A visible-light-induced cascade reaction of etherification/C–C cyclization: efficient synthesis of dibenzo[b,d]oxepin-7(6H)-ones

2019 ◽  
Vol 17 (13) ◽  
pp. 3324-3327 ◽  
Author(s):  
Wanyong Fu ◽  
Aixia Yu ◽  
Hongshuo Jiang ◽  
Minghui Zuo ◽  
Hongfeng Wu ◽  
...  

A visible-light-induced palladium-catalyzed cascade reaction was developed by etherification/C–C coupling cyclization of α-bromoacetophenones with phenols.

Synthesis ◽  
2018 ◽  
Vol 51 (02) ◽  
pp. 522-529 ◽  
Author(s):  
Deqing Shi ◽  
Lingna Wang ◽  
Tiancong Ma ◽  
Mingming Qiao ◽  
Qiangxian Wu ◽  
...  

A visible-light photoredox-catalyzed oxidation/[3+2] cycloaddition/oxidative aromatization cascade reaction of [(3,4-dihydroisoquinolin-2(1H)-yl)methyl]phosphonates and activated olefins or alkynes for the efficient synthesis of potentially biological active pyrrolo[2,1-a]isoquinoline-substituted phosphonates was developed. This transformation features mild reaction conditions (i.e., visible light irradiation, room temperature), molecular oxygen (O2) as a green oxidant, simple ‘one-pot’ operation.


Author(s):  
Fan Teng ◽  
Juan Du ◽  
Changping Xun ◽  
Mengxue Zhu ◽  
Ziqin Lu ◽  
...  

A visible-light-promoted radical cascade reaction of N-arylacrylamide and cyclobutanone oxime esters with sulfur dioxide insertion is established.


RSC Advances ◽  
2014 ◽  
Vol 4 (72) ◽  
pp. 38258-38262 ◽  
Author(s):  
Langxi Hu ◽  
Weijun Gui ◽  
Zichen Liu ◽  
Baishan Jiang

A three-component cascade reaction involving gem-dibromovinylanilines, tert-butyl isocyanide and arylboronic acids for the efficient synthesis of 3-aryl-2-aminoquinolines has been developed.


2020 ◽  
Vol 17 (12) ◽  
pp. 944-950
Author(s):  
Shangrong Zhu ◽  
Xuechen Lu ◽  
Qiuneng Xu ◽  
Jian Li ◽  
Shenghu Yan

A straightforward and efficient synthesis of acridine derivatives via a copper-catalyzed cascade reaction among isoxazoles and diaryliodonium salts is achieved. Various mono-, multi-substituted and 9-substituted acridine derivatives could be obtained in moderate to good yields. The process has gone through tandem double arylation and Friedel-Crafts reactions.


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