Catalytic transfer hydrogenation of oleic acid to octadecanol over magnetic recoverable cobalt catalysts

2019 ◽  
Vol 21 (2) ◽  
pp. 314-320 ◽  
Author(s):  
Juncheng Wang ◽  
Renfeng Nie ◽  
Ling Xu ◽  
Xilei Lyu ◽  
Xiuyang Lu
Keyword(s):  
Oleic Acid ◽  
Synergistic Effect ◽  
Cobalt Catalysts ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Highly Efficient ◽  
Earth Abundant ◽  
Catalytic Transfer

Earth-abundant magnetic cobalt is highly efficient for CTH of oleic acid with isopropanol as a hydrogen donor, affording 100% conversion as well as 91.9% octadecanol yield at 200 °C, which can be ascribed to the synergistic effect between Coδ+ and Co0.

Highly efficient catalytic transfer hydrogenation of furfural over defect-rich amphoteric ZrO2 with abundant surface acid–base sites

2021 ◽  
Vol 50 (7) ◽  
pp. 2616-2626
Author(s):  
Zekun Zhu ◽  
Lingling Yang ◽  
Changxuan Ke ◽  
Guoli Fan ◽  
Lan Yang ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Acid Base ◽  
Highly Efficient ◽  
Catalytic Transfer ◽  
Effect Of Surface

The synergistic effect of surface acid–base sites affords a harmonious environment for achieving excellent efficiency for catalytic transfer hydrogenation of furfural.

Synergistic Effect of B and N Dopants in Catalytic Transfer Hydrogenation

2018 ◽  
Vol 7 (6) ◽  
pp. 1107-1112 ◽  
Author(s):  
Yunrui Zhang ◽  
Yingying Zhai ◽  
Minzhe Chu ◽  
Li Huo ◽  
Haijun Wang ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Catalytic Transfer

scholarly journals On the catalytic transfer hydrogenation of nitroarenes by a cubane-type Mo3S4 cluster hydride: disentangling the nature of the reaction mechanism

2019 ◽  
Vol 21 (31) ◽  
pp. 17221-17231 ◽  
Author(s):  
Vicent S. Safont ◽  
Iván Sorribes ◽  
Juan Andrés ◽  
Rosa Llusar ◽  
Mónica Oliva ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Dft Calculations ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Efficient Catalyst ◽  
Highly Efficient ◽  
Catalytic Transfer

Transfer hydrogenation cluster catalysis operates through a panoply of cycles, according to DFT calculations, affording a highly efficient catalyst.

scholarly journals Hierarchically constructed NiO with improved performance for catalytic transfer hydrogenation of biomass-derived aldehydes

2019 ◽  
Vol 9 (5) ◽  
pp. 1289-1300 ◽  
Author(s):  
Jian He ◽  
Monia Runge Nielsen ◽  
Thomas Willum Hansen ◽  
Song Yang ◽  
Anders Riisager
Keyword(s):  
Furfuryl Alcohol ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Highly Efficient ◽  
Catalytic Transfer ◽  
Improved Performance ◽  
Facile Route

A 3D nanometer-scaled NiO material with urchin-like structure was prepared via a facile route, and served as a highly efficient and durable catalyst for catalytic transfer hydrogenation of bio-based furfural to furfuryl alcohol using 2-propanol as H-donor and solvent.

Palladium-catalyzed simple and efficient hydrogenative cleavage of azo compounds using recyclable polymer-supported formate

2005 ◽  
Vol 83 (5) ◽  
pp. 517-520 ◽  
Author(s):  
Keelara Abiraj ◽  
Gejjalagere R Srinivasa ◽  
D Channe Gowda
Keyword(s):  
Functional Groups ◽  
Room Temperature ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Azo Compounds ◽  
Catalytic Transfer Hydrogenation ◽  
Palladium Catalyzed ◽  
Catalytic Transfer ◽  
Polymer Supported

Palladium-catalyzed room temperature transfer hydrogenation of azo compounds using recyclable polymer-supported formate as the hydrogen donor produces corresponding amine(s) in excellent yields (88%–98%). This method was found to be highly facile with selectivity over a number of other functional groups such as halogen, alkene, nitrile, carbonyl, amide, methoxy, and hydroxyl.Key words: azo compounds, catalytic transfer hydrogenation, polymer-supported formate, 10% Pd-C, amines.

Catalytic transfer hydrogenation of biomass-derived 5-hydroxymethylfurfural into 2,5-bis(hydroxymethyl)furan over tunable Zr-based bimetallic catalysts

2018 ◽  
Vol 8 (17) ◽  
pp. 4474-4484 ◽  
Author(s):  
Junnan Wei ◽  
Xuejuan Cao ◽  
Ting Wang ◽  
Huai Liu ◽  
Xing Tang ◽  
...  
Keyword(s):  
Bimetallic Catalysts ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Highly Efficient ◽  
Catalytic Transfer ◽  
Mpv Reduction

ZrBa-SBA is highly efficient for the MPV reduction of HMF to BHMF, as the etherification of BHMF was suppressed.

Reductive Cleavage of Azo Compounds Catalysed by Commercial Zinc Dust and Hydrazinium Monoformate as a New Hydrogen Donor for Heterogeneous Catalytic Transfer Hydrogenation

2002 ◽  
Vol 2002 (8) ◽  
pp. 384-385 ◽  
Author(s):  
Shankare Gowda ◽  
K. Abiraj ◽  
D. Channe Gowda
Keyword(s):  
Zinc Dust ◽  
Reductive Cleavage ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Azo Compounds ◽  
Catalytic Transfer Hydrogenation ◽  
Heterogeneous Catalytic ◽  
Catalytic Transfer ◽  
Reflux Temperature

Azo compounds are reductively cleaved to amine/s at reflux temperature within 15 min by employing less expensive commercial zinc dust and hydrazinium monoformate, a new hydrogen donor for catalytic transfer hydrogenation.

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