Two-dimensional MXene modified AgNRs as a surface-enhanced Raman scattering substrate for sensitive determination of polychlorinated biphenyls

The Analyst ◽  
2020 ◽  
Vol 145 (22) ◽  
pp. 7421-7428
Author(s):  
Xuejiao Fang ◽  
Yuhang Song ◽  
Yi Huang ◽  
Guohai Yang ◽  
Caiqin Han ◽  
...  

A MXene/AgNR substrate was prepared through a facile modification strategy. The substrate can perform sensitive SERS detection of polychlorinated biphenyls, which may have potential in environmental monitoring at the point of need.

2021 ◽  
Vol 2114 (1) ◽  
pp. 012084
Author(s):  
Hammad R. Humud ◽  
Fatimah Jumaah Moaen

Abstract The current study examines recent advancements in surface-enhanced Raman scattering (SERS), a technique that employs flexible surfaces as an active substrate, this surfaces consist from two-dimensional thermo-plasmonic grating. With 53 nm Au layer (was deposited on the 2D grating structure of the PDMS by the PVD method). The explosive wire technique was used to preparing Ag nanoparticles that were used for the purpose of SERS. The effect of the plasmonic nanostructures on the absorption spectra and Surface - Enhanced Raman Scattering (SERS) activities was examined. Rhodamine 6G dye was used as a probe molecule. X-Ray diffraction (XRD) was used to examine the structural characteristics of the nanoparticles. The morphology was assessed using Field Emission Scanning Electron Microscopy(FESEM). A twin beam UV-Vis Spectrophotometer was used to measure the absorption of the combined Rh6G dye (concentration 1×10“–6M) with the nanostructures. a Sunshine Raman microscope system and a 50mm objective lens, used for investigating the Raman spectra of the Rh6G combined with nanostructures. The results showed that the enhancement factor (EF) for SERS of R6G (1×M) reached to (2.2×10 3) When using Ag nanoparticles and (0.08 × 103) when R6G deposited directly on the flexible substrates without nanostructures at the wave number (1650 cm−1), we produced a recyclable, homogeneous, and highly sensitive SERS substrate with dependable reproducibility. For the SERS substrate, a surface made up of two-dimensional (2D) flexible grating substrates was chosen to provide multiple modalities in electrical and medicinal applications.


2018 ◽  
Vol 42 (21) ◽  
pp. 17750-17755 ◽  
Author(s):  
Ruoxuan Jiang ◽  
Wei Xu ◽  
Yifang Wang ◽  
Shaoming Yu

Silver porous nanostructures with tunable porosity were fabricated as an excellent enhancing substrate for SERS detection of trace pesticide residues.


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