Synthesis of silyl iron hydride via Si–H activation and its dual catalytic application in the hydrosilylation of carbonyl compounds and dehydration of benzamides

2018 ◽  
Vol 47 (12) ◽  
pp. 4352-4359 ◽  
Author(s):  
Shishuai Ren ◽  
Shangqing Xie ◽  
Tingting Zheng ◽  
Yangyang Wang ◽  
Shilu Xu ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Catalytic Application ◽  
Iron Hydride

A silyl iron hydride as a dual catalyst was synthesized for the reduction of carbonyl compounds and the dehydration of amides.

scholarly journals Catalytic application of sulfamic acid-functionalized magnetic Fe3O4 nanoparticles (SA-MNPs) for protection of aromatic carbonyl compounds and alcohols: experimental and theoretical studies

RSC Advances ◽  
2020 ◽  
Vol 10 (73) ◽  
pp. 44946-44957
Author(s):  
Sepideh Khaef ◽  
Mohammad Ali Zolfigol ◽  
Avat Arman Taherpour ◽  
Meysam Yarie
Keyword(s):  
Organic Compounds ◽  
Carbonyl Compounds ◽  
Sulfamic Acid ◽  
Synthetic Methods ◽  
Theoretical Studies ◽  
Catalytic Application ◽  
Magnetic Fe3o4 Nanoparticles ◽  
Aromatic Carbonyl Compounds ◽  
Experimental And Theoretical Studies ◽  
Magnetic Fe3o4

Protection techniques of functional groups within the structure of organic compounds are important synthetic methods against unwanted attacks from various reagents during synthetic sequences.

Selective C–F and C–H Activation of Fluoroarenes by Fe(PMe3)4 and Catalytic Performance of Iron Hydride in Hydrosilylation of Carbonyl Compounds

2016 ◽  
Vol 35 (20) ◽  
pp. 3538-3545 ◽  
Author(s):  
Tingting Zheng ◽  
Junye Li ◽  
Shumiao Zhang ◽  
Benjing Xue ◽  
Hongjian Sun ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Catalytic Performance ◽  
Iron Hydride

scholarly journals An experimental and computational study for a Pd(II) catalysed hydroboration and reductive amination reaction of carbonyl compounds

2022 ◽  
Author(s):  
Tarun Kanti Panda ◽  
Shreya Mahato ◽  
Parveen Rawal ◽  
Ajitaro Devadkar ◽  
Mayank Joshi ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Reductive Amination ◽  
Computational Study ◽  
Catalytic Application ◽  
Amination Reaction ◽  
Salen Ligand

We report the synthesis, characterisation, and catalytic application of a palladium (II) complex [(4-{1,2-C6H4(N=CH-C6H4O)2}Pd] (1) supported by a dianionic salen ligand [1,2-C6H4(N=CH-C6H4O)2]2- (L) as a molecular pre-catalyst for the hydroboration...

Synthesis and Catalytic Activity of Iron Hydride Ligated with Bidentate N-Heterocyclic Silylenes for Hydroboration of Carbonyl Compounds

2019 ◽  
Vol 38 (2) ◽  
pp. 268-277 ◽  
Author(s):  
Xinghao Qi ◽  
Tingting Zheng ◽  
Junhao Zhou ◽  
Yanhong Dong ◽  
Xia Zuo ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbonyl Compounds ◽  
Iron Hydride

Synthesis of [POCOP]-pincer iron and cobalt complexes via Csp3–H activation and catalytic application of iron hydride in hydrosilylation reactions

RSC Advances ◽  
2015 ◽  
Vol 5 (20) ◽  
pp. 15660-15667 ◽  
Author(s):  
Shaofeng Huang ◽  
Hua Zhao ◽  
Xiaoyan Li ◽  
Lin Wang ◽  
Hongjian Sun
Keyword(s):  
Bond Activation ◽  
Cobalt Complexes ◽  
Pincer Ligand ◽  
Catalytic Application ◽  
Iron Hydride

Csp3–H bond activation in pincer ligand (Ph2PO(o-C6H2-(4,6-tBu2)))2CH2 (1) (POCH2OP) was achieved by Fe(PMe3)4 and CoMe(PMe3)4 to afford (POCHOP)Fe(H) (PMe3)2 (2) and (POCHOP)Co(PMe3)2 (4).

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