A sodium trifluoromethanesulfinate-mediated photocatalytic strategy for aerobic oxidation of alcohols

2020 ◽  
Vol 56 (82) ◽  
pp. 12443-12446
Author(s):  
Xianjin Zhu ◽  
Can Liu ◽  
Yong Liu ◽  
Haijun Yang ◽  
Hua Fu
Keyword(s):  
Carboxylic Acids ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Oxidation Of Alcohols ◽  
First Time

A sodium trifluoromethanesulfinate-mediated photocatalytic strategy for the aerobic oxidation of secondary and primary alcohols to ketones and carboxylic acids has been developed for the first time.

ChemInform Abstract: Iron Catalysis for Room-Temperature Aerobic Oxidation of Alcohols to Carboxylic Acids.

ChemInform ◽  
2016 ◽  
Vol 47 (50) ◽  
Author(s):  
Xingguo Jiang ◽  
Jiasheng Zhang ◽  
Shengming Ma
Keyword(s):  
Carboxylic Acids ◽  
Room Temperature ◽  
Aerobic Oxidation ◽  
Iron Catalysis ◽  
Oxidation Of Alcohols

Reusable Homogeneous Metal- and Additive-Free Photocatalyst for High-Performance Aerobic Oxidation of Alcohols to Carboxylic Acids

2021 ◽  
pp. 121028
Author(s):  
Jing-Wang Cui ◽  
Shuai Ma ◽  
Cai-Hui Rao ◽  
Meng-Ze Jia ◽  
Xin-Rong Yao ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
High Performance ◽  
Aerobic Oxidation ◽  
Oxidation Of Alcohols

Transition-metal-free aerobic oxidation of primary alcohols to carboxylic acids

2013 ◽  
Vol 37 (6) ◽  
pp. 1700 ◽  
Author(s):  
Jing Wang ◽  
Chao Liu ◽  
Jiwen Yuan ◽  
Aiwen Lei
Keyword(s):  
Transition Metal ◽  
Carboxylic Acids ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Metal Free

Aerobic Oxidation of Diverse Primary Alcohols to Carboxylic Acids with a Heterogeneous Pd–Bi–Te/C (PBT/C) Catalyst

2017 ◽  
Vol 21 (9) ◽  
pp. 1388-1393 ◽  
Author(s):  
Maaz S. Ahmed ◽  
David S. Mannel ◽  
Thatcher W. Root ◽  
Shannon S. Stahl
Keyword(s):  
Carboxylic Acids ◽  
Aerobic Oxidation ◽  
Primary Alcohols

scholarly journals A Recyclable, Metal-Free Mechanochemical Approach for the Oxidation of Alcohols to Carboxylic Acids

Molecules ◽  
2020 ◽  
Vol 25 (2) ◽  
pp. 364 ◽  
Author(s):  
Kendra Leahy Denlinger ◽  
Preston Carr ◽  
Daniel C. Waddell ◽  
James Mack
Keyword(s):  
Stainless Steel ◽  
Ball Milling ◽  
Carboxylic Acids ◽  
Steric Hindrance ◽  
Primary Alcohol ◽  
Oxidation Reactions ◽  
Primary Alcohols ◽  
Metal Free ◽  
Oxidation Of Alcohols ◽  
Stainless Steel Ball

The oxidation of primary alcohols under mechanochemical conditions in a Spex8000M Mixer/Mill was investigated. To facilitate ease of separation and recyclability, a polystyrene-bound version of a TEMPO catalyst was employed. When paired with Oxone® in a stainless-steel vial with a stainless-steel ball, several primary alcohols were successfully oxidized to the corresponding carboxylic acids. The product was isolated using gravity filtration, which also allowed for the polystyrene-bound TEMPO catalyst to be recovered and reused in subsequent oxidation reactions. Furthermore, it was demonstrated that the size and steric hindrance of the primary alcohol does not hinder the rate of the reaction. Finally, the aldehyde was selectively obtained from a primary alcohol under ball milling conditions by using a combination of non-supported TEMPO with a copper vial and copper ball.

scholarly journals Palladium supported on a novel ordered mesoporous polypyrrole/carbon nanocomposite as a powerful heterogeneous catalyst for the aerobic oxidation of alcohols to carboxylic acids and ketones on water

RSC Advances ◽  
2020 ◽  
Vol 10 (23) ◽  
pp. 13616-13631 ◽  
Author(s):  
Nasim Ganji ◽  
Babak Karimi ◽  
Sepideh Najafvand-Derikvandi ◽  
Hojatollah Vali
Keyword(s):  
Heterogeneous Catalyst ◽  
Carboxylic Acids ◽  
Aerobic Oxidation ◽  
Ordered Mesoporous ◽  
Oxidation Of Alcohols ◽  
Carbon Nanocomposite

Aerobic oxidation of alcohols to carboxylic acids and ketones in water using palladium species supported on an ordered mesoporous polypyrrole/carbon nanocomposite.

scholarly journals A green and sustainable phosphine-free NHC-ruthenium catalyst for selective oxidation of alcohols to carboxylic acids in water

2015 ◽  
Vol 44 (39) ◽  
pp. 17409-17414 ◽  
Author(s):  
Jagadeesh Malineni ◽  
Helmut Keul ◽  
Martin Möller
Keyword(s):  
Oxygen Atom ◽  
Carboxylic Acids ◽  
Selective Oxidation ◽  
Direct Synthesis ◽  
Ruthenium Catalyst ◽  
Catalytic Dehydrogenation ◽  
Oxidizing Agent ◽  
Primary Alcohols ◽  
Oxidation Of Alcohols ◽  
Atom Source

An efficient novel protocol is applied for direct synthesis of carboxylic acids from primary alcohols through catalytic dehydrogenation. This reaction occurs in water as the solvent and as the oxygen-atom source and no toxic oxidizing agent is involved.

Iron Catalysis for Room-Temperature Aerobic Oxidation of Alcohols to Carboxylic Acids

2016 ◽  
Vol 138 (27) ◽  
pp. 8344-8347 ◽  
Author(s):  
Xingguo Jiang ◽  
Jiasheng Zhang ◽  
Shengming Ma
Keyword(s):  
Carboxylic Acids ◽  
Room Temperature ◽  
Aerobic Oxidation ◽  
Iron Catalysis ◽  
Oxidation Of Alcohols

ChemInform Abstract: Transition-Metal-Free Aerobic Oxidation of Primary Alcohols to Carboxylic Acids.

ChemInform ◽  
2013 ◽  
Vol 44 (45) ◽  
pp. no-no
Author(s):  
Jing Wang ◽  
Chao Liu ◽  
Jiwen Yuan ◽  
Aiwen Lei
Keyword(s):  
Transition Metal ◽  
Carboxylic Acids ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Metal Free
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