Enhanced fluorescence of phthalimide compounds induced by the incorporation of electron-donating alicyclic amino groups

2018 ◽  
Vol 20 (23) ◽  
pp. 16033-16044 ◽  
Author(s):  
Ryoji Orita ◽  
Marius Franckevičius ◽  
Aurimas Vyšniauskas ◽  
Vidmantas Gulbinas ◽  
Haruki Sugiyama ◽  
...  

A significant difference in fluorescence properties between 3- and 4-substituted phthalimides demonstrates the formation of excited TICT and planar ICT states, respectively.

ChemPlusChem ◽  
2020 ◽  
Vol 85 (7) ◽  
pp. 1523-1528
Author(s):  
Qing Li ◽  
Xin Yang ◽  
Liwei Zhang ◽  
Yuefei Wang ◽  
Jia Kong ◽  
...  

2015 ◽  
Vol 39 (6) ◽  
pp. 4334-4342 ◽  
Author(s):  
Huanjie Tang ◽  
Changhua Zhou ◽  
Ruili Wu ◽  
Mao Mao ◽  
Huaibin Shen ◽  
...  

Amino-functionalized hydrophilic QDs insulated with PEI(n)Cs had enhanced PL intensity and colloidal stability compared to those of PEI-QDs.


Author(s):  
A M A Hammouda ◽  
G E Mady

The measurement of carbamylated haemoglobin is a useful indicator of uraemic state during the preceding few weeks in patients with renal failure. In diabetic uraemic patients with hyperglycaemia, glycation of haemoglobin may interfere with its carbamylation, as both reactions involve the free amino groups of the protein. The aim of this study was to investigate the carbamylation of haemoglobin in the presence of hyperglycaemia. The study included 29 patients with chronic renal failure on regular haemodialysis, 14 diabetic and 15 non-diabetic patients, and 10 healthy controls. We found a significant correlation between the degree of haemoglobin carbamylation and mean blood urea concentration in both uraemic and control subjects. Carbamylation of haemoglobin was higher in both diabetic and non-diabetic chronic renal failure patients, but there were no significant differences between the groups regarding mean blood urea concentration or level of haemoglobin carbamylation. Carbamylated haemoglobin per unit of blood urea concentration was lower in the diabetic patients. Using a correction formula to account for the degree of haemoglobin glycation, there was no longer a significant difference in carbamylation per unit of blood urea concentration. In vitro incubation of red blood cells from six healthy and six diabetic non-uraemic patients in 70mmol/L urea showed a significantly lower carbamylation in the diabetic patients, but there was no significant difference when using corrected carbamylated haemoglobin values. We conclude that glycation of haemoglobin affects its carbamylation and that monitoring of uraemia in a diabetic patient necessitates the use of carbamylated haemoglobin value corrected for the degree of glycation.


2014 ◽  
Vol 3 (5) ◽  
pp. 405-409 ◽  
Author(s):  
Jan-Moritz Koenen ◽  
Xuzhi Zhu ◽  
Zhenxing Pan ◽  
Fude Feng ◽  
Jie Yang ◽  
...  

2017 ◽  
Vol 41 (24) ◽  
pp. 15244-15250 ◽  
Author(s):  
Ramar Rajamanikandan ◽  
Malaichamy Ilanchelian

The emission intensity of red emissive GSH-AgNCs is notably enhanced after the addition of dopamine. The increasing emission intensity is attributed to the hydrogen bonding interaction between the carboxyl groups of GSH-AgNCs and amino groups of dopamine.


Author(s):  
Ying Fu ◽  
Xiao-Xiao Pang ◽  
Kui Wang ◽  
Zhi-Qiang Wang ◽  
Guan-Yu Li ◽  
...  

A series of novel N-n-butyl-1,8-naphthalimide derivatives were synthesized via a three-step reaction involving nucleophilic substitution and acylation. All of the compounds were characterized by IR, 1H NMR, 13C NMR, MS, and elemental analysis, and the crystal structure of N-n-butyl-4-[N’,N’-bis(2`,4`-dichlorobenzoyl)ethylamino]-1,8-naphthalimide was determined. The π-π stacking interactions and hydrogen bonds between the two molecular core planes (naphthalimide ring) and the van der Waals forces between the flexible n-butyl groups resulted in a 3D long-chain structure. The UV-vis and fluorescence properties of the title compounds were investigated. The results indicated that the monosubstituted 1,8-naphthalimide derivatives bearing an electron-donating group on the benzene ring or a structure with a larger conjugative effect exhibited enhanced fluorescence properties.


2019 ◽  
Vol 7 (39) ◽  
pp. 6010-6023 ◽  
Author(s):  
A. Gopinath ◽  
N. Manivannan ◽  
Sudip Mandal ◽  
N. Mathivanan ◽  
A. Sultan Nasar

In this paper, we report the fluorescence properties of new star α-cyanostilbene molecules. Fungus cell imaging studies using one of the molecules allowed observing nuclear movement in the live mycelium.


RSC Advances ◽  
2017 ◽  
Vol 7 (32) ◽  
pp. 19808-19814 ◽  
Author(s):  
Shipeng Wen ◽  
Guiming Zhang ◽  
Rong Zhang ◽  
Liqun Zhang ◽  
Li Liu

Due to the LSPR effect of Ag-NPs, the fluorescence intensity, quantum efficiency of Tb-complex in the composite fibers were improved.


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