scholarly journals Inversion of donor–acceptor roles in photoinduced intervalence charge transfers

2019 ◽  
Vol 55 (53) ◽  
pp. 7659-7662 ◽  
Author(s):  
Bruno M. Aramburu-Trošelj ◽  
Paola S. Oviedo ◽  
Ivana Ramírez-Wierzbicki ◽  
Luis M. Baraldo ◽  
Alejandro Cadranel
Keyword(s):  
Electron Donor ◽  
Electron Acceptor ◽  
Ground State ◽  
Mixed Valence ◽  
Donor Acceptor

Upon MLCT photoexcitation, {(tpy)Ru} becomes the electron acceptor in the mixed valence {(tpy˙−)RuIII−δ-NC-MII+δ} moiety, reversing its role as the electron donor in the ground-state mixed valence analogue.

Ultrafast IR spectroscopy of photo-induced electron transfer in self-assembled donor–acceptor coordination cages

2017 ◽  
Vol 19 (21) ◽  
pp. 13596-13603 ◽  
Author(s):  
J. Ahrens ◽  
M. Frank ◽  
G. H. Clever ◽  
D. Schwarzer
Keyword(s):  
Electron Transfer ◽  
Ir Spectroscopy ◽  
Electron Donor ◽  
Electron Acceptor ◽  
Donor Acceptor ◽  
Coordination Cages ◽  
Photo Induced Electron Transfer ◽  
Self Assembled

Photo-excitation of self-assembled palladium based coordination cages consisting of phenothiazine electron donor and anthraquinone electron acceptor ligands produce charge separated states with lifetimes of up to 1.5 ns.

A double B←N bridged bipyridine (BNBP)-based polymer electron acceptor: all-polymer solar cells with a high donor : acceptor blend ratio

2017 ◽  
Vol 1 (5) ◽  
pp. 852-858 ◽  
Author(s):  
Xiaojing Long ◽  
Zicheng Ding ◽  
Chuandong Dou ◽  
Jun Liu ◽  
Lixiang Wang
Keyword(s):  
Solar Cells ◽  
Electron Donor ◽  
Electron Acceptor ◽  
Polymer Solar Cells ◽  
Device Performance ◽  
Blend Ratio ◽  
Donor Acceptor ◽  
Blend Ratios ◽  
High Donor

All-polymer solar cells with P3HT as an electron donor exhibit good device performance with high donor : acceptor blend ratios (w : w, from 0.5 : 1 to 9 : 1).

Donor–acceptor type conjugated copolymers based on alternating BNBP and oligothiophene units: from electron acceptor to electron donor and from amorphous to semicrystalline

2020 ◽  
Vol 8 (40) ◽  
pp. 20998-21006
Author(s):  
Junhui Miao ◽  
Hongxiang Li ◽  
Tao Wang ◽  
Yanchun Han ◽  
Jun Liu ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Electron Donor ◽  
Electron Acceptor ◽  
Donor Acceptor ◽  
Conjugated Copolymers

A series of D–A type conjugated polymers based on alternating BNBP unit and oligothiophene units of various length were developed and served as from electron acceptor to electron donor.

Corannulene-Based Donor-Acceptor-Type Conjugated Polymers with Electrochromic Properties

2021 ◽  
Author(s):  
Jing-Ju Huang ◽  
Hsing-An Lin ◽  
Chi Chen ◽  
Po-Wen Tang ◽  
Shyh-Chyang Luo
Keyword(s):  
Conjugated Polymers ◽  
Electron Donor ◽  
Electron Acceptor ◽  
Color Change ◽  
Material Research ◽  
Electrochromic Properties ◽  
Electrochromic Material ◽  
Wide Range ◽  
Donor Acceptor

π−Conjugated polymers have received increasing attention in electrochromic material research because their color change can be altered over a wide range by introducing electron-donor (D) and electron-acceptor (A) moieties. In...

scholarly journals Synthetic reactions driven by electron-donor–acceptor (EDA) complexes

2021 ◽  
Vol 17 ◽  
pp. 771-799
Author(s):  
Zhonglie Yang ◽  
Yutong Liu ◽  
Kun Cao ◽  
Xiaobin Zhang ◽  
Hezhong Jiang ◽  
...  
Keyword(s):  
Electron Donor ◽  
Ground State ◽  
Transition Metal Catalysts ◽  
External Energy ◽  
The Past ◽  
Dipole Interactions ◽  
Synthetic Reactions ◽  
Donor Acceptor ◽  
External Energy Source ◽  
Eda Complex

The reversible, weak ground-state aggregate formed by dipole–dipole interactions between an electron donor and an electron acceptor is referred to as an electron-donor–acceptor (EDA) complex. Generally, upon light irradiation, the EDA complex turns into the excited state, causing an electron transfer to give radicals and to initiate subsequent reactions. Besides light as an external energy source, reactions involving the participation of EDA complexes are mild, obviating transition metal catalysts or photosensitizers in the majority of cases and are in line with the theme of green chemistry. This review discusses the synthetic reactions concerned with EDA complexes as well as the mechanisms that have been shown over the past five years.

Tuning the Electron Acceptor in Phthalocyanine-Based Electron Donor-Acceptor Conjugates

2015 ◽  
Vol 21 (52) ◽  
pp. 19028-19040 ◽  
Author(s):  
Michael Sekita ◽  
Ángel J. Jiménez ◽  
M. Luisa Marcos ◽  
Esmeralda Caballero ◽  
M. Salomé Rodríguez-Morgade ◽  
...  
Keyword(s):  
Electron Donor ◽  
Electron Acceptor ◽  
Donor Acceptor

Mix and (Mis)match: further studies of the electronic structure and mixed-valence characteristics of 1,4-diethynylbenzene-bridged bimetallic complexes

2020 ◽  
Vol 49 (28) ◽  
pp. 9835-9848
Author(s):  
Parvin Safari ◽  
Stephen A. Moggach ◽  
Paul J. Low
Keyword(s):  
Electronic Structure ◽  
Ground State ◽  
Mixed Valence ◽  
Bimetallic Complexes ◽  
Redox Processes ◽  
Infra Red ◽  
Donor Acceptor ◽  
The One

Infra-red spectroelectrochemical studies of [{Cp′(CO)xM′}(μ-CCC6H4CC){M(PP)Cp′}]n+ [n = 0, 1] illustrate limited ground-state interactions in these donor–acceptor compounds and the localised nature of the one-electron redox processes.

Synthesis and optoelectronic investigations of triarylamines based on naphtho[2,3-f]quinoxaline-7,12-dione core as donor–acceptors for n-type materials

RSC Advances ◽  
2016 ◽  
Vol 6 (65) ◽  
pp. 60084-60093 ◽  
Author(s):  
Azam M. Shaikh ◽  
Bharat K. Sharma ◽  
Sajeev Chacko ◽  
Rajesh M. Kamble
Keyword(s):  
Electron Donor ◽  
Electron Acceptor ◽  
Bond Forming ◽  
Palladium Catalyzed ◽  
Donor Acceptor

We have synthesized a new series of fully characterized donor–acceptor systems (2–7) involving electron donor triarylamines and electron acceptor naphtho[2,3-f]quinoxaline-7,12-dione by employing palladium catalyzed C–N bond forming amination reactions in good yields.

Sign in / Sign up

Export Citation Format

Share Document