A novel bicomponent Co3S4/Co@C cocatalyst on CdS, accelerating charge separation for highly efficient photocatalytic hydrogen evolution

2020 ◽  
Vol 22 (1) ◽  
pp. 238-247 ◽  
Author(s):  
Yunpeng Liu ◽  
Bingxiong Wang ◽  
Qiao Zhang ◽  
Siyuan Yang ◽  
Yuhang Li ◽  
...  

Due to the stepwise down energy band structure of Co and Co3S4, the designed Co3S4/Co-CdS exhibits excellent photocatalytic H2 evolution.

2015 ◽  
Vol 3 (23) ◽  
pp. 12482-12499 ◽  
Author(s):  
Amare Aregahegn Dubale ◽  
Chun-Jern Pan ◽  
Andebet Gedamu Tamirat ◽  
Hung-Ming Chen ◽  
Wei-Nien Su ◽  
...  

The energy band structure of Cu2O, Cu2O/CuO and Cu2O/CuO/Ni.


2021 ◽  
Author(s):  
Hanghang Zhou ◽  
Lan Wang ◽  
Hang Shi ◽  
Huan Zhang ◽  
Yue Wang ◽  
...  

Combining different semiconductor materials with diverse geometric structures and energy level configurations is an effective strategy for constructing high-activity heterostructure photocatalyst. Using the solvothermal method, 1D TiO2 nanobelts were uniformly...


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Yunyan Wu ◽  
Pan Xiong ◽  
Jianchun Wu ◽  
Zengliang Huang ◽  
Jingwen Sun ◽  
...  

AbstractGraphitic carbon nitride (g-C3N4)-based photocatalysts have shown great potential in the splitting of water. However, the intrinsic drawbacks of g-C3N4, such as low surface area, poor diffusion, and charge separation efficiency, remain as the bottleneck to achieve highly efficient hydrogen evolution. Here, a hollow oxygen-incorporated g-C3N4 nanosheet (OCN) with an improved surface area of 148.5 m2 g−1 is fabricated by the multiple thermal treatments under the N2/O2 atmosphere, wherein the C–O bonds are formed through two ways of physical adsorption and doping. The physical characterization and theoretical calculation indicate that the O-adsorption can promote the generation of defects, leading to the formation of hollow morphology, while the O-doping results in reduced band gap of g-C3N4. The optimized OCN shows an excellent photocatalytic hydrogen evolution activity of 3519.6 μmol g−1 h−1 for ~ 20 h, which is over four times higher than that of g-C3N4 (850.1 μmol g−1 h−1) and outperforms most of the reported g-C3N4 catalysts.


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