A polyamine dendritic polymer–copper complex: a reusable catalyst for the additive-free amination of aryl bromides, and iodides

Additive-free synthesis of aryl amines from aryl halides using a reusable water-soluble porphyrin-cored amine-functionalized dendritic polymer copper complex (PPECH–Amine–Cu) catalyst in aqueous media.

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Ferromagnetic nanoparticle-supported copper complex: A highly efficient and reusable catalyst for three-component syntheses of 1,4-disubstituted 1,2,3-triazoles and C-S coupling of aryl halides

Applied Organometallic Chemistry ◽

10.1002/aoc.3714 ◽

2017 ◽

Vol 31 (10) ◽

pp. e3714 ◽

Cited By ~ 9

Author(s):

Mohammad Mehdi Khodaei ◽

Kiumars Bahrami ◽

Farhat Sadat Meibodi

Keyword(s):

Copper Complex ◽

Aryl Halides ◽

Reusable Catalyst ◽

Highly Efficient

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J‐aggregate formation of a water‐soluble porphyrin in acidic aqueous media

The Journal of Chemical Physics ◽

10.1063/1.466109 ◽

1993 ◽

Vol 99 (5) ◽

pp. 4128-4139 ◽

Cited By ~ 321

Author(s):

Osamu Ohno ◽

Youkoh Kaizu ◽

Hiroshi Kobayashi

Keyword(s):

Aqueous Media ◽

Water Soluble ◽

Aggregate Formation ◽

Water Soluble Porphyrin

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Porphyrin Cored Amine Functionalized Dendritic Polymer: An Efficient Reusable Catalyst for Quinoline Synthesis

ChemistrySelect ◽

10.1002/slct.201901012 ◽

2019 ◽

Vol 4 (19) ◽

pp. 5897-5902 ◽

Cited By ~ 3

Author(s):

G. Avudaiappan ◽

V. Unnikrishnan ◽

Jisha J. Pillai ◽

K. Sreekumar

Keyword(s):

Reusable Catalyst ◽

Dendritic Polymer ◽

Amine Functionalized

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Self-Healing Polymer-Clay Hybrids by Facile Complexation of a Waterborne Polymer with a Clay

Materials Advances ◽

10.1039/d1ma00099c ◽

2021 ◽

Author(s):

Aranee Pleng Teepakakorn ◽

Makoto Ogawa

Keyword(s):

Vinyl Alcohol ◽

Aqueous Media ◽

Water Soluble ◽

Poly Vinyl Alcohol ◽

Self Healing ◽

Soluble Polymer ◽

Water Soluble Polymer ◽

Smectite Clay

Water-induced self-healing materials were prepared by the hybridization of a water-soluble polymer, poly(vinyl alcohol), with a smectite clay by mixing in an aqueous media and subsequent casting. Without using chemical...

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Dissociation of imino proton(s) of a highly water-soluble metal-free phthalocyanine and determination of its pKa value in water

Journal of Porphyrins and Phthalocyanines ◽

10.1142/s1088424613500235 ◽

2013 ◽

Vol 17 (06n07) ◽

pp. 447-453 ◽

Cited By ~ 2

Author(s):

Hiroaki Isago ◽

Harumi Fujita

Keyword(s):

Aqueous Media ◽

Thermal Reaction ◽

Water Soluble ◽

Acid Dissociation ◽

Acid Dissociation Constant ◽

Metal Free ◽

Imino Proton ◽

Pka Value ◽

Triton X

Dissociation of imino proton(s) in the cavity of the macrocycle of a highly water-soluble, metal-free phthalocyanine ( H 2( H 4 tsppc ); where H 4 tsppc denotes tetrakis{(2′,6′-dimethyl-4′-sulfonic acid)phenoxy}phthalocyaninate) in ethanolic and aqueous solutions has spectrophotometrically been investigated. The spectral changes associated with reaction with NaOH have been found to involve one-proton transfer process in aqueous media while two-protons process in ethanolic media. The acid-dissociation constant of the first imino proton in water (in the presence of Triton X-100) has been determined to be 12.5 ± 0.2 (as pKa) at 25 °C. The doubly deprotonated species in EtOH has been easily converted to its corresponding cobalt(II) derivative by thermal reaction with anhydrous CoCl 2.

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