A series of porous 3D inorganic–organic hybrid framework crystalline materials based on 5-aminoisophthalic acid for photocatalytic degradation of crystal violet

2021 ◽  
Vol 45 (7) ◽  
pp. 3432-3440
Author(s):  
Yu Xin ◽  
Jun Zhou ◽  
Yong Heng Xing ◽  
Feng Ying Bai ◽  
Li Xian Sun

Seven 3D metal-organic frameworks have been designed and synthesized by the hydrothermal synthetic method based on the ligand 5-aminoisophthalic acid. Complexes 1-4 have better photocatalytic degradation properties for dyes CV.

2021 ◽  
Vol 7 (2) ◽  
pp. 47
Author(s):  
Flávio Figueira ◽  
Filipe A. Almeida Paz

Metal–organic frameworks (MOFs) are crystalline materials with permanent porosity, composed of metal nodes and organic linkers whose well-ordered arrangement enables them to act as ideal templates to produce materials with a uniform distribution of heteroatom and metal elements. The hybrid nature of MOFs, well-defined pore structure, large surface area and tunable chemical composition of their precursors, led to the preparation of various MOF-derived porous carbons with controlled structures and compositions bearing some of the unique structural properties of the parent networks. In this regard, an important class of MOFs constructed with porphyrin ligands were described, playing significant roles in the metal distribution within the porous carbon material. The most striking early achievements using porphyrin-based MOF porous carbons are here summarized, including preparation methods and their transformation into materials for electrochemical reactions.


RSC Advances ◽  
2017 ◽  
Vol 7 (17) ◽  
pp. 10415-10423 ◽  
Author(s):  
Yu Wu ◽  
Jian Wu ◽  
Zhidong Luo ◽  
Jun Wang ◽  
Yulong Li ◽  
...  

Two new MOFs show 3D 2-fold interpenetrating 4-connected networks and could be a prospective candidate for developing the luminescence sensors and the photocatalysis due to their highly stabilities.


2016 ◽  
Vol 16 (4) ◽  
pp. 2309-2316 ◽  
Author(s):  
Ya-Pan Wu ◽  
Xue-Qian Wu ◽  
Jian-Fang Wang ◽  
Jun Zhao ◽  
Wen-Wen Dong ◽  
...  

CrystEngComm ◽  
2021 ◽  
Author(s):  
Olaya Paz Gomez ◽  
Rosa Carballo ◽  
Ana Belen Lago ◽  
Ezequiel M. Vazquez-Lopez

Polymorphism is a common phenomenon in crystalline materials but it has barely been studied in the field of metal organic frameworks. The study of polymorphism is useful to investigate structure–property...


2020 ◽  
Vol 8 (3) ◽  
pp. 103726 ◽  
Author(s):  
Sanjeev Gautam ◽  
Harshita Agrawal ◽  
Manisha Thakur ◽  
Ali Akbari ◽  
Hemam Sharda ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (23) ◽  
pp. 17601-17605 ◽  
Author(s):  
Yueyue Tan ◽  
Wei Zhang ◽  
Yilong Gao ◽  
Jianxiang Wu ◽  
Bohejin Tang

A facile synthetic method was developed to prepare Zr-MOFs. Pseudocapacitor behavior in KOH electrolyte. Zr-MOF1 with small particle size exhibited higher supercapacitive performance.


Inorganics ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 81
Author(s):  
Alessia Tombesi ◽  
Claudio Pettinari

Metal–organic frameworks (MOFs) are a family of porous crystalline materials that serve in some cases as versatile platforms for catalysis. In this review, we overview the recent developments about the use of these species as heterogeneous catalysts in olefin epoxidation and carbon dioxide cycloaddition. We report the most important results obtained in this field relating them to the presence of specific organic linkers, metal nodes or clusters and mixed-metal species. Recent advances obtained with MOF nanocomposites were also described. Finally we compare the results and summarize the major insights in specific Tables, outlining the major challenges for this emerging field. This work could promote new research aimed at producing coordination polymers and MOFs able to catalyse a broader range of CO2 consuming reactions.


2021 ◽  
Author(s):  
Shadpour Mallakpour ◽  
Elham Azadi ◽  
Chaudhery Mustansar Hussain

Over the past decade, porous crystalline materials such as covalent organic frameworks (COFs) and metal-organic frameworks (MOFs) with unique features such as intrinsic porosity, well-defined topology, diverse functionalities, large surface...


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