Overview on Oscillating Water Column Devices

Oscillating-water-column (OWC) converters, of fixed structure or floating, are an important class of wave energy devices. A large part of wave energy converter prototypes deployed so far into the sea are of OWC type. The paper presents a review of recent advances in OWC technology, including sea-tested prototypes and plants, new concepts, air turbines, model testing techniques and control.

Post-Synthetic Enzymatic and Chemical Modifications for Novel Sustainable Polyesters

Because of their biodegradability, compostability, compatibility and flexible structures, biodegradable polymers such as polyhydroxyalkanoates (PHA) are an important class of biopolymers with various industrial and biological uses. PHAs are thermoplastic polyesters with a limited processability due to their low heat resistance. Furthermore, due to their high crystallinity, some PHAs are stiff and brittle. These features result sometimes in very poor mechanical characteristics with low extension at break values which limit the application range of some natural PHAs. Several in vivo approaches for PHA copolymer modifications range from polymer production to enhance PHA-based material performance after synthesis. The methods for enzymatic and chemical polymer modifications are aiming at modifying the structures of the polyesters and thereby their characteristics while retaining the biodegradability. This survey illustrates the efficient use of enzymes and chemicals in post-synthetic PHA modifications, offering insights on these green techniques for modifying and improving polymer performance. Important studies in this sector will be reviewed, as well as chances and obstacles for their stability and hyper-production.

The application of multiple parallel diodes to control large currents

This paper discusses a few issues concerning diodes and their application in electric circuits. Considering voltage and current restrictions, experimental and theoretical efforts are made to safely apply semiconducting diodes in circuits working with large current regimes. Combinations of diodes and protecting resistors connected in series and parallel have demonstrated to be of great help with the task of controlling electric currents. To this aim, several activities have enabled participants to observe and measure, or to calculate and display valuable data. Therefore, important class conclusions are stated.

FDA-Approved Oximes and Their Significance in Medicinal Chemistry

Despite the scientific advancements, organophosphate (OP) poisoning continues to be a major threat to humans, accounting for nearly one million poisoning cases every year leading to at least 20,000 deaths worldwide. Oximes represent the most important class in medicinal chemistry, renowned for their widespread applications as OP antidotes, drugs and intermediates for the synthesis of several pharmacological derivatives. Common oxime based reactivators or nerve antidotes include pralidoxime, obidoxime, HI-6, trimedoxime and methoxime, among which pralidoxime is the only FDA-approved drug. Cephalosporins are β-lactam based antibiotics and serve as widely acclaimed tools in fighting bacterial infections. Oxime based cephalosporins have emerged as an important class of drugs with improved efficacy and a broad spectrum of anti-microbial activity against Gram-positive and Gram-negative pathogens. Among the several oxime based derivatives, cefuroxime, ceftizoxime, cefpodoxime and cefmenoxime are the FDA approved oxime-based antibiotics. Given the pharmacological significance of oximes, in the present paper, we put together all the FDA-approved oximes and discuss their mechanism of action, pharmacokinetics and synthesis.

Recent progress in pyrazinoacenes containing nonbenzenoid rings: synthesis, properties and applications

Azaacenes have emerged as a new and important class of organic materials, and their synthetic strategies and applications as organic semiconductors have gained great progress in recent years. Generally, adopting...

Regulation of Conjugate Rigid Plane Structure to Achieving Transformation of Fluorescent Recognition Properties

Bisbenzimidazole is an important class of fluorescence molecular probe materials with environmental, clinical and biological systems. Meanwhile, different bisbenzimidazole derivatives due to excellent coordination property and various fluorescence characteristic, were...

Anisotropic Oxidative Growth Of Goethite-Coated Sand Particles In Column Reactors During 4-Chloronitrobenzene Reduction by Fe(II)/Goethite

Reduction of nitroaromatic compounds (NACs), an important class of groundwater pollutants, by Fe(II) associated with iron oxides, a highly reactive reductant in anoxic aquifers, has been studied widely, but there...

BINOL-phosphoric acid and metalloporphyrin derived chiral covalent organic framework for enantioselective α-benzylation of aldehydes

The catalytic asymmetric α-benzylation of aldehydes represents a highly valuable reaction for organic synthesis. For example, the generated α-heteroarylmethyl aldehydes, such as (R)-2-methyl-3-(pyridin-4-yl)propanal ((R)-MPP), are an important class of synthons...

Quantum Dot Photolithography using Quantum Dot Photoresist composed of Organic-Inorganic Hybrid Coating Layer

Quantum dots (QDs) have emerged as an important class of material due to their excellent photonic properties and durability for diverse applications such as solid-state lighting, energy conversion, display, biomedicine,...

Characterization and Applications of Metal Ferrite Nanocomposites

In recent years, nanosized spinel-type ferrites emerged as an important class of nanomaterials due to their high electrical resistivity, low eddy current loss, structural stability, large permeability at high frequency, high coercivity, high cubic magnetocrystalline anisotropy, good mechanical hardness, and chemical stability [...]