The effect of various electrolyte cations on electrochemical performance of polypyrrole/RGO based supercapacitors

2015 ◽  
Vol 17 (43) ◽  
pp. 28666-28673 ◽  
Author(s):  
Jianbo Zhu ◽  
Youlong Xu ◽  
Jie Wang ◽  
Jun Lin ◽  
Xiaofei Sun ◽  
...  

Cationic mobility determines capacitance performance and rate capability in various electrolytes, while cycling stability is strongly dependent on the cationic size.

2018 ◽  
Vol 5 (1) ◽  
pp. 171186 ◽  
Author(s):  
Guofu Ma ◽  
Fengting Hua ◽  
Kanjun Sun ◽  
Enke Fenga ◽  
Hui Peng ◽  
...  

The electrochemical performance of an energy conversion and storage device like the supercapacitor mainly depends on the microstructure and morphology of the electrodes. In this paper, to improve the capacitance performance of the supercapacitor, the all-pseudocapacitive electrodes of lamella-like Bi 18 SeO 29 /BiSe as the negative electrode and flower-like Co 0.85 Se nanosheets as the positive electrode are synthesized by using a facile low-temperature one-step hydrothermal method. The microstructures and morphology of the electrode materials are carefully characterized, and the capacitance performances are also tested. The Bi 18 SeO 29 /BiSe and Co 0.85 Se have high specific capacitance (471.3 F g –1 and 255 F g –1 at 0.5 A g –1 ), high conductivity, outstanding cycling stability, as well as good rate capability. The assembled asymmetric supercapacitor completely based on the pseudocapacitive electrodes exhibits outstanding cycling stability (about 93% capacitance retention after 5000 cycles). Moreover, the devices exhibit high energy density of 24.2 Wh kg –1 at a power density of 871.2 W kg –1 in the voltage window of 0–1.6 V with 2 M KOH solution.


2016 ◽  
Vol 4 (27) ◽  
pp. 10414-10418 ◽  
Author(s):  
Ying Ma ◽  
Yulong Jia ◽  
Lina Wang ◽  
Min Yang ◽  
Yingpu Bi ◽  
...  

Three-dimensional MoO2–G flower-like nanostructures were synthesized through a facile hydrothermal reaction and showed significantly improved specific capacitance, good rate capability and cycling stability.


Nanoscale ◽  
2020 ◽  
Vol 12 (32) ◽  
pp. 16831-16839
Author(s):  
Na Li ◽  
Kang Wu ◽  
Yu Lin Lee ◽  
Dang Rongbin ◽  
Xin Deng ◽  
...  

The relationship between bond energy and electrochemical performance was studied through substituting Mn in O3-NaNi0.33Mn0.33Fe0.33O2 oxide with Y and Al.


2019 ◽  
Vol 7 (11) ◽  
pp. 6080-6089 ◽  
Author(s):  
Manjing Tang ◽  
Jun Yang ◽  
Nantao Chen ◽  
Shengcai Zhu ◽  
Xing Wang ◽  
...  

Overall structural modification, integrating coating and doping, was developed to enhance the structural stability and Li+ transport kinetics in a layered Ni-rich cathode, which significantly improves the electrochemical performance at high voltage.


2014 ◽  
Vol 16 (35) ◽  
pp. 18680-18685 ◽  
Author(s):  
Xiujuan Wei ◽  
Qinyou An ◽  
Qiulong Wei ◽  
Mengyu Yan ◽  
Xuanpeng Wang ◽  
...  

A Bowknot-like RuO2 quantum dots@V2O5 cathode exhibits superior rate capability and cycling stability.


2014 ◽  
Vol 2 (25) ◽  
pp. 9506-9513 ◽  
Author(s):  
Young-Min Song ◽  
Jung-Gu Han ◽  
Soojin Park ◽  
Kyu Tae Lee ◽  
Nam-Soon Choi

An organic–inorganic based surface film was formed on a 5 V-class LiNi0.5Mn1.5O4 cathode by tris(trimethylsilyl)phosphite (TMSP). This surface-modified cathode exhibited significantly improved electrochemical properties in terms of cycling stability and rate capability.


2019 ◽  
Vol 12 (03) ◽  
pp. 1950026 ◽  
Author(s):  
Lili Wang ◽  
Yanxia Huang ◽  
Xiaoshan Li ◽  
Hang Ma ◽  
Chenghang You ◽  
...  

The paper reports a kind of NiCo2O4 material with urchin-like morphology. This material was prepared using a facile strategy of hydrothermal process followed by calcinations, and exhibits an excellent electrochemical performance. For example, it delivers a specific capacitance high up to 1167[Formula: see text]Fg[Formula: see text] at 1[Formula: see text]Ag[Formula: see text] and still retains a value of 1095[Formula: see text]Fg[Formula: see text] at 10[Formula: see text]Ag[Formula: see text], showing a good rate capability; after suffering from 3000 cycles at 10[Formula: see text]A[Formula: see text]g[Formula: see text], the specific capacitance has only a decay of 12%, presenting a good cycling stability.


RSC Advances ◽  
2015 ◽  
Vol 5 (121) ◽  
pp. 99856-99865 ◽  
Author(s):  
Li Wang ◽  
Dan Chen ◽  
Jiangfeng Wang ◽  
Guijuan Liu ◽  
Wei Wu ◽  
...  

The Cr and/or Ti doping leads to the enhanced rate capability and cycling stability. The co-doped sample exhibits the optimal electrochemical performance due to the presence of appropriate Mn3+ content and higher Li+ ion diffusion coefficient.


2020 ◽  
Vol 56 (58) ◽  
pp. 8039-8042 ◽  
Author(s):  
Tong Mu ◽  
Jiguang Zhang ◽  
Rui Shi ◽  
Yunfeng Zhu ◽  
Jinglian Zhu ◽  
...  

By introducing oxygen vacancies, TiO2 microspheres exhibit outstanding electrochemical performance for dual Mg/Li-ion batteries.


2020 ◽  
Vol 2 (9) ◽  
pp. 4229-4241 ◽  
Author(s):  
Meenaketan Sethi ◽  
U. Sandhya Shenoy ◽  
D. Krishna Bhat

Solvothermal synthesis of a porous graphene–NiFe2O4 nanocomposite exhibiting high specific capacitance and high rate capability along with high cycling stability.


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