Lithium Dendrite Formation in Li/Poly(ethylene oxide)–Lithium Bis(trifluoromethanesulfonyl)imide and N-Methyl-N-propylpiperidinium Bis(trifluoromethanesulfonyl)imide/Li Cells

2010 ◽  
Vol 157 (10) ◽  
pp. A1092 ◽  
Author(s):  
S. Liu ◽  
N. Imanishi ◽  
T. Zhang ◽  
A. Hirano ◽  
Y. Takeda ◽  
...  
Keyword(s):  
Ethylene Oxide ◽  
Dendrite Formation ◽  
Poly Ethylene Oxide ◽  
Lithium Dendrite ◽  
Poly Ethylene

Effect of nano-silica filler in polymer electrolyte on Li dendrite formation in Li/poly(ethylene oxide)–Li(CF3SO2)2N/Li

2010 ◽  
Vol 195 (19) ◽  
pp. 6847-6853 ◽  
Author(s):  
S. Liu ◽  
N. Imanishi ◽  
T. Zhang ◽  
A. Hirano ◽  
Y. Takeda ◽  
...  
Keyword(s):  
Ethylene Oxide ◽  
Polymer Electrolyte ◽  
Nano Silica ◽  
Dendrite Formation ◽  
Silica Filler ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

scholarly journals Suppression of Lithium Dendrite Growth Using Cross-Linked Polyethylene/Poly(ethylene oxide) Electrolytes: A New Approach for Practical Lithium-Metal Polymer Batteries

2014 ◽  
Vol 136 (20) ◽  
pp. 7395-7402 ◽  
Author(s):  
Rachna Khurana ◽  
Jennifer L. Schaefer ◽  
Lynden A. Archer ◽  
Geoffrey W. Coates
Keyword(s):  
Ethylene Oxide ◽  
Dendrite Growth ◽  
Lithium Metal ◽  
New Approach ◽  
Poly Ethylene Oxide ◽  
Lithium Dendrite ◽  
Poly Ethylene ◽  
Metal Polymer

scholarly journals High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)

2019 ◽  
Vol 116 (38) ◽  
pp. 18815-18821 ◽  
Author(s):  
Henghui Xu ◽  
Po-Hsiu Chien ◽  
Jianjian Shi ◽  
Yutao Li ◽  
Nan Wu ◽  
...  
Keyword(s):  
Solid State ◽  
Ethylene Oxide ◽  
Ion Conductivity ◽  
Composite Electrolyte ◽  
Lithium Anode ◽  
Metallic Lithium ◽  
Poly Ethylene Oxide ◽  
Li Ion ◽  
Lithium Dendrite ◽  
Poly Ethylene

Flexible and low-cost poly(ethylene oxide) (PEO)-based electrolytes are promising for all-solid-state Li-metal batteries because of their compatibility with a metallic lithium anode. However, the low room-temperature Li-ion conductivity of PEO solid electrolytes and severe lithium-dendrite growth limit their application in high-energy Li-metal batteries. Here we prepared a PEO/perovskite Li3/8Sr7/16Ta3/4Zr1/4O3 composite electrolyte with a Li-ion conductivity of 5.4 × 10−5 and 3.5 × 10−4 S cm−1 at 25 and 45 °C, respectively; the strong interaction between the F− of TFSI− (bis-trifluoromethanesulfonimide) and the surface Ta5+ of the perovskite improves the Li-ion transport at the PEO/perovskite interface. A symmetric Li/composite electrolyte/Li cell shows an excellent cyclability at a high current density up to 0.6 mA cm−2. A solid electrolyte interphase layer formed in situ between the metallic lithium anode and the composite electrolyte suppresses lithium-dendrite formation and growth. All-solid-state Li|LiFePO4 and high-voltage Li|LiNi0.8Mn0.1Co0.1O2 batteries with the composite electrolyte have an impressive performance with high Coulombic efficiencies, small overpotentials, and good cycling stability.

The Structure of Radiation Cross-Linked Poly (ethylene oxide) Gels

1971 ◽  
Vol 29 ◽  
pp. 76-77
Author(s):  
C. E. Cluthe ◽  
G. G. Cocks
Keyword(s):  
Molecular Weight ◽  
Ethylene Oxide ◽  
Parallel Plate ◽  
Average Molecular Weight ◽  
Radical Reaction ◽  
Free Radical Reaction ◽  
Nitrogen Gas ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Initial Viscosity

Aqueous solutions of a 1 weight-per cent poly (ethylene oxide) (PEO) were degassed under vacuum, transferred to a parallel plate viscometer under a nitrogen gas blanket, and exposed to Co60 gamma radiation. The Co60 source was rated at 4000 curies, and the dose ratewas 3.8x105 rads/hr. The poly (ethylene oxide) employed in the irradiations had an initial viscosity average molecular weight of 2.1 x 106.The solutions were gelled by a free radical reaction with dosages ranging from 5x104 rads to 4.8x106 rads.

High-Frequency Heating of a Multiply Protonated Poly(ethylene oxide) Chain in a Vacuum

2020 ◽  
Vol 62 (5) ◽  
pp. 578-587
Author(s):  
S. A. Dubrovskii ◽  
N. K. Balabaev
Keyword(s):  
Ethylene Oxide ◽  
High Frequency ◽  
Poly Ethylene Oxide ◽  
Ethylene Oxide Chain ◽  
Poly Ethylene ◽  
Frequency Heating

Preparation of Organized Mesoporous Silica from Sodium Metasilicate Solutions in Alkaline Medium Using Nonionic Surfactants

2003 ◽  
Vol 68 (10) ◽  
pp. 2019-2031 ◽  
Author(s):  
Markéta Zukalová ◽  
Jiří Rathouský ◽  
Arnošt Zukal
Keyword(s):  
Mesoporous Silica ◽  
Ethylene Oxide ◽  
Sodium Metasilicate ◽  
Spherical Particles ◽  
Structure Directing Agent ◽  
Inorganic Species ◽  
Poly Ethylene Oxide ◽  
Acidic Conditions ◽  
Poly Ethylene ◽  
Hydrolysis Of

A new procedure has been developed, which is based on homogeneous precipitation of organized mesoporous silica from an aqueous solution of sodium metasilicate and a nonionic poly(ethylene oxide) surfactant serving as a structure-directing agent. The decrease in pH, which induces the polycondensation of silica, is achieved by hydrolysis of ethyl acetate. Owing to the complexation of Na+ cations by poly(ethylene oxide) segments, assembling of the mesostructure appears to occur under electrostatic control by the S0Na+I- pathway, where S0 and I- are surfactant and inorganic species, respectively. As the complexation of Na+ cations causes extended conformation of poly(ethylene oxide) segments, the pore size and pore volume of organized mesoporous silica increase in comparison with materials prepared under neutral or acidic conditions. The assembling of particles can be fully separated from their solidification, which results in the formation of highly regular spherical particles of mesoporous silica.

Effect of pressure on hydrodynamic properties of poly(ethylene oxide) in deuterated and in non-deuterated solvents

Polymer ◽  
1991 ◽  
Vol 32 (5) ◽  
pp. 904-908 ◽  
Author(s):  
B. Nyström ◽  
K. Olafsen ◽  
J. Roots
Keyword(s):  
Ethylene Oxide ◽  
Hydrodynamic Properties ◽  
Effect Of Pressure ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

Interactions between fenoprofen sodium and poly (ethylene oxide)

1998 ◽  
Vol 46 (1) ◽  
pp. 51-59 ◽  
Author(s):  
T Rades ◽  
C.C Mueller-Goymann
Keyword(s):  
Ethylene Oxide ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene
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