scholarly journals Using nanoconfinement to inhibit the degradation pathways of conversion-metal oxide anodes for highly stable fast-charging Li-ion batteries

2020 ◽  
Vol 8 (5) ◽  
pp. 2712-2727 ◽  
Author(s):  
Benjamin Ng ◽  
Xiong Peng ◽  
Ehsan Faegh ◽  
William E. Mustain

Nanostructured hybrids that physically encapsulate highly morphable, high capacity Li-ion battery anodes can potentially enable much longer cycle life than straightforward deployment of the same chemistry.

2015 ◽  
Vol 3 (30) ◽  
pp. 15403-15407 ◽  
Author(s):  
Xizheng Liu ◽  
De Li ◽  
Songyan Bai ◽  
Haoshen Zhou

Magnetic Fe3O4 particles are used as the binder in a Li-ion battery. This new battery gives a long cycle life and can work well even after intensive vibration. The electrode is fabricated in a liquid-free process and can be easily recycled after battery disposal. It decrease the total cost and pollutant emission over the whole battery life.


RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24320-24330 ◽  
Author(s):  
Junkai He ◽  
Ying Liu ◽  
Yongtao Meng ◽  
Xiangcheng Sun ◽  
Sourav Biswas ◽  
...  

A new one-step microwave method was designed for synthesis of rGO/Co3O4, and the Li-ion battery showed high capacity and long life.


Nanoscale ◽  
2021 ◽  
Vol 13 (37) ◽  
pp. 15624-15630
Author(s):  
Jinyun Liu ◽  
Ting Zhou ◽  
Yan Wang ◽  
Tianli Han ◽  
Chaoquan Hu ◽  
...  

A novel nanosphere-confined one-dimensional yolk–shell anode is developed for Li-ion batteries.


2020 ◽  
Vol 8 (35) ◽  
pp. 18132-18142 ◽  
Author(s):  
Tahar Azib ◽  
Nicolas Bibent ◽  
Michel Latroche ◽  
Florent Fischer ◽  
Jean-Claude Jumas ◽  
...  

High-capacity Si-based anodes with good coulombic efficiency and long-cycle life are achieved by embedding silicon nanoparticles in dual Ni3Sn4/Ni3Sn2 active/inactive intermetallic matrix.


2014 ◽  
Vol 1678 ◽  
Author(s):  
Masaharu Shiratani ◽  
Kunihiro Kamataki ◽  
Giichiro Uchida ◽  
Kazunori Koga ◽  
Hyunwoong Seo ◽  
...  

ABSTRACTWe present here performance of Li ion batteries with SiC nanoparticle-film anode, which is fabricated by a double multi-hollow discharge plasma chemical vapor deposition (CVD) method. The first cycle of charge/discharge property of the Li ion battery with the SiC nanoparticle-film anode shows a high capacity of over 4,000 mAh/g, which is 12 times higher than the Li ion battery with the conventional graphite anode. The discharge capacity shows high stability for first 10th cycle, and is 3750 mAh/g for the 10th cycle.


2020 ◽  
Vol 117 (47) ◽  
pp. 29453-29461
Author(s):  
Hansen Wang ◽  
Yangying Zhu ◽  
Sang Cheol Kim ◽  
Allen Pei ◽  
Yanbin Li ◽  
...  

Rechargeability and operational safety of commercial lithium (Li)-ion batteries demand further improvement. Plating of metallic Li on graphite anodes is a critical reason for Li-ion battery capacity decay and short circuit. It is generally believed that Li plating is caused by the slow kinetics of graphite intercalation, but in this paper, we demonstrate that thermodynamics also serves a crucial role. We show that a nonuniform temperature distribution within the battery can make local plating of Li above 0 V vs. Li0/Li+(room temperature) thermodynamically favorable. This phenomenon is caused by temperature-dependent shifts of the equilibrium potential of Li0/Li+. Supported by simulation results, we confirm the likelihood of this failure mechanism during commercial Li-ion battery operation, including both slow and fast charging conditions. This work furthers the understanding of nonuniform Li plating and will inspire future studies to prolong the cycling lifetime of Li-ion batteries.


2016 ◽  
Vol 301 ◽  
pp. 41-46 ◽  
Author(s):  
Jicheng Zhang ◽  
Shibing Ni ◽  
Jianjun Ma ◽  
Xuelin Yang ◽  
Lulu Zhang

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