High performance organic sodium-ion hybrid capacitors based on nano-structured disodium rhodizonate rivaling inorganic hybrid capacitors

2018 ◽  
Vol 20 (21) ◽  
pp. 4920-4931 ◽  
Author(s):  
Ranjith Thangavel ◽  
Rubha Ponraj ◽  
Aravindaraj G. Kannan ◽  
Karthikeyan Kaliyappan ◽  
Dong Won Kim ◽  
...  

Sodium hybrid capacitors (NHCs) have tremendous potential to meet the simultaneous high energy–high power requirement of next-generation storage applications.

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Qiulong Wei ◽  
Qidong Li ◽  
Yalong Jiang ◽  
Yunlong Zhao ◽  
Shuangshuang Tan ◽  
...  

AbstractHigh-performance and low-cost sodium-ion capacitors (SICs) show tremendous potential applications in public transport and grid energy storage. However, conventional SICs are limited by the low specific capacity, poor rate capability, and low initial coulombic efficiency (ICE) of anode materials. Herein, we report layered iron vanadate (Fe5V15O39 (OH)9·9H2O) ultrathin nanosheets with a thickness of ~ 2.2 nm (FeVO UNSs) as a novel anode for rapid and reversible sodium-ion storage. According to in situ synchrotron X-ray diffractions and electrochemical analysis, the storage mechanism of FeVO UNSs anode is Na+ intercalation pseudocapacitance under a safe potential window. The FeVO UNSs anode delivers high ICE (93.86%), high reversible capacity (292 mAh g−1), excellent cycling stability, and remarkable rate capability. Furthermore, a pseudocapacitor–battery hybrid SIC (PBH-SIC) consisting of pseudocapacitor-type FeVO UNSs anode and battery-type Na3(VO)2(PO4)2F cathode is assembled with the elimination of presodiation treatments. The PBH-SIC involves faradaic reaction on both cathode and anode materials, delivering a high energy density of 126 Wh kg−1 at 91 W kg−1, a high power density of 7.6 kW kg−1 with an energy density of 43 Wh kg−1, and 9000 stable cycles. The tunable vanadate materials with high-performance Na+ intercalation pseudocapacitance provide a direction for developing next-generation high-energy capacitors.


2015 ◽  
Vol 3 (42) ◽  
pp. 21277-21283 ◽  
Author(s):  
Shengyang Dong ◽  
Laifa Shen ◽  
Hongsen Li ◽  
Ping Nie ◽  
Yaoyao Zhu ◽  
...  

Pseudocapacitive behaviours of Na2Ti3O7@CNTs enhance the electrochemical performance of Na-ion capacitors with high energy density and high power density.


Author(s):  
Chong Wang ◽  
Ning Zhao ◽  
Bohan Li ◽  
Qingtao Yu ◽  
Wanci Shen ◽  
...  

Developing high-performance electrode material for energy-storage devices with high energy-power densities, such as sodium ion hybrid capacitors (SIHCs), is of vital importance for applications in electric vehicles and portable electronics....


2019 ◽  
Vol 7 (3) ◽  
pp. 1138-1148 ◽  
Author(s):  
Xiang Hu ◽  
Yangjie Liu ◽  
Junxiang Chen ◽  
Jingchun Jia ◽  
Hongbing Zhan ◽  
...  

The 3D ordered macroporous structure made of FeS quantum dots homogeneously embedded in a 3D inverse opal-structured carbon matrix was designed for sodium ion capacitors with high energy/power densities.


2021 ◽  
Vol 493 ◽  
pp. 229678
Author(s):  
Licong Huang ◽  
Linchao Zeng ◽  
Jianhui Zhu ◽  
Lingna Sun ◽  
Lei Yao ◽  
...  

2017 ◽  
Vol 61 (2) ◽  
pp. 285-295 ◽  
Author(s):  
Yongqiang Ding ◽  
Bingjun Yang ◽  
Jiangtao Chen ◽  
Li Zhang ◽  
Junshuai Li ◽  
...  

2018 ◽  
Vol 6 (21) ◽  
pp. 9846-9853 ◽  
Author(s):  
Ranjith Thangavel ◽  
Aravindaraj G. Kannan ◽  
Rubha Ponraj ◽  
Xueliang Sun ◽  
Dong-Won Kim ◽  
...  

Developing sodium based energy storage systems that retain high energy density at high power along with stable cycling is of paramount importance to meet the energy demands of next generation applications.


2018 ◽  
Vol 6 (45) ◽  
pp. 22840-22850 ◽  
Author(s):  
Meiling Kang ◽  
Yingying Wu ◽  
Xin Huang ◽  
Kaiqiang Zhou ◽  
Zhigao Huang ◽  
...  

A high-performance hybrid sodium-ion capacitor was developed through the engineering of a TiO2 anode to achieve record high initial coulombic efficiency.


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