Competition between the heavy atom effect and vibronic coupling in donor–bridge–acceptor organometallics

2020 ◽  
Vol 22 (8) ◽  
pp. 4659-4667 ◽  
Author(s):  
Julien Eng ◽  
Stuart Thompson ◽  
Heather Goodwin ◽  
Dan Credgington ◽  
Thomas James Penfold
Keyword(s):  
Excited State ◽  
Quantum Dynamics ◽  
Heavy Atom ◽  
Vibronic Coupling ◽  
Intersystem Crossing ◽  
Heavy Atom Effect ◽  
Metal Amides ◽  
Coinage Metals ◽  
Dynamics Simulations ◽  
Atom Effect

The excited state properties and intersystem crossing dynamics of a series of donor–bridge–acceptor carbene metal-amides based upon the coinage metals Cu, Ag, Au, are investigated using quantum dynamics simulations and supported by photophysical characterisation.

Enhancement of Reverse Intersystem Crossing in Charge‐Transfer Molecule through Internal Heavy Atom Effect

2021 ◽  
pp. 2104646
Author(s):  
Hyung Suk Kim ◽  
Ja Yeon Lee ◽  
Seongjun Shin ◽  
Wonkyo Jeong ◽  
Sang Hoon Lee ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Heavy Atom ◽  
Intersystem Crossing ◽  
Heavy Atom Effect ◽  
Atom Effect

An exceptionally long-lived triplet state of red light-absorbing compact phenothiazine-styrylBodipy electron donor/acceptor dyads: a better alternative to the heavy atom-effect?

2020 ◽  
Vol 56 (11) ◽  
pp. 1721-1724 ◽  
Author(s):  
Yuqi Hou ◽  
Qingyun Liu ◽  
Jianzhang Zhao
Keyword(s):  
Charge Transfer ◽  
Triplet State ◽  
Electron Donor ◽  
Heavy Atom ◽  
Red Light ◽  
Intersystem Crossing ◽  
Spin Orbital ◽  
Heavy Atom Effect ◽  
Donor Acceptor ◽  
Atom Effect

Heavy atom-free dyads showing a red light-absorbing and exceptionally long-lived triplet state based on a spin–orbital charge transfer intersystem crossing mechanism.

Photochemical heavy-atom effect. 9. Spin-orbital effects on the excited-state cycloaddition of 5-acetoacenaphthylene to cyclopentadiene

1979 ◽  
Vol 44 (4) ◽  
pp. 514-519 ◽  
Author(s):  
Timothy E. O'Boyle ◽  
Lou J. Scott ◽  
Benjamin F. Plummer ◽  
P. S. Song
Keyword(s):  
Excited State ◽  
Heavy Atom ◽  
Spin Orbital ◽  
Heavy Atom Effect ◽  
Atom Effect

scholarly journals Intersystem Crossing of Radical Pair in Solvent Cage. External Heavy Atom Effect on Dual Photoreactions of Phthalazine

1991 ◽  
Vol 64 (11) ◽  
pp. 3340-3344 ◽  
Author(s):  
Hiroyasu Inoue ◽  
Tadamitsu Sakurai ◽  
Toshihiko Hoshi ◽  
Jun Okubo ◽  
Isao Ono
Keyword(s):  
Radical Pair ◽  
Heavy Atom ◽  
Intersystem Crossing ◽  
Heavy Atom Effect ◽  
Solvent Cage ◽  
Atom Effect

The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy

2016 ◽  
Vol 15 (2) ◽  
pp. 250-259 ◽  
Author(s):  
Jamaludin Al Anshori ◽  
Tomáš Slanina ◽  
Eduardo Palao ◽  
Petr Klán
Keyword(s):  
Absorption Spectroscopy ◽  
Transient Absorption ◽  
Heavy Atom ◽  
Transient Absorption Spectroscopy ◽  
Intersystem Crossing ◽  
Heavy Atom Effect ◽  
Atom Effect

The extent of intersystem crossing related to the heavy-atom effect of Se and Te atoms was investigated on monosubstituted 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives.

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