Alloying in inverse CeO2/Pd nanoparticles to enhance the electrocatalytic activity for the formate oxidation reaction

2019 ◽  
Vol 7 (40) ◽  
pp. 22996-23007 ◽  
Author(s):  
Quan Tang ◽  
Fuyi Chen ◽  
Tao Jin ◽  
Longfei Guo ◽  
Qiao Wang ◽  
...  
Keyword(s):  
Electrocatalytic Activity ◽  
Oxidation Reaction ◽  
Electronic Effect ◽  
Pd Nanoparticles ◽  
Pd Catalysts ◽  
Formate Oxidation

Inverse CeO2/Pd catalysts with Pd/Ce alloying enhanced FOR activity by the electronic effect of Ce and the oxophilic effect of CeO2.

Graphene-based porous carbon-Pd/SnO2 nanocomposites with enhanced electrocatalytic activity and durability for methanol oxidation

2016 ◽  
Vol 4 (22) ◽  
pp. 8898-8904 ◽  
Author(s):  
Lirui Nan ◽  
Zetan Fan ◽  
Wenbo Yue ◽  
Qiao Dong ◽  
Lisha Zhu ◽  
...  
Keyword(s):  
Methanol Oxidation ◽  
Porous Carbon ◽  
Electrocatalytic Activity ◽  
Pd Nanoparticles ◽  
Pd Catalysts ◽  
Supported Pd Catalysts ◽  
Supported Pd

Pd nanoparticles with a trace of SnO2 are prepared on a novel graphene-based porous carbon and they show dramatically improved electrocatalytic activity and durability for methanol oxidation compared to porous carbon supported Pd catalysts with SnO2 or graphene-based porous carbon supported Pd catalysts without SnO2.

Component-Dependent Electrocatalytic Activity of Ultrathin PdRh Alloy Nanocrystals for the Formate Oxidation Reaction

2018 ◽  
Vol 7 (2) ◽  
pp. 2830-2836 ◽  
Author(s):  
Juan Bai ◽  
Qi Xue ◽  
Yue Zhao ◽  
Jia-Xing Jiang ◽  
Jing-Hui Zeng ◽  
...  
Keyword(s):  
Electrocatalytic Activity ◽  
Oxidation Reaction ◽  
Alloy Nanocrystals ◽  
Formate Oxidation

scholarly journals Effect of Pd on the Electrocatalytic Activity of Pt towards Oxidation of Ethanol in Alkaline Solutions

2021 ◽  
Vol 11 (3) ◽  
pp. 1315
Author(s):  
Salma Jadali ◽  
Mohammad Ali Kamyabi ◽  
José Solla-Gullón ◽  
Enrique Herrero
Keyword(s):  
Photoelectron Spectroscopy ◽  
Electrocatalytic Activity ◽  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Aldol Condensation ◽  
Pd Nanoparticles ◽  
Alkaline Media ◽  
Alkaline Solutions ◽  
Ethanol Oxidation Reaction ◽  
X Ray

The understanding of electrocatalytic activity and poisoning resistance properties of Pt and Pd nanoparticles, recognized as the best electrocatalysts for the ethanol oxidation reaction, is an essential step for the commercialization of direct ethanol fuel cells (DEFCs). In this paper, mono and bimetallic Pt and Pd nanoparticles with different atomic ratios have been synthesized to study their electrocatalytic properties for an ethanol oxidation reaction in alkaline solutions. The different nanoparticles were physiochemically characterized by transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The electrochemical characterization was performed by cyclic voltammetry and chronoamperometry measurements. The electrochemical measurements indicate that Pt nanoparticles have much higher electrocatalytic activity for ethanol oxidation than Pd nanoparticles. The studies with bimetallic PtPd nanoparticles showed a significant impact of their composition on the ethanol oxidation. Thus, the highest electrocatalytic activity and poisoning resistance properties were obtained for Pt3Pd2 nanoparticles. Moreover, this study demonstrates that the poisoning of the catalyst surface through ethanol oxidation is related to the prevalence of the acetaldehyde–acetate route and the polymerization of acetaldehyde through aldol condensation in the alkaline media.

Remarkable electrocatalytic activity of Pd nanoparticles dispersed on polyaniline-polydiphenylamine copolymer nanocomposite for methanol and ethanol oxidation reaction

2021 ◽  
Vol 281 ◽  
pp. 116925
Author(s):  
Suba Lakshmi Madaswamy ◽  
M. Alfakeer ◽  
Aboud Ahmed Awadh Bahajjaj ◽  
Mohamed Ouladsmane ◽  
Saikh Mohammad Wabaidur ◽  
...  
Keyword(s):  
Electrocatalytic Activity ◽  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Pd Nanoparticles ◽  
Ethanol Oxidation Reaction

Surface Pourbaix diagrams of AgPd nanoalloys and its application in formate oxidation reaction

2021 ◽  
pp. 138465
Author(s):  
Zhen Li ◽  
Fuyi Chen ◽  
Weiqi Bian ◽  
Bo Kou ◽  
Qiao Wang ◽  
...  
Keyword(s):  
Oxidation Reaction ◽  
Pourbaix Diagrams ◽  
Formate Oxidation

Catalytic activity of palladium-doped silver dilute nanoalloys for formate oxidation from a theoretical perspective

2019 ◽  
Vol 21 (40) ◽  
pp. 22598-22610 ◽  
Author(s):  
Nan Zhang ◽  
Fuyi Chen ◽  
Longfei Guo
Keyword(s):  
Catalytic Activity ◽  
Oxidation Reaction ◽  
Theoretical Perspective ◽  
Single Atom ◽  
High Catalytic Activity ◽  
Formate Oxidation ◽  
First Time ◽  
Single Atom Alloys

We demonstrate for the first time that the Pd1Ag single-atom alloys exhibit a high catalytic activity for formate oxidation reaction.

Sign in / Sign up

Export Citation Format

Share Document