Constructing consistent pore microstructures of bacterial cellulose-derived cathode and anode materials for high energy density sodium-ion capacitors

2020 ◽  
Vol 44 (5) ◽  
pp. 1865-1871 ◽  
Author(s):  
Tianyun Zhang ◽  
Fujuan Wang ◽  
Liang Yang ◽  
Hongxia Li ◽  
Jiangtao Chen ◽  
...  

Bacterial cellulose-derived cathode and anode with similar carbon microstructure are well match in kinetic for high energy density sodium-ion capacitor.

Author(s):  
Chenrui Zhang ◽  
Tingting Liang ◽  
Huilong Dong ◽  
Junjun Li ◽  
Junyu Shen ◽  
...  

Sodium-ion batteries (SIBs) have been considered as promising candidates for large-scale energy storage. However, viable anode materials still suffer from sluggish electrochemical reaction kinetics and huge volume expansion during cycling,...


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Qiulong Wei ◽  
Qidong Li ◽  
Yalong Jiang ◽  
Yunlong Zhao ◽  
Shuangshuang Tan ◽  
...  

AbstractHigh-performance and low-cost sodium-ion capacitors (SICs) show tremendous potential applications in public transport and grid energy storage. However, conventional SICs are limited by the low specific capacity, poor rate capability, and low initial coulombic efficiency (ICE) of anode materials. Herein, we report layered iron vanadate (Fe5V15O39 (OH)9·9H2O) ultrathin nanosheets with a thickness of ~ 2.2 nm (FeVO UNSs) as a novel anode for rapid and reversible sodium-ion storage. According to in situ synchrotron X-ray diffractions and electrochemical analysis, the storage mechanism of FeVO UNSs anode is Na+ intercalation pseudocapacitance under a safe potential window. The FeVO UNSs anode delivers high ICE (93.86%), high reversible capacity (292 mAh g−1), excellent cycling stability, and remarkable rate capability. Furthermore, a pseudocapacitor–battery hybrid SIC (PBH-SIC) consisting of pseudocapacitor-type FeVO UNSs anode and battery-type Na3(VO)2(PO4)2F cathode is assembled with the elimination of presodiation treatments. The PBH-SIC involves faradaic reaction on both cathode and anode materials, delivering a high energy density of 126 Wh kg−1 at 91 W kg−1, a high power density of 7.6 kW kg−1 with an energy density of 43 Wh kg−1, and 9000 stable cycles. The tunable vanadate materials with high-performance Na+ intercalation pseudocapacitance provide a direction for developing next-generation high-energy capacitors.


Author(s):  
Jiefei Liu ◽  
Kangshou Lin ◽  
Yu Zhou ◽  
Yu Zhou ◽  
Xianhua Hou ◽  
...  

The sodium super ionic conductor (NASICON) materials are considered as the attractive cathode in sodium-ion batteries. Although the three-electron reactions in Na3MnTi(PO4)3 have greatly enhanced the capacity of NASICON-structure materials,...


Author(s):  
Congkai Sun ◽  
Xiong Zhang ◽  
Chen Li ◽  
Kai Wang ◽  
Xianzhong Sun ◽  
...  

Author(s):  
Qi Zhang ◽  
Xuan-Wen Gao ◽  
Ying Shi ◽  
Wen-Bin Luo ◽  
Yang Li ◽  
...  

Nanoscale ◽  
2021 ◽  
Vol 13 (37) ◽  
pp. 15781-15788
Author(s):  
Liaona She ◽  
Feng Zhang ◽  
Congying Jia ◽  
Liping Kang ◽  
Qi Li ◽  
...  

Ti2Nb2O9/CNF anode with excellent sodium storage performance is fabricated by electrospinning and carbonization treatment. The assembled Ti2Nb2O9/CNF//AC SIC exhibits a high energy density of 129 W h kg-1 at 75 W kg-1.


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