Synergized Cu/Pb Core/Shell Electrocatalyst for High-Efficiency CO2 Reduction to C2+ Liquids

ACS Nano ◽  
2020 ◽  
Author(s):  
Pengtang Wang ◽  
Hao Yang ◽  
Yong Xu ◽  
Xiaoqing Huang ◽  
Juan Wang ◽  
...  
2020 ◽  
Vol 8 (6) ◽  
pp. 3344-3350 ◽  
Author(s):  
Xiaoming Ma ◽  
Yongli Shen ◽  
Shuang Yao ◽  
Cuihua An ◽  
Weiqing Zhang ◽  
...  

Monolithic bulk nanoporous core–shell AuCu3@Au has been synthesized through a facile oxidative etching of the Au20Cu80 alloy, which exhibits high efficiency for the electrocatalytic reduction of CO2 in a broad potential window.


2021 ◽  
Vol 46 (11) ◽  
pp. 7772-7781 ◽  
Author(s):  
Shasha Dou ◽  
Wanyu Zhang ◽  
Yuting Yang ◽  
Shuqing Zhou ◽  
Xianfa Rao ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
H. Rajabi-Moghaddam ◽  
M. R. Naimi-Jamal ◽  
M. Tajbakhsh

AbstractIn the present work, an attempt has been made to synthesize the 1,2,3-triazole derivatives resulting from the click reaction, in a mild and green environment using the new copper(II)-coated magnetic core–shell nanoparticles Fe3O4@SiO2 modified by isatoic anhydride. The structure of the catalyst has been determined by XRD, FE-SEM, TGA, VSM, EDS, and FT-IR analyzes. The high efficiency and the ability to be recovered and reused for at least up to 6 consecutive runs are some superior properties of the catalyst.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Ji-Yong Kim ◽  
Deokgi Hong ◽  
Jae-Chan Lee ◽  
Hyoung Gyun Kim ◽  
Sungwoo Lee ◽  
...  

AbstractFor steady electroconversion to value-added chemical products with high efficiency, electrocatalyst reconstruction during electrochemical reactions is a critical issue in catalyst design strategies. Here, we report a reconstruction-immunized catalyst system in which Cu nanoparticles are protected by a quasi-graphitic C shell. This C shell epitaxially grew on Cu with quasi-graphitic bonding via a gas–solid reaction governed by the CO (g) - CO2 (g) - C (s) equilibrium. The quasi-graphitic C shell-coated Cu was stable during the CO2 reduction reaction and provided a platform for rational material design. C2+ product selectivity could be additionally improved by doping p-block elements. These elements modulated the electronic structure of the Cu surface and its binding properties, which can affect the intermediate binding and CO dimerization barrier. B-modified Cu attained a 68.1% Faradaic efficiency for C2H4 at −0.55 V (vs RHE) and a C2H4 cathodic power conversion efficiency of 44.0%. In the case of N-modified Cu, an improved C2+ selectivity of 82.3% at a partial current density of 329.2 mA/cm2 was acquired. Quasi-graphitic C shells, which enable surface stabilization and inner element doping, can realize stable CO2-to-C2H4 conversion over 180 h and allow practical application of electrocatalysts for renewable energy conversion.


Chemosphere ◽  
2017 ◽  
Vol 183 ◽  
pp. 528-535 ◽  
Author(s):  
Huilin You ◽  
Zheng Wu ◽  
Yanmin Jia ◽  
Xiaoli Xu ◽  
Yuntao Xia ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 3798-3802 ◽  
Author(s):  
Jinliang Lin ◽  
Rongying Liao ◽  
Junli Xu

A high efficiency photocatalytic conversion of CO2 into CO has been achieved by construction of a binary liquid system.


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