One-pot synthesized core/shell structured zeolite@copper catalysts for selective hydrogenation of ethylene carbonate to methanol and ethylene glycol

2019 ◽  
Vol 21 (19) ◽  
pp. 5414-5426 ◽  
Author(s):  
Yu Ding ◽  
Jingxia Tian ◽  
Wei Chen ◽  
Yejun Guan ◽  
Hao Xu ◽  
...  

Novel hierarchical core/shell structured S-1@Cu with balanced Cu0 and Cu+ active species was synthesized via base-assisted hydrothermal chemistry and served as a robust catalyst for selective EC hydrogenation to methanol.

2015 ◽  
Vol 51 (7) ◽  
pp. 1252-1254 ◽  
Author(s):  
Chao Lian ◽  
Fumin Ren ◽  
Yuxi Liu ◽  
Guofeng Zhao ◽  
Yongjun Ji ◽  
...  

Heterogeneous selective hydrogenation of ethylene carbonate to methanol and ethylene glycol, which provides an opportunity for industrial application of CO2 indirect conversion, was achieved for the first time over a copper chromite nanocatalyst.


RSC Advances ◽  
2016 ◽  
Vol 6 (51) ◽  
pp. 45894-45906 ◽  
Author(s):  
Fengjiao Li ◽  
Liguo Wang ◽  
Xiao Han ◽  
Peng He ◽  
Yan Cao ◽  
...  

Cu/SBA-15 was successfully prepared by ammonia evaporation method and exhibited a high activity for the hydrogenation of ethylene carbonate to co-produce ethylene glycol and methanol.


2018 ◽  
Vol 8 (10) ◽  
pp. 2624-2635 ◽  
Author(s):  
Jingxia Tian ◽  
Wei Chen ◽  
Peng Wu ◽  
Zhirong Zhu ◽  
Xiaohong Li

A Cux–Mgy–Zrz/SiO2 catalyst with a total metal loading of 60 wt% prepared by a deposition–precipitation method was applied for the selective hydrogenation of ethylene carbonate to methanol and ethylene glycol in a fixed-bed reactor.


2019 ◽  
Vol 9 (23) ◽  
pp. 6749-6759 ◽  
Author(s):  
Wei Chen ◽  
Tongyang Song ◽  
Jingxia Tian ◽  
Peng Wu ◽  
Xiaohong Li

The Cu/SiO2 catalyst prepared by the ammonia-evaporation method and further modified with glucose showed greatly enhanced catalytic performance and stability.


2015 ◽  
Vol 51 (72) ◽  
pp. 13776-13778 ◽  
Author(s):  
Xi Chen ◽  
Yuanyuan Cui ◽  
Chao Wen ◽  
Bin Wang ◽  
Wei-Lin Dai

Continuous fixed-bed catalytic hydrogenation of ethylene carbonate (EC) to methanol and ethylene glycol (EG), an emerging synthetic process of methanol via indirect conversion of CO2, was successfully performed over Cu/HMS catalysts prepared by the ammonia evaporation (AE) method.


2021 ◽  
Author(s):  
Chaowei Wang ◽  
Zhe Liu ◽  
Guangfa HU ◽  
Ruimin Gao ◽  
Jianshe Zhao

In this study, the novel magnetic core-shell composites Fe3O4@UiO-66-HPA consisted of magnetic Fe3O4@UiO-66 and active species vanadium-substituted Keggin-type heteropolyacids supported by Zr-MOF were successfully prepared via one pot method and...


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