Cleavage of C-O and C-H bonds in ethers by a genuine Si=O bond

2021 ◽  
Author(s):  
Ryo Kobayashi ◽  
Shintaro Ishida ◽  
Takeaki Iwamoto
Keyword(s):  
Electronic Stabilization

An isolable three-coordinate dialkylsilanone without a substantial electronic stabilization reacts with several ethers resulting in the cleavage of the C-O or C-H and C-O bonds in ether which have not...

Nickel(II)-Methyl Complexes Adopting Idealized Seesaw Geometries

2019 ◽  
Author(s):  
Ethan A. Hill ◽  
Norman Zhao ◽  
Alexander S. Filatov ◽  
John Anderson
Keyword(s):  
Singlet State ◽  
Strong Field ◽  
Structural Distortion ◽  
Computational Results ◽  
Threefold Symmetry ◽  
Chelating Ligand ◽  
Electronic Stabilization

We report four-coordinate nickel(II)-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.

Photoemission evidence of electronic stabilization of polar surfaces inK3C60

2000 ◽  
Vol 62 (23) ◽  
pp. 16046-16055 ◽  
Author(s):  
R. Hesper ◽  
L. H. Tjeng ◽  
A. Heeres ◽  
G. A. Sawatzky
Keyword(s):  
Polar Surfaces ◽  
Electronic Stabilization

Electronic stabilization of the Si(111)5 × 2–Au surface: Pb and Si adatoms

2012 ◽  
Vol 24 (9) ◽  
pp. 095002 ◽  
Author(s):  
A Stȩpniak ◽  
M Krawiec ◽  
G Zawadzki ◽  
M Jałochowski
Keyword(s):  
Electronic Stabilization

Study on Stability of Nano-Al2O3 Aqueous Suspension

2007 ◽  
Vol 280-283 ◽  
pp. 1023-1026
Author(s):  
Wei Zhao ◽  
De An Yang ◽  
Xiu Xin Yin ◽  
Ting Xian Xu
Keyword(s):  
High Performance ◽  
Aqueous Suspension ◽  
Ammonium Citrate ◽  
Tem Analysis ◽  
Sediment Volume ◽  
Electrostatic Stabilization ◽  
Volume Viscosity ◽  
High Performance Composite ◽  
Electronic Stabilization ◽  
Ceramic Fillers

Al2O3 ceramic fillers were incorporated into polyetheretherketone (PEEK) to improve the mechanical property in order to suit its aerospace application. To get the high performance composite, it is important to control the dispersion of the nano-Al2O3 among the PEEK matrix. As a pre-fabrication process, the dispersion behaviors of the nano-Al2O3 particles in the liquid medium were studied. Thestability of suspensions was characterized by zeta potential, sediment volume, viscosity and TEM analysis. The mechanism of dispersing nano-Al2O3 aqueous suspension has been investigated including single-electronic stabilization, steric stabilization, and electrostatic stabilization. The highly dispersed and stabilized nano-Al2O3 aqueous suspensions were obtained at acidic condition (pH=3) with PEG-400 and tri-ammonium citrate (TAC).

Electronic stabilization of scanning interferometers

1976 ◽  
Vol 15 (4) ◽  
pp. 929 ◽  
Author(s):  
H. R. Carleton
Keyword(s):  
Electronic Stabilization
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