A hydrophobic semiconducting metal–organic framework assembled from silver chalcogenide wires

2020 ◽  
Vol 56 (14) ◽  
pp. 2091-2094 ◽  
Author(s):  
Jia-Yin Wang ◽  
Wen-Hua Li ◽  
Zhong Wei ◽  
Chong Zhang ◽  
Ya-Hui Li ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Metal Organic Framework ◽  
Carboxylate Ligand ◽  
Framework Structure ◽  
Silver Chalcogenide ◽  
Rigid Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

Silver chalcogenide wires are for the first time assembled into a rigid framework structure using a fluorinated carboxylate ligand, where electron transfer along Ag–S chains enables semi-conduction.

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

Selective chemochromic and chemically-induced photochromic response of a metal–organic framework

2020 ◽  
Vol 56 (44) ◽  
pp. 5929-5932 ◽  
Author(s):  
Peng Li ◽  
Qi Sui ◽  
Meng-Yue Guo ◽  
Shuai-Liang Yang ◽  
Ran Bu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electron Acceptor ◽  
Photoinduced Electron Transfer ◽  
Color Change ◽  
Metal Organic Framework ◽  
Confined Space ◽  
Chemically Induced ◽  
Metal Organic ◽  
Organic Framework

The MOF provides unique confined space furnished with electron acceptor sites, and exposure to amines/alcohols causes specific and size-selective direct/UV-assisted color change owing to spontaneous/photoinduced electron transfer.

scholarly journals A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP

2016 ◽  
Vol 7 (47) ◽  
pp. 7199-7203 ◽  
Author(s):  
Hui-Chun Lee ◽  
Markus Antonietti ◽  
Bernhard V. K. J. Schmidt
Keyword(s):  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Metal Organic Framework ◽  
Recyclable Catalyst ◽  
Atom Transfer ◽  
Arget Atrp ◽  
Metal Organic ◽  
Organic Framework

A Cu(ii) MOF can serve as an comprehensive catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) in the synthesis of benzyl methacrylate, styrene, isoprene and 4-vinylpyridine.

Enantiopure vs. racemic metalloligands: impact on metal–organic framework structure and synthesis

2007 ◽  
pp. 4881 ◽  
Author(s):  
Sergio J. Garibay ◽  
Jay R. Stork ◽  
Zhenqiang Wang ◽  
Seth M. Cohen ◽  
Shane G. Telfer
Keyword(s):  
Metal Organic Framework ◽  
Framework Structure ◽  
Metal Organic ◽  
Organic Framework

Metal–organic frameworks: a universal strategy towards super-elastic hydrogels

2019 ◽  
Vol 10 (18) ◽  
pp. 2263-2272 ◽  
Author(s):  
Huaizhi Liu ◽  
Hao Peng ◽  
Yumeng Xin ◽  
Jiuyang Zhang
Keyword(s):  
Drug Delivery ◽  
Mechanical Performance ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
High Loading ◽  
Loading Capacity ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

We reported for the first time using metal–organic framework (MOF) nanoparticles as effective nanofillers to significantly enhance the mechanical performance of hydrogels. The MOF hydrogels have been developed for drug delivery materials with high loading capacity and much extended drug releasing profiles.

Nanoarchitectured metal–organic framework/polypyrrole hybrids for brackish water desalination using capacitive deionization

2019 ◽  
Vol 6 (7) ◽  
pp. 1433-1437 ◽  
Author(s):  
Ziming Wang ◽  
Xingtao Xu ◽  
Jeonghun Kim ◽  
Victor Malgras ◽  
Ran Mo ◽  
...  
Keyword(s):  
Brackish Water ◽  
Metal Organic Framework ◽  
Water Desalination ◽  
Capacitive Deionization ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

Metal–organic framework/polypyrrole hybrids are synthesized and directly used in capacitive deionization for the first time.

scholarly journals Direct evidence of charge separation in a metal–organic framework: efficient and selective photocatalytic oxidative coupling of amines via charge and energy transfer

2018 ◽  
Vol 9 (12) ◽  
pp. 3152-3158 ◽  
Author(s):  
Caiyun Xu ◽  
Hang Liu ◽  
Dandan Li ◽  
Ji-Hu Su ◽  
Hai-Long Jiang
Keyword(s):  
Energy Transfer ◽  
Charge Separation ◽  
Oxidative Coupling ◽  
Direct Evidence ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

For the first time, the photoexcited charge separation in a metal–organic framework has been evidenced with clear ESR signals, based on efficient and selective photocatalytic oxidative coupling of amines.

scholarly journals Facile isolation of a stable S6-symmetric methanol hexamer using the guest-free microporous metal-organic framework: zinc 5-tert-butyl isophthalate

2018 ◽  
Vol 233 (6) ◽  
pp. 429-435
Author(s):  
Samaila A. Jovial ◽  
James Raftery ◽  
Michael W. Anderson ◽  
Martin P. Attfield
Keyword(s):  
Metal Organic Framework ◽  
Structural Effect ◽  
Molecular Clusters ◽  
Ordered Structure ◽  
Framework Structure ◽  
Void Space ◽  
Tert Butyl ◽  
Metal Organic ◽  
Organic Framework

Abstract The ordered structure of the guest-free microporous metal-organic framework zinc 5-tert-butyl isophthalate {Zn[(CH3)3CC6H3(CO2)2]} has been determined and shown to be easily loaded with methanol to form {Zn[(CH3)3CC6H3(CO2)2]}·CH3OH. The methanol forms a S6-symmetric hexamer within the pores of the material that is uniquely defined by the void space and exerts a subtle structural effect on the framework structure of the host. The work demonstrates the use of this type of metal-organic framework as a matrix to isolate unique molecular clusters in a facile manner.

Sign in / Sign up

Export Citation Format

Share Document