Suppressing lithium dendrite formation by slowing its desolvation kinetics

2019 ◽  
Vol 55 (88) ◽  
pp. 13211-13214 ◽  
Author(s):  
Huicong Yang ◽  
Lichang Yin ◽  
Huifa Shi ◽  
Kuang He ◽  
Hui-Ming Cheng ◽  
...  
Keyword(s):  
Energy Barrier ◽  
Desolvation Energy ◽  
Dendrite Formation ◽  
Lithium Dendrite

A higher desolvation energy barrier and slower lithium electrodeposition kinetics tends to inhibit dendrite formation.

scholarly journals Avoiding Dendrite Formation by Confining Lithium Deposition Underneath Li-Sn Coatings

2020 ◽  
Author(s):  
Grace Whang ◽  
Qizhang Yan ◽  
Da Li ◽  
Ziyang Wei ◽  
Danielle M. Butts ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Focused Ion Beam ◽  
Ion Beam ◽  
Research Direction ◽  
Exchange Current ◽  
Atomic Scale ◽  
Interfacial Layers ◽  
Dendrite Formation ◽  
Lithium Deposition ◽  
Lithium Dendrite

<p>The use of interfacial layers to stabilize the lithium surface is a popular research direction for improving the morphology of deposited lithium and suppressing lithium dendrite formation. This work considers a different approach to controlling dendrite formation where lithium is plated underneath an interfacial coating. In the present research, a Li-Sn intermetallic was chosen as a model system due to its lithium-rich intermetallic phases and high Li diffusivity. These coatings also exhibit a significantly higher Li exchange current than bare Li thus leading to better charge transfer kinetics. The exchange current is instrumental in determining whether lithium deposition occurs above or below the Li-Sn coating. High-resolution transmission electron microscopy and cryogenic focused ion beam scanning electron microscopy were used to identify the features associated with Li deposition. Atomic scale simulations provide insight as to the adsorption energies determining the deposition of lithium below the Li-Sn coating. </p>

Inhibition effect of covalently cross-linked gel electrolytes on lithium dendrite formation

2001 ◽  
Vol 46 (8) ◽  
pp. 1201-1205 ◽  
Author(s):  
Tetsu Tatsuma ◽  
Makoto Taguchi ◽  
Noboru Oyama
Keyword(s):  
Inhibition Effect ◽  
Dendrite Formation ◽  
Gel Electrolytes ◽  
Lithium Dendrite

scholarly journals Avoiding Dendrite Formation by Confining Lithium Deposition Underneath Li-Sn Coatings

2020 ◽  
Author(s):  
Grace Whang ◽  
Qizhang Yan ◽  
Da Li ◽  
Ziyang Wei ◽  
Danielle M. Butts ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Focused Ion Beam ◽  
Ion Beam ◽  
Research Direction ◽  
Exchange Current ◽  
Atomic Scale ◽  
Interfacial Layers ◽  
Dendrite Formation ◽  
Lithium Deposition ◽  
Lithium Dendrite

<p>The use of interfacial layers to stabilize the lithium surface is a popular research direction for improving the morphology of deposited lithium and suppressing lithium dendrite formation. This work considers a different approach to controlling dendrite formation where lithium is plated underneath an interfacial coating. In the present research, a Li-Sn intermetallic was chosen as a model system due to its lithium-rich intermetallic phases and high Li diffusivity. These coatings also exhibit a significantly higher Li exchange current than bare Li thus leading to better charge transfer kinetics. The exchange current is instrumental in determining whether lithium deposition occurs above or below the Li-Sn coating. High-resolution transmission electron microscopy and cryogenic focused ion beam scanning electron microscopy were used to identify the features associated with Li deposition. Atomic scale simulations provide insight as to the adsorption energies determining the deposition of lithium below the Li-Sn coating. </p>

scholarly journals Beyond the Polysulfide Shuttle and Lithium Dendrite Formation: Addressing the Sluggish Sulfur Redox Kinetics for Practical High‐Energy Li‐S Batteries

2020 ◽  
Vol 59 (40) ◽  
pp. 17634-17640 ◽  
Author(s):  
Chen Zhao ◽  
Gui‐Liang Xu ◽  
Tianshou Zhao ◽  
Khalil Amine
Keyword(s):  
High Energy ◽  
Dendrite Formation ◽  
Redox Kinetics ◽  
Lithium Dendrite ◽  
Polysulfide Shuttle

Modifying an ultrathin insulating layer to suppress lithium dendrite formation within garnet solid electrolytes

2021 ◽  
Author(s):  
Shijun Tang ◽  
Gui-Wei Chen ◽  
Fucheng Ren ◽  
Hongchun Wang ◽  
Wu Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Electronic Conductivity ◽  
Practical Application ◽  
Insulating Layer ◽  
Dendrite Formation ◽  
Lithium Dendrite

The electronic conductivity of solid electrolytes, which plays an important role in inducing Li dendrite deposition, is a key obstacle to the practical application of Li metal to all-solid-state lithium...

scholarly journals Lithium Dendrites: Inside or Outside: Origin of Lithium Dendrite Formation of All Solid‐State Electrolytes (Adv. Energy Mater. 40/2019)

2019 ◽  
Vol 9 (40) ◽  
pp. 1970155
Author(s):  
Fangjie Mo ◽  
Jiafeng Ruan ◽  
Shuxian Sun ◽  
Zixuan Lian ◽  
Sangpu Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Dendrite Formation ◽  
Lithium Dendrites ◽  
Solid State Electrolytes ◽  
Lithium Dendrite ◽  
Energy Mater

Oxygen-Enriched α-MoO3– nanobelts suppress lithium dendrite formation in stable lithium-metal batteries

2021 ◽  
Vol 507 ◽  
pp. 230306
Author(s):  
Rohan Paste ◽  
Syed Ali Abbas ◽  
Anupriya Singh ◽  
Hong-Cheu Lin ◽  
Chih Wei Chu
Keyword(s):  
Lithium Metal ◽  
Dendrite Formation ◽  
Lithium Metal Batteries ◽  
Lithium Dendrite

Inside or Outside: Origin of Lithium Dendrite Formation of All Solid‐State Electrolytes

2019 ◽  
Vol 9 (40) ◽  
pp. 1902123 ◽  
Author(s):  
Fangjie Mo ◽  
Jiafeng Ruan ◽  
Shuxian Sun ◽  
Zixuan Lian ◽  
Sangpu Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Dendrite Formation ◽  
Solid State Electrolytes ◽  
Lithium Dendrite

Lithium Dendrite Formation in Li/Poly(ethylene oxide)–Lithium Bis(trifluoromethanesulfonyl)imide and N-Methyl-N-propylpiperidinium Bis(trifluoromethanesulfonyl)imide/Li Cells

2010 ◽  
Vol 157 (10) ◽  
pp. A1092 ◽  
Author(s):  
S. Liu ◽  
N. Imanishi ◽  
T. Zhang ◽  
A. Hirano ◽  
Y. Takeda ◽  
...  
Keyword(s):  
Ethylene Oxide ◽  
Dendrite Formation ◽  
Poly Ethylene Oxide ◽  
Lithium Dendrite ◽  
Poly Ethylene

scholarly journals Inhibition of Lithium Dendrite Formation in Lithium Metal Batteries via Regulated Cation Transport through Ultrathin Sub‐Nanometer Porous Carbon Nanomembranes

2021 ◽  
pp. 2100666
Author(s):  
Sathish Rajendran ◽  
Zian Tang ◽  
Antony George ◽  
Andrew Cannon ◽  
Christof Neumann ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Cation Transport ◽  
Lithium Metal ◽  
Dendrite Formation ◽  
Lithium Metal Batteries ◽  
Lithium Dendrite
Sign in / Sign up

Export Citation Format

Share Document