Effects of acid, sodium and its salt counterions on the atomic emission of copper and zinc in plasma pencil

2019 ◽  
Vol 34 (12) ◽  
pp. 2451-2458
Author(s):  
Magda Dvořáková ◽  
Aleš Hrdlička ◽  
Pavel Slavíček ◽  
Viktor Kanický

Copper, zinc and sodium atomic line emissions in the pencil plasma under the influence of easily ionizable elements (EIE), counterions and nitric acid were studied.

2018 ◽  
Vol 30 (1) ◽  
pp. 7-10
Author(s):  
Beata Kuziemska ◽  
Andrzej Wysokiński ◽  
Dawid Jaremko ◽  
Krzysztof Pakuła ◽  
Maria Popek ◽  
...  

Abstract The aim of the research was to evaluate the accumulation level of copper, zinc and nickel in forest mushrooms – Bay Bolete (Xerocomus badius), Saffron Milk Cap (Lactarius deliciosus), Rough-Stemmed Bolete (Leccinum scabrum), Slippery Jack (Suillus luteus) and Parasol Mushroom (Macrolepiota procera). The analysed mushrooms were obtained from growth forests located in the Masovian Voivodeship in the following counties: Siedlce, Sokołów, Łosice and Łuków. Total content of metals was determined using the method of atomic emission spectroscopy with inductively coupled plasma, after the earlier mineralisation of materials ‘by dry combustion’ in a muffle furnace at the temperature of 450°C, and after melting of ash in a 10% solution of HCl. In the soil samples taken from the places where the tested mushrooms occur, pH in 1 mol KCl·dm-3 and total content of copper, zinc and nickel were determined by the ICP-AES method after earlier mineralization in mixture of concentration HCl and HNO3 (3:1) in a microwave system. Test results were statistically analysed with the use of software STATISTICA 12 PL (STATSOFT, TULSA, USA). The analysed mushrooms had diverse content of the determined metals. The highest total average content of copper and zinc was present in Bay Bolete: 34.83 mg ∙ kg-1d.m. for Cu and 155.50 mg ∙ kg-1d.m. for Zn, and the highest average content of nickel was contained in Rough-Stemmed Bolete – 2.98 mg ∙ kg-1d.m.. The lowest average content of copper and zinc was determined in Rough-Stemmed Bolete: 11.98 mg ∙ kg-1d.m. for Cu and 91.90 mg ∙ kg-1d.m. for Zn, and lowest total average content of nickel was present in Bay Bolete – 1.05 mg ∙ kg-1d.m. No excessive accumulation of examined heavy metals was stated in the analysed mushrooms species.


1994 ◽  
Vol 40 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Idris Yücel ◽  
Fikret Arpaci ◽  
Ahmet Özet ◽  
Bülent Döner ◽  
Turan Karayilanoĝlu ◽  
...  

2018 ◽  
Vol 13 (3) ◽  
pp. 612-620
Author(s):  
Filipe Sousa dos Santos ◽  
Eduarda Medran Rangel ◽  
Pedro José Sanches Filho

Abstract Determination of trace metals was carried out in Mangueira Lagoon, in the southern zone of Rio Grande do Sul. Samples were collected at five points to evaluate the concentrations of the following trace metals: copper, zinc, lead, chromium, nickel and iron. Metals were determined by digestion with concentrated nitric acid and pre-concentrated in Chelex 100 resin analyzed by atomic absorption spectrophotometry. In parallel, the physical-chemical parameters pH, chlorides, alkalinity, hardness and organic matter in the water were determined. Potassium and sodium metals were analyzed by atomic emission spectrometry. The analyzes of pH and conductance were analyzed in the field while the others were done in the laboratory of the research group of environmental contaminants (GPCA). Through the results of physical-chemical parameters of the water, the Mangueira Lagoon exhibits a low degree of contamination, but in the future may compromise the biota of the lagoon. Regarding the focus of this work, of Cu, Cr, Fe, Ni, Pb, and Zn (heavy metals), only lead and iron obtained the values above that are established in CONAMA 357/2005.


2009 ◽  
Vol 4 (2) ◽  
Author(s):  
A. Chaudhuri ◽  
M. Mitra ◽  
J.G. Schwarz ◽  
S. Schiewer

Dried raw and protonated biomasses of the brown seaweed Fucus vesiculosus and the red seaweed Gracilaria tikvahiae were used to study their biosorption performance for copper, zinc, nickel, and cobalt. Representative samples of both species were collected from Chincoteague Bay, Virginia. A series of “sorbate” or metal concentrations (10-450 mg L-1) were selected for each metal to compare the seaweeds' biosorption performance at pH 4.5 ± 0.1 and 25±1 °C. Samples were analyzed on Inductively Coupled Plasma-Atomic Emission Spectrometer (ICP-AES). Langmuir and Freundlich adsorption isotherm models for single solute systems were used to assess sorption performance. Both raw and protonated Fucus vesiculosus exhibited higher affinity for metal ions than Gracilaria tikvahiae, at both high and low ends of the concentration ranges. The protonated red seaweed species had maximum metal uptake values of 0.99 mequiv g-1 (copper), 0.39 mequiv g-1 (zinc), 0.66 mequiv g-1 (nickel) and 0.79 mequiv g-1 (cobalt). In comparison, protonated Fucus vesiculosus sorbed higher amounts (1.63, 1.10, 1.40, and 1.69 mequiv g-1 of the metals in the same order). The prospects of using the brown seaweed species in the treatment of industrial wastewaters in place of expensive, conventional ion-exchange resins are envisaged.


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