexpensive and highly efficient materials as an electrocatalyst for large scale practical application. Layered transition metal dichalcogenides (TMDCs) are promising candidates for durable HER catalysts due to their cost-effective, highly active edges and Earth-abundant elements to replace Pt electrocatalysts. Herein, we design an active, stable earth-abundant TMDCs based catalyst, WS(1−x)Sex nanoparticles-decorated onto a 3D porous graphene/Ni foam. The WS(1−x)Sex/graphene/NF catalyst exhibits fast hydrogen evolution kinetics with a moderate overpotential of ~−93 mV to drive a current density of 10 mA cm−2, a small Tafel slope of ~51 mV dec−1, and a long cycling lifespan more than 20 h in 0.5 M sulfuric acid, which is much better than WS2/NF and WS2/graphene/NF catalysts. Our outcomes enabled a way to utilize the TMDCs decorated graphene and precious-metal-free electrocatalyst as mechanically robust and electrically conductive catalyst materials.


2018 ◽  
Vol 775 ◽  
pp. 139-143 ◽  
Author(s):  
Luigi A. Dahonog ◽  
Mary Donnabelle L. Balela

Nickel cobaltite (NiCo2O4) nanowires were successfully grown on the surface of carbon fiber via hydrothermal treatment, followed by annealing. After 2 h, SEM revealed the formation of NiCo2O4 nanowire arrays on the surface of the carbon fiber paper. With increasing hydrothermal time from 2 to 12 h, the NiCo2O4 nanowires also self-assembled into urchin-like morphologies. When used as catalysts for hydrogen evolution reaction, the NiCo2O4 nanowires exhibit an onset potential for the cathodic current at-0.13 V vs. Ag/AgCl in 0.1 M KOH.


2014 ◽  
Vol 2 (43) ◽  
pp. 18383-18397 ◽  
Author(s):  
Amare Aregahegn Dubale ◽  
Wei-Nien Su ◽  
Andebet Gedamu Tamirat ◽  
Chun-Jern Pan ◽  
Belete Asefa Aragaw ◽  
...  

The graphene modified Cu2O nanowire array demonstrates improved photocurrent density and photostability, attributed to the synergetic effect of graphene.


2019 ◽  
Vol 29 (44) ◽  
pp. 1970308
Author(s):  
Adeela Nairan ◽  
Peichao Zou ◽  
Caiwu Liang ◽  
Jiaxing Liu ◽  
Dang Wu ◽  
...  

2015 ◽  
Vol 51 (75) ◽  
pp. 14160-14163 ◽  
Author(s):  
Canbin Ouyang ◽  
Xin Wang ◽  
Shuangyin Wang

P doped CoS2 nanosheet arrays were prepared by a two-step reaction at lower temperature. P doped CoS2, as a highly efficient HER catalyst, shows lower onset potential, smaller Tafel slope and better catalytic stability than pure CoS2.


Author(s):  
Ning Xie ◽  
Dong-Dong Ma ◽  
Yu-Lin Wu ◽  
Xintao Wu ◽  
Qi-Long Zhu

Exploiting the highly active and low-cost electrocatalysts based on earth-abundant elements for hydrogen evolution reaction (HER) is an extremely desired but challenging task. Herein, we present a facile and economical...


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