Porous Li-MOF as a solid-state electrolyte: exploration of lithium ion conductivity through bio-inspired ionic channels

2020 ◽  
Vol 56 (94) ◽  
pp. 14873-14876
Author(s):  
Karabi Nath ◽  
Abdulla Bin Rahaman ◽  
Rajib Moi ◽  
Kartik Maity ◽  
Kumar Biradha
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Lithium Ion ◽  
Ionic Channels ◽  
Solvent Free ◽  
Ion Conductivity ◽  
Solid State Electrolyte ◽  
Li Ion ◽  
Lithium Ion Conductivity

A newly constructed porous Li-MOF was used as a solvent free solid electrolyte for Li-ion conductivity.

Enhancing the Lithium Ion Conductivity of an All Solid-State Electrolyte via Dry and Solvent-Free Scalable Series Production Processes

2020 ◽  
Vol 167 (2) ◽  
pp. 020558 ◽  
Author(s):  
Linus Froboese ◽  
Lajos Groffmann ◽  
Frederike Monsees ◽  
Laura Helmers ◽  
Thomas Loellhoeffel ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion ◽  
Solvent Free ◽  
Ion Conductivity ◽  
Series Production ◽  
Solid State Electrolyte ◽  
Production Processes ◽  
Lithium Ion Conductivity

scholarly journals Lithium-ion conductivity in Li6Y(BO3)3: a thermally and electrochemically robust solid electrolyte

2016 ◽  
Vol 4 (18) ◽  
pp. 6972-6979 ◽  
Author(s):  
Beatriz Lopez-Bermudez ◽  
Wolfgang G. Zeier ◽  
Shiliang Zhou ◽  
Anna J. Lehner ◽  
Jerry Hu ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Ion Diffusion ◽  
New Energy ◽  
Li Ion ◽  
Lithium Ion Conductivity ◽  
Storage Technologies

The development of new frameworks for solid electrolytes exhibiting fast Li-ion diffusion is critical for enabling new energy storage technologies.

Cationic covalent organic framework based all-solid-state electrolytes

2020 ◽  
Vol 4 (4) ◽  
pp. 1164-1173 ◽  
Author(s):  
Zhen Li ◽  
Zhi-Wei Liu ◽  
Zhen-Jie Mu ◽  
Chen Cao ◽  
Zeyu Li ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolytes ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Li Ion Battery ◽  
Covalent Organic Framework ◽  
Li Ion ◽  
Lithium Ion Conductivity ◽  
Organic Framework

Two new imidazolium-based cationic COFs were synthesized and employed as all-solid electrolytes, and exhibited high lithium ion conductivity at high temperature. The assembled Li-ion battery displays preferable battery performance at 353 K.

Lithium ion conductivity of oriented Li0.33La0.56TiO3 solid electrolyte films prepared by a sol–gel process

2016 ◽  
Vol 284 ◽  
pp. 1-6 ◽  
Author(s):  
Takashi Teranishi ◽  
Yuki Ishii ◽  
Hidetaka Hayashi ◽  
Akira Kishimoto
Keyword(s):  
Solid Electrolyte ◽  
Sol Gel ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Sol Gel Process ◽  
Lithium Ion Conductivity

scholarly journals Mastering the interface for advanced all-solid-state lithium rechargeable batteries

2016 ◽  
Vol 113 (47) ◽  
pp. 13313-13317 ◽  
Author(s):  
Yutao Li ◽  
Weidong Zhou ◽  
Xi Chen ◽  
Xujie Lü ◽  
Zhiming Cui ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Rechargeable Batteries ◽  
Ion Conductivity ◽  
Rhombohedral Structure ◽  
Interfacial Resistance ◽  
Lithium Anode ◽  
Metal Anode ◽  
Li Ion

A solid electrolyte with a high Li-ion conductivity and a small interfacial resistance against a Li metal anode is a key component in all-solid-state Li metal batteries, but there is no ceramic oxide electrolyte available for this application except the thin-film Li-P oxynitride electrolyte; ceramic electrolytes are either easily reduced by Li metal or penetrated by Li dendrites in a short time. Here, we introduce a solid electrolyte LiZr2(PO4)3 with rhombohedral structure at room temperature that has a bulk Li-ion conductivity σLi = 2 × 10−4 S⋅cm−1 at 25 °C, a high electrochemical stability up to 5.5 V versus Li+/Li, and a small interfacial resistance for Li+ transfer. It reacts with a metallic lithium anode to form a Li+-conducting passivation layer (solid-electrolyte interphase) containing Li3P and Li8ZrO6 that is wet by the lithium anode and also wets the LiZr2(PO4)3 electrolyte. An all-solid-state Li/LiFePO4 cell with a polymer catholyte shows good cyclability and a long cycle life.

Engineering Frenkel defects of anti-perovskite solid-state electrolytes and their applications in all-solid-state lithium-ion batteries

2020 ◽  
Vol 56 (8) ◽  
pp. 1251-1254 ◽  
Author(s):  
Lihong Yin ◽  
Huimin Yuan ◽  
Long Kong ◽  
Zhouguang Lu ◽  
Yusheng Zhao
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Cell Configuration ◽  
Solid State Cell ◽  
Frenkel Defects ◽  
Lithium Ion Conductivity ◽  
Solid State Electrolytes

Fluorinated lithium-rich anti-perovskite (F-LiRAP) is proposed to enhance lithium ion conductivity by creating Frenkel defects and an all-solid-state cell configuration based on F-LiRAP is successfully demonstrated.

ChemInform Abstract: A Sol-Gel Solid Electrolyte with High Lithium Ion Conductivity.

ChemInform ◽  
2010 ◽  
Vol 28 (27) ◽  
pp. no-no
Author(s):  
P.-W. WU ◽  
S. R. HOLM ◽  
A. T. DUONG ◽  
B. DUNN ◽  
R. B. KANER
Keyword(s):  
Solid Electrolyte ◽  
Sol Gel ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Lithium Ion Conductivity

A Sol-Gel Solid Electrolyte with High Lithium Ion Conductivity

1997 ◽  
Vol 9 (4) ◽  
pp. 1004-1011 ◽  
Author(s):  
Pu-Wei Wu ◽  
Steven R. Holm ◽  
Anh T. Duong ◽  
Bruce Dunn ◽  
Richard B. Kaner
Keyword(s):  
Solid Electrolyte ◽  
Sol Gel ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Lithium Ion Conductivity

Epitaxial growth and lithium ion conductivity of lithium-oxide garnet for an all solid-state battery electrolyte

2013 ◽  
Vol 42 (36) ◽  
pp. 13112 ◽  
Author(s):  
Sangryun Kim ◽  
Masaaki Hirayama ◽  
Sou Taminato ◽  
Ryoji Kanno
Keyword(s):  
Solid State ◽  
Epitaxial Growth ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Lithium Oxide ◽  
Solid State Battery ◽  
Battery Electrolyte ◽  
Lithium Ion Conductivity
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