Metal-free imidazolium hydrogen carbonate ionic liquids as bifunctional catalysts for the one-pot synthesis of cyclic carbonates from olefins and CO2

2019 ◽  
Vol 21 (14) ◽  
pp. 3834-3838 ◽  
Author(s):  
Jia Liu ◽  
Guoqiang Yang ◽  
Ying Liu ◽  
Dongsheng Wu ◽  
Xingbang Hu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Bifunctional Catalysts ◽  
Cyclic Carbonates ◽  
One Pot ◽  
Metal Free ◽  
Direct Route ◽  
One Pot Synthesis ◽  
Hydrogen Carbonate ◽  
The One

A direct route for the synthesis of cyclic carbonates from olefins and CO2 has been achieved by using imidazolium hydrogen carbonate ionic liquids as bifunctional catalysts in the absence of a solvent.

Direct Propargylation of ortho-Quinone Methides with Alkynyl Zinc Reagents: An Application to the One-Pot Synthesis of 2,3-Disubstituted Benzofurans

Synlett ◽  
2020 ◽  
Vol 31 (08) ◽  
pp. 818-822
Author(s):  
Hongjun Ren ◽  
Manman Sun ◽  
Jinyu Song ◽  
Lei Wang ◽  
Wenguang Yin ◽  
...  
Keyword(s):  
Transition Metal ◽  
Functional Group ◽  
Quinone Methides ◽  
One Pot ◽  
Metal Free ◽  
Efficient Strategy ◽  
One Pot Synthesis ◽  
Subsequent Cyclization ◽  
The One

A transition-metal-free propargylation of ortho-quinone methides (o-QMs) with alkynyl zinc reagents was achieved. A conjugate alkynylation of an o-QM and subsequent cyclization sequence in the presence of KOt-Bu for the synthesis of 2,3-disubstituted benzofurans in one pot was developed. This efficient strategy exhibits good functional-group compatibility and gives moderate to good yields. The present reaction might serve as an attractive method for the synthesis of polysubstituted benzofurans.

One-Pot Multicomponent Synthesis of Imidazole Rings in Acidic Ionic Liquids: A Review

2020 ◽  
Vol 17 (8) ◽  
pp. 975-990
Author(s):  
Cosmas Chinweike Eze ◽  
Mercy Amarachi Ezeokonkwo ◽  
Benjamin Ebere Ezema ◽  
Abraham Efeturi Onoabedje ◽  
Fidelia Ngozika Ibeanu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Multicomponent Synthesis ◽  
One Pot ◽  
Environmentally Sustainable ◽  
Environmental Media ◽  
The Past ◽  
One Pot Synthesis ◽  
Acidic Ionic Liquids ◽  
The One ◽  
Environmentally Friendly Approach

The design of the environmentally friendly approach to the synthesis of biologically important compounds without compromising the yield has been the focus of many chemists in recent years. The development of the one-pot synthesis of heterocycles in the presence of Ionic Liquids (ILs), used as both environmental media and catalysts, is efficient and environmentally sustainable. This review highlights the one-pot synthesis of imidazoles in acidic ILs in the past decade. Some reviews have been conducted on imidazoles, such as their pharmacological importance. Hence, we decided to focus on their synthesis in acidic ionic liquids, which the authors are not aware of any published literature.

Metal-free catalysis for the one-pot synthesis of organic carbamates from amines, CO2, and alcohol at mild condition

2021 ◽  
pp. 131452
Author(s):  
Leizhi Zheng ◽  
Guoqiang Yang ◽  
Jia Liu ◽  
Xingbang Hu ◽  
Zhibing Zhang
Keyword(s):  
Mild Condition ◽  
One Pot ◽  
Metal Free ◽  
One Pot Synthesis ◽  
The One

scholarly journals Pentafluoropropionic Acid: An Efficient and Metal-Free Catalyst for the One-Pot Synthesis of Tetrahydrobenzo[b]pyran Derivatives

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Naser Montazeri ◽  
Taghva Noghani ◽  
Mona Ghorchibeigy ◽  
Rozita Zoghi
Keyword(s):  
Reaction Time ◽  
Aromatic Aldehyde ◽  
One Pot ◽  
Short Reaction Time ◽  
Metal Free ◽  
One Pot Synthesis ◽  
Three Component Reaction ◽  
The One ◽  
High Yields

Pentafluoropropionic acid (PFPA) efficiently catalyzes the one-pot, three-component reaction of aromatic aldehyde, malononitrile, and dimedone to yield tetrahydrobenzo[b]pyran derivatives in high yields. This method is of great value because of its easy processing, short reaction time, environmentally, and high yields.

Transition-metal-free cross-coupling of thioethers with aryl(cyano)iodonium triflates: a facile and efficient method for the one-pot synthesis of thiocyanates

2015 ◽  
Vol 51 (33) ◽  
pp. 7180-7183 ◽  
Author(s):  
Dan Zhu ◽  
Denghu Chang ◽  
Lei Shi
Keyword(s):  
Transition Metal ◽  
Efficient Method ◽  
Bond Cleavage ◽  
Cross Coupling ◽  
One Pot ◽  
Metal Free ◽  
One Pot Synthesis ◽  
One Step ◽  
The One

A novel transition-metal-free method for the one-step synthesis of thiocyanates via the C–S bond cleavage of readily available thioethers was developed.

One-pot Synthesis of Novel 2-(Benzofuran-2-yl)-4-Phenylquinoline-3-Carboxylates

2017 ◽  
Vol 41 (1) ◽  
pp. 45-49
Author(s):  
Wentao Gao ◽  
Xinbo Fu ◽  
Yanan Zhao ◽  
Dongfang Wang
Keyword(s):  
Transition Metal ◽  
Efficient Synthesis ◽  
One Pot ◽  
Metal Free ◽  
One Pot Synthesis ◽  
The One

A facile and efficient synthesis of novel ethyl 2-(benzofuran-2-yl)-4-phenylquinoline-3-carboxylates and the corresponding acids through the one-pot three-step reaction of ethyl 2-(chloromethyl)-4-phenylquinoline-3-carboxylate with a series of salicylaldehydes is described. It allows an efficient and practical access to some 2-(benzofuran-2-yl)quinolines under transition-metal-free conditions.

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