Overall structural modification of a layered Ni-rich cathode for enhanced cycling stability and rate capability at high voltage

2019 ◽  
Vol 7 (11) ◽  
pp. 6080-6089 ◽  
Author(s):  
Manjing Tang ◽  
Jun Yang ◽  
Nantao Chen ◽  
Shengcai Zhu ◽  
Xing Wang ◽  
...  

Overall structural modification, integrating coating and doping, was developed to enhance the structural stability and Li+ transport kinetics in a layered Ni-rich cathode, which significantly improves the electrochemical performance at high voltage.

Nanoscale ◽  
2015 ◽  
Vol 7 (28) ◽  
pp. 12215-12224 ◽  
Author(s):  
Yongquan Zhang ◽  
Qiang Fu ◽  
Qiaoling Xu ◽  
Xiao Yan ◽  
Rongyu Zhang ◽  
...  

The substituted-N plays a key role in improving the conductivity and structural stability of TiO2-B. Thereout, the rate capability and cycling stability of the TiO2-B nanowires are significantly improved.


2016 ◽  
Vol 4 (27) ◽  
pp. 10414-10418 ◽  
Author(s):  
Ying Ma ◽  
Yulong Jia ◽  
Lina Wang ◽  
Min Yang ◽  
Yingpu Bi ◽  
...  

Three-dimensional MoO2–G flower-like nanostructures were synthesized through a facile hydrothermal reaction and showed significantly improved specific capacitance, good rate capability and cycling stability.


2012 ◽  
Vol 541 ◽  
pp. 125-131 ◽  
Author(s):  
Yansong Bai ◽  
Xianyou Wang ◽  
Shunyi Yang ◽  
Xiaoyan Zhang ◽  
Xiukang Yang ◽  
...  

Author(s):  
Yun Xu ◽  
Mingyang Zhao ◽  
Syed Khalid ◽  
Hongmei Luo ◽  
Kyle S. Brinkman

The high voltage cathode material, LiMn1.6Ni0.4O4, was prepared by a polymer-assisted method. The novelty of this work is the substitution of Ni with Mn, which already exists in the crystal structure instead of other isovalent metal ion dopants which would result in capacity loss. The electrochemical performance testing including stability and rate capability was evaluated. The temperature was found to impose a change on the valence and structure of the cathode materials. Specifically, manganese tends to be reduced at a high temperature of 800 °C and leads to structural changes. The manganese substituted LiMn1.5Ni0.5O4 (LMN) has proved to be a good candidate material for Li-ion battery cathodes displaying good rate capability and capacity retention. The cathode materials processed at 550 °C showed a stable performance with negligible capacity loss for 400 cycles.


2014 ◽  
Vol 267 ◽  
pp. 874-880 ◽  
Author(s):  
Xue-Hui Liu ◽  
Li-Qin Kou ◽  
Ting Shi ◽  
Kun Liu ◽  
Li Chen

2015 ◽  
Vol 17 (43) ◽  
pp. 28666-28673 ◽  
Author(s):  
Jianbo Zhu ◽  
Youlong Xu ◽  
Jie Wang ◽  
Jun Lin ◽  
Xiaofei Sun ◽  
...  

Cationic mobility determines capacitance performance and rate capability in various electrolytes, while cycling stability is strongly dependent on the cationic size.


Nanoscale ◽  
2020 ◽  
Vol 12 (32) ◽  
pp. 16831-16839
Author(s):  
Na Li ◽  
Kang Wu ◽  
Yu Lin Lee ◽  
Dang Rongbin ◽  
Xin Deng ◽  
...  

The relationship between bond energy and electrochemical performance was studied through substituting Mn in O3-NaNi0.33Mn0.33Fe0.33O2 oxide with Y and Al.


2014 ◽  
Vol 16 (35) ◽  
pp. 18680-18685 ◽  
Author(s):  
Xiujuan Wei ◽  
Qinyou An ◽  
Qiulong Wei ◽  
Mengyu Yan ◽  
Xuanpeng Wang ◽  
...  

A Bowknot-like RuO2 quantum dots@V2O5 cathode exhibits superior rate capability and cycling stability.


2018 ◽  
Vol 6 (25) ◽  
pp. 12098-12105 ◽  
Author(s):  
Qiang Zhang ◽  
Gang Peng ◽  
Jean Pierre Mwizerwa ◽  
Hongli Wan ◽  
Liangting Cai ◽  
...  

All-solid-state lithium batteries employing NiS–CNT nanocomposites as cathodes exhibit superior rate capability and cycling performances owing to their excellent ionic/electronic conduction and structural stability.


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