Core–shell nanoporous AuCu3@Au monolithic electrode for efficient electrochemical CO2 reduction

2020 ◽  
Vol 8 (6) ◽  
pp. 3344-3350 ◽  
Author(s):  
Xiaoming Ma ◽  
Yongli Shen ◽  
Shuang Yao ◽  
Cuihua An ◽  
Weiqing Zhang ◽  
...  
Keyword(s):  
High Efficiency ◽  
Co2 Reduction ◽  
Core Shell ◽  
Electrocatalytic Reduction ◽  
Oxidative Etching ◽  
Electrochemical Co2 Reduction

Monolithic bulk nanoporous core–shell AuCu3@Au has been synthesized through a facile oxidative etching of the Au20Cu80 alloy, which exhibits high efficiency for the electrocatalytic reduction of CO2 in a broad potential window.

Synergized Cu/Pb Core/Shell Electrocatalyst for High-Efficiency CO2 Reduction to C2+ Liquids

ACS Nano ◽  
2020 ◽  
Author(s):  
Pengtang Wang ◽  
Hao Yang ◽  
Yong Xu ◽  
Xiaoqing Huang ◽  
Juan Wang ◽  
...  
Keyword(s):  
High Efficiency ◽  
Co2 Reduction ◽  
Core Shell

Bromine anion mediated epitaxy growth of core-shell Pd@Ag towards efficient electrochemical CO2 reduction

2021 ◽  
Author(s):  
Yinqiong Wu ◽  
Jiachang Zeng ◽  
Yang Yang ◽  
Zhaojie Li ◽  
Wenbiao Zhang ◽  
...  
Keyword(s):  
Noble Metal ◽  
Co2 Reduction ◽  
Core Shell ◽  
Metal Core ◽  
Shell Nanostructures ◽  
Electrochemical Co2 Reduction

Noble-metal core-shell nanostructures are promising electrocatalysts for CO2 reduction thanks to their interfacial configurations beneficial for electrocatalytic kinetics, but are severely limited to few couples that require tiny lattice mismatches...

Selective electrochemical CO2 reduction over highly porous gold films

2017 ◽  
Vol 5 (41) ◽  
pp. 21955-21964 ◽  
Author(s):  
Chengzhen Chen ◽  
Bo Zhang ◽  
Juhua Zhong ◽  
Zhenmin Cheng
Keyword(s):  
Co2 Reduction ◽  
Gold Films ◽  
Electrocatalytic Reduction ◽  
Porous Gold ◽  
Electrochemical Co2 Reduction ◽  
Competitive Reduction ◽  
Highly Porous

Electrocatalytic reduction of CO2 to CO is usually subject to the competitive reduction of H+ to hydrogen.

Rapidly synthesizing gold-palladium core-shell aerogels for selective and robust electrochemical CO2 reduction

2021 ◽  
Author(s):  
Ran Du ◽  
Wei Jin ◽  
Hengbo Wu ◽  
René Hübner ◽  
Lin Zhou ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Noble Metal ◽  
Noble Metals ◽  
Co2 Reduction ◽  
Core Shell ◽  
High Catalytic Activity ◽  
Electrochemical Co2 Reduction

Noble metal aerogels (NMAs), one of the youngest members in the aerogel family, have drawn increasing attention in the last decade. Featuring the high catalytic activity of noble metals and...

Ce-doped Bi based catalysts for highly efficient electroreduction of CO2 to formate

2021 ◽  
Author(s):  
De-Huang Zhuo ◽  
Qing-Song Chen ◽  
Xiu-Hui Zhao ◽  
Yin-Long Jiang ◽  
Jian Lu ◽  
...  
Keyword(s):  
Shell Structure ◽  
Metal Organic Frameworks ◽  
Co2 Reduction ◽  
Core Shell ◽  
Excellent Performance ◽  
Highly Efficient ◽  
Electrochemical Co2 Reduction ◽  
Metal Organic ◽  
Core Shell Structure ◽  
Novel Catalyst

Ce-Bi@CeBiOx/C with core-shell structure has been synthesized by pyrolysis of cerium doped bismuth-based metal-organic frameworks. This novel catalyst exhibits excellent performance for electrochemical CO2 reduction to formate with a maximum...

Boosting Tunable Syngas Formation via Electrochemical CO2 Reduction on Cu/In2O3 Core/Shell Nanoparticles

2018 ◽  
Vol 10 (43) ◽  
pp. 36996-37004 ◽  
Author(s):  
Huan Xie ◽  
Shaoqing Chen ◽  
Feng Ma ◽  
Jiashun Liang ◽  
Zhengpei Miao ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Core Shell ◽  
Shell Nanoparticles ◽  
Electrochemical Co2 Reduction ◽  
Core Shell Nanoparticles

scholarly journals Core-Shell ZnO@Cu2O as Catalyst to Enhance the Electrochemical Reduction of Carbon Dioxide to C2 Products

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 535
Author(s):  
Shuaikang Zhu ◽  
Xiaona Ren ◽  
Xiaoxue Li ◽  
Xiaopo Niu ◽  
Miao Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Current Density ◽  
High Selectivity ◽  
Co2 Reduction ◽  
Flow Cell ◽  
Core Shell ◽  
Electrochemical Co2 Reduction ◽  
Total Current Density ◽  
Core Shell Structure ◽  
Copper Based Catalyst

The copper-based catalyst is considered to be the only catalyst for electrochemical carbon dioxide reduction to produce a variety of hydrocarbons, but its low selectivity and low current density to C2 products restrict its development. Herein, a core-shell xZnO@yCu2O catalysts for electrochemical CO2 reduction was fabricated via a two-step route. The high selectivity of C2 products of 49.8% on ZnO@4Cu2O (ethylene 33.5%, ethanol 16.3%) with an excellent total current density of 140.1 mA cm−2 was achieved over this core-shell structure catalyst in a flow cell, in which the C2 selectivity was twice that of Cu2O. The high electrochemical activity for ECR to C2 products was attributed to the synergetic effects of the ZnO core and Cu2O shell, which not only enhanced the selectivity of the coordinating electron, improved the HER overpotential, and fastened the electron transfer, but also promoted the multielectron involved kinetics for ethylene and ethanol production. This work provides some new insights into the design of highly efficient Cu-based electrocatalysts for enhancing the selectivity of electrochemical CO2 reduction to produce high-value C2 products.

Sign in / Sign up

Export Citation Format

Share Document