scholarly journals Revisiting and improving the preparation of silicon-based electrodes for lithium-ion batteries: ball milling impact on poly(acrylic acid) polymer binders

2019 ◽  
Vol 3 (5) ◽  
pp. 881-891 ◽  
Author(s):  
Thibaut Chartrel ◽  
Mariama Ndour ◽  
Véronique Bonnet ◽  
Sébastien Cavalaglio ◽  
Luc Aymard ◽  
...  

This study revisits and optimizes silicon/carbon/poly(acrylic acid) – (PAA) composite anode preparation for lithium-ion batteries.

2009 ◽  
Vol 189 (1) ◽  
pp. 16-21 ◽  
Author(s):  
Zhaojun Luo ◽  
Dongdong Fan ◽  
Xianlong Liu ◽  
Huanyu Mao ◽  
Caifang Yao ◽  
...  

2016 ◽  
Vol 168 ◽  
pp. 138-142 ◽  
Author(s):  
Yu Zhou ◽  
Huajun Guo ◽  
Yong Yang ◽  
Zhixing Wang ◽  
Xinhai Li ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 6660-6666 ◽  
Author(s):  
Jun Wang ◽  
Shengli Li ◽  
Yi Zhao ◽  
Juan Shi ◽  
Lili Lv ◽  
...  

With a high specific capacity (4200 mA h g−1), silicon based materials have become the most promising anode materials in lithium-ions batteries.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jaebin Nam ◽  
Eunsoo Kim ◽  
Rajeev K.K. ◽  
Yeonho Kim ◽  
Tae-Hyun Kim

Abstract A ureido-pyrimidinone (UPy)-functionalized poly(acrylic acid) grafted with poly(ethylene glycol)(PEG), designated PAU-g-PEG, was developed as a high performance polymer binder for Si anodes in lithium-ion batteries. By introducing both a ureido-pyrimidinone (UPy) unit, which is capable of self-healing through dynamic hydrogen bonding within molecules as well as with Si, and an ion-conducting PEG onto the side chain of the poly(acrylic acid), this water-based self-healable and conductive polymer binder can effectively accommodate the volume changes of Si, while maintaining electronic integrity, in an electrode during repeated charge/discharge cycles. The Si@PAU-g-PEG electrode retained a high capacity of 1,450.2 mAh g−1 and a Coulombic efficiency of 99.4% even after 350 cycles under a C-rate of 0.5 C. Under a high C-rate of 3 C, an outstanding capacity of 2,500 mAh g−1 was also achieved, thus demonstrating its potential for improving the electrochemical performance of Si anodes.


2019 ◽  
Vol 43 (32) ◽  
pp. 12555-12562 ◽  
Author(s):  
Xiaofei Yang ◽  
Huimin Zhang ◽  
Hai Ming ◽  
Jingyi Qiu ◽  
Gaoping Cao ◽  
...  

The aqueous binder effects of poly(acrylic acid) and carboxy methylated cellulose on metal (oxide) anode performance in lithium-ion batteries were studied.


2019 ◽  
Vol 7 (8) ◽  
pp. 3874-3881 ◽  
Author(s):  
Min Cui ◽  
Lin Wang ◽  
Xianwei Guo ◽  
Errui Wang ◽  
Yubo Yang ◽  
...  

A mass-produced and low-cost hierarchical mesoporous/macroporous silicon-based composite material with an ample porous structure and dual carbon protective layers has been rationally designed and constructed. The Si/SiO2@C composite anode materials for LIBs show enhanced electrochemical properties.


2017 ◽  
Vol 4 (12) ◽  
pp. 1996-2004 ◽  
Author(s):  
Yankai Li ◽  
Zhi Long ◽  
Pengyuan Xu ◽  
Yang Sun ◽  
Kai Song ◽  
...  

A novel silicon–carbon composite with a 3D pore-nest structure denoted as Si@SiOx/CNTs@C was prepared and studied, and the capacity of a Si@SiOx/CNTs@C composite anode can be maintained at above 1740 mA h g−1 at a current density of 0.42 A g−1 after 700 cycles.


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