Highly efficient utilization of light and charge separation over a hematite photoanode achieved through a noncontact photonic crystal film for photoelectrochemical water splitting

2020 ◽  
Vol 22 (36) ◽  
pp. 20202-20211
Author(s):  
Wen-Yuan Yu ◽  
De-Kun Ma ◽  
Dong-Peng Yang ◽  
Xiao-Gang Yang ◽  
Quan-Long Xu ◽  
...  

Highly efficient utilization of light and charge separation over a hematite photoanode could be achieved through a noncontact photonic crystal film.

2016 ◽  
Vol 9 (8) ◽  
pp. 2633-2643 ◽  
Author(s):  
Fanyu Ning ◽  
Mingfei Shao ◽  
Simin Xu ◽  
Yi Fu ◽  
Ruikang Zhang ◽  
...  

TiO2/graphene/NiFe-layered double hydroxide nanorod arrays were fabricated as highly efficient photoanodes for photoelectrochemical water splitting with simultaneously enhanced charge separation and water oxidation efficiency.


2019 ◽  
Author(s):  
Jiajia Tao ◽  
Hong-Ping Ma ◽  
Kaiping Yuan ◽  
Yang Gu ◽  
Jianwei Lian ◽  
...  

<div>As a promising oxygen evolution reaction semiconductor, TiO2 has been extensively investigated for solar photoelectrochemical water splitting. Here, a highly efficient and stable strategy for rationally preparing GaON cocatalysts on TiO2 by atomic layer deposition is demonstrated, which we show significantly enhances the</div><div>photoelectrochemical performance compared to TiO2-based photoanodes. For TiO2@20 nm-GaON core-shell nanowires a photocurrent density up to 1.10 mA cm-2 (1.23 V vs RHE) under AM 1.5 G irradiation (100 mW cm-2) has been achieved, which is 14 times higher than that of TiO2 NWs. Furthermore, the oxygen vacancy formation on GaON as well as the band gap matching with TiO2 not only provides more active sites for water oxidation but also enhances light absorption to promote interfacial charge separation and migration. Density functional theory studies of model systems of GaON-modified TiO2 confirm the band gap reduction, high reducibility and ability to activate water. The highly efficient and stable systems of TiO2@GaON core-shell nanowires provide a deeper understanding and universal strategy for enhancing photoelectrochemical performance of photoanodes now available. </div>


2019 ◽  
Vol 48 (31) ◽  
pp. 11934-11940 ◽  
Author(s):  
Jianmin Wang ◽  
Yunan Wang ◽  
Xinchao Xv ◽  
Yan Chen ◽  
Xi Yang ◽  
...  

Defective Fe3+ self-doped spinel ZnFe2O4 with abundant oxygen vacancies exhibits largely enhanced photoelectrochemical performance.


2016 ◽  
Vol 7 (9) ◽  
pp. 6076-6082 ◽  
Author(s):  
Ailong Li ◽  
Zhiliang Wang ◽  
Heng Yin ◽  
Shengyang Wang ◽  
Pengli Yan ◽  
...  

The key to phase junctions for efficient charge separation is to consider both the phase alignment and interface structure.


2021 ◽  
Author(s):  
Dong Qiu ◽  
Chengli He ◽  
Yuxuan Lu ◽  
Qiaodan Li ◽  
Yang Chen ◽  
...  

Photoelectrochemical water splitting is an excellent strategy for hydrogen generation, and it is pivotal to develop photoanodes with proficient sunlight harvesting, rapid charge separation, and enhanced electron injection efficiency. In...


2018 ◽  
Vol 6 (41) ◽  
pp. 20393-20401 ◽  
Author(s):  
Dong Chen ◽  
Zhifeng Liu ◽  
Zhengang Guo ◽  
Weiguo Yan ◽  
Ying Xin

A feasible strategy of spatially separated noble-metal cocatalysts for Cu2O photocathodes to enhance light harvesting and charge separation.


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