Are ionic liquids and liquid coordination complexes really different? – Synthesis, characterization, and catalytic activity of AlCl3/base catalysts

2020 ◽  
Vol 56 (40) ◽  
pp. 5362-5365 ◽  
Author(s):  
Rajkumar Kore ◽  
Steven P. Kelley ◽  
Anand D. Sawant ◽  
Manish Kumar Mishra ◽  
Robin D. Rogers
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Lewis Acid ◽  
Coordination Complexes ◽  
Acid Base ◽  
Base Catalysts ◽  
Acidic Ionic Liquid ◽  
Alkylation Of Benzene ◽  
Base Liquid

Unique Lewis acid/base liquid coordination catalysts were compared to the known super acidic ionic liquid chloroaluminates and found to have higher catalytic activity in the alkylation of benzene.

Understanding the role of hydrogen bonding in Brønsted acidic ionic liquid-catalyzed transesterification: a combined theoretical and experimental investigation

2016 ◽  
Vol 18 (48) ◽  
pp. 32723-32734 ◽  
Author(s):  
Kaixin Li ◽  
Yibo Yan ◽  
Jun Zhao ◽  
Junxi Lei ◽  
Xinli Jia ◽  
...  
Keyword(s):  
Experimental Investigation ◽  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Acidic Ionic Liquids ◽  
Hydrogen Bonding Networks

The intra- and inter-hydrogen bonding networks that govern the catalytic activity of Brønsted acidic ionic liquids were identified.

Reusable and Efficient PS-Supported Acidic Ionic Liquid Catalyst for Mononitration of Toluene

2012 ◽  
Vol 581-582 ◽  
pp. 252-256 ◽  
Author(s):  
Li Xia Li ◽  
Qi Long Ling ◽  
Xiao Dong Xing ◽  
Ye Zhang ◽  
Zu Liang Liu
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Nitric Acid ◽  
Acid Base ◽  
Acidic Ionic Liquid ◽  
Acid Base Titration ◽  
Ft Ir

A polystyrene-supported 1-(propyl-3-sulfonate)-3-methy-imidazolium hydrosulfate acidic ionic liquid (PS-[SO3H-PMIM][HSO4]) catalyst was prepared by grafting and characterized by FT-IR, SEM/TEM, elements analysis, TG/DSC and acid base titration. It exhibited higher catalytic activity and improved para-selectivity than its homogenous counterpart for the nitration of toluene with 68% nitric acid. The catalytic activity of this catalyst decreased slightly after fifth runs in the synthesis of nitrotoluene.

Study of Performance and Synthesis of Et3NHC1-AlC13

2014 ◽  
Vol 1051 ◽  
pp. 178-181
Author(s):  
Li Ming Zhang ◽  
Hai Yan Hu
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Reaction Time ◽  
Influencing Factors ◽  
Mole Fraction ◽  
Catalytic Performance ◽  
Temperature Reaction ◽  
Optimal Conditions ◽  
Alkylation Of Benzene

This thesis is focused on the catalyst of ionic liquids. Firstly, chloroaluminate ionic liquid consisting of triethylaminia hydrochloride and anhydrous A1C13 was prepared, and its catalytic performance on the alkylation of benzene with 1-bromobutane was studied experimentally. The composition of the system was analyzed using gas chromatogram. The effect of such influencing factors were investigated as the constitute of ionic liquid,the dosage of catalyst, the mole ratio of benzene to 1-bromobutane, temperature,reaction time,the regeneration approach of the used ionic liquid catalyst. The results suggested that it helps to increase the conversion of propylene and the selectivity of 1-butylbenzene by increasing the mole fraction of AlCl3 in the ionic liquid, the amount of catalyst, the mole ratio of benzene to 1-butylbenzene, reaction time and by reducing reaction temperature. At optimal conditions of 66.7% of mole fraction of AlCl3 in the ionic liquid, l0wt% of catalyst with respect to benzene, 10:1 of mole ratio of benzene to 1-bromobutane and 313 .15K, both conversion of 1-bromobutane and selectivity of butylbenzene can reach 96.6% in 20 minutes. The activity of the catalyst can be basically remained after eight times reused. For the used ionic liquid, its catalytic activity can be partially recovered via adding some extra AlCl3 notwithstanding less satisfactory. The catalyst performance of ionic liquids on the esterification of ethanol with ethanonic acid was studied.

Tetracarboxyl-Functionalized Ionic Liquid: Synthesis and Catalytic Properties

2015 ◽  
Vol 68 (10) ◽  
pp. 1513 ◽  
Author(s):  
Miaona Feng ◽  
Guoying Zhao ◽  
Hongling Gao ◽  
Suojiang Zhang
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Propionic Acid ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
High Stability ◽  
Ammonium Acetate ◽  
Catalytic Properties ◽  
Potential Applications

Novel tetracarboxyl-functionalized 2,2′-biimidazolium-based ionic liquids (ILs) with different anions were synthesized in two steps from readily available and sustainable starting materials including ammonium acetate, glyoxal, and halogenated propionic acid. The functionalized IL exhibited higher catalytic activity towards the cycloaddition of CO2 to terminal epoxides. With propylene oxide as a substrate, the optimum yield of propylene carbonate reached 82.7 % at an initial CO2 pressure of 2.0 MPa for 4 h at 140°C. Moreover, the functionalized IL catalyst displayed a high stability and can be reused for at least five cycles without obvious loss of catalytic activity. The results provide a simple and economical way to synthesize multi-functionalized imidazolium-based ILs with versatile potential applications.

Brønsted acidic ionic liquid-catalyzed dehydrative formation of isosorbide from sorbitol: introduction of a continuous process

2017 ◽  
Vol 7 (10) ◽  
pp. 2065-2073 ◽  
Author(s):  
Jie Deng ◽  
Bao-Hua Xu ◽  
Yao-Feng Wang ◽  
Xian-En Mo ◽  
Rui Zhang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Continuous Process ◽  
Efficient Synthesis ◽  
Acidic Ionic Liquid ◽  
Highly Efficient ◽  
Brønsted Acidic Ionic Liquid ◽  
Acidic Ionic Liquids ◽  
First Time

A highly efficient synthesis of isosorbide from sorbitol was developed using Brønsted acidic ionic liquids (BILs) as the catalyst for the first time.

Synthesis, Characterization, and Crystal Structure of Several Novel Acidic Ionic Liquids: 1-ethyl-2-alkyl-benzimidazolium Tetra-Fluoroborate

2013 ◽  
Vol 457-458 ◽  
pp. 139-143 ◽  
Author(s):  
Ming Tian Wang ◽  
Chang Ping Pan ◽  
Wei Peng Gai ◽  
Xiao Xia Lv ◽  
Min Gang Zhai ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Ionic Liquid ◽  
Acetic Acid ◽  
Catalytic Activity ◽  
Lamellar Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Acidic Ionic Liquid ◽  
Acidic Ionic Liquids ◽  
Good Catalytic Activity

A series of novel acidic ionic liquid: 1-ethyl-2-alkyl-benzimidazolium tetra-fluoroborate (alkyl= Et, Pr-n, Bu-n) were prepared by simple acid-based neutralization of 1-ethyl-2-alkyl-benzimidazole and tetrafluoroboric acid. The compounds were characterized by FTIR spectra, elemental analysis,1HNMR spectra and thermogravimetric analysis. These novel tetra-fluoroborate salts show good catalytic activity to esterification of benzyl alcohol and acetic acid. Furthermore, a crystal of ([H-ebBiBF4) was prepared with the crystal structure and determined by X-ray diffraction analysis. The molecular is of lamellar structure as mainly π electron ring is stacked interleaving between two layers. The results of cation and anion arranged orderly in pair indicate that the coulombic attraction is more dominant. Simultaneously, the weak local hydrogen bonds C-H···F exist in the molecules.

scholarly journals The effect of the morpholinium ionic liquid anion on the catalytic activity of Rh (or Pt) complex–ionic liquid systems in hydrosilylation processes

RSC Advances ◽  
2018 ◽  
Vol 8 (47) ◽  
pp. 26922-26927 ◽  
Author(s):  
Magdalena Jankowska-Wajda ◽  
Izabela Dąbek ◽  
Ryszard Fiedorow ◽  
Hieronim Maciejewski
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Platinum Complexes ◽  
Pt Complex ◽  
Liquid Systems

Rhodium and platinum complexes were immobilized in morpholinium ionic liquids, the effect of which on the catalytic activity was determined.

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