Unconventional ionic ring-deconstruction pathways of a three-membered heterocycle
Two different ionic deconstruction reactions of the oxaphosphirane ring in I are reported. One is induced by base and involves displacement of the aldehyde unit forming II whilst acid-initiated extrusion of the ring-carbon with its substituents yielded III. Further insights into the latter ring-deconstruction were obtained by quantum chemical calculations.
2015 ◽
Vol 135
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pp. 618-623
2020 ◽
2020 ◽
2020 ◽
Vol 16
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pp. 93-103
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1977 ◽
Vol 42
(2)
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pp. 687-696
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